Monthly Tech-Tip from Tony Hansen SignUp

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Comparing two glazes having different mechanisms for their matteness

These are two cone 6 matte glazes (shown side by side in an account at Insight-live). G1214Z is high calcium and a high silica:alumina ratio. It crystallizes during cooling to make the matte effect and the degree of matteness is adjustable by trimming the silica content (but notice how much it runs). The G2928C has high MgO and it produces the classic silky matte by micro-wrinkling the surface, its matteness is adjustable by trimming the calcined kaolin. CaO is a standard oxide that is in almost all glazes, 0.4 is not high for it. But you would never normally see more than 0.3 of MgO in a cone 6 glaze (if you do it will likely be unstable). The G2928C also has 5% tin, if that was not there it would be darker than the other one because Ravenscrag Slip has a little iron. This was made by recalculating the Moore's Matte recipe to use as much Ravenscrag Slip as possible yet keep the overall chemistry the same. This glaze actually has texture like a dolomite matte at cone 10R, it is great. And it has wonderful application properties. And it does not craze, on Plainsman M370 (it even survived a 300F-to-ice water IWCT test). This looks like it could be a great liner glaze.

Comparing two glazes having different mechanisms for their matteness

Related Pictures

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You will see examples of replacing unavailable materials (especially frits), fixing various issues (e.g. running, crazing, settling), making them melt more, adjusting matteness, etc. Insight-Live has an extensive help system (the round blue icon on the left) that also deals with fixing real-world problems and understanding glazes and clay bodies.

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Glossary Matte Glaze
Random material mixes that melt well overwhelmingly want to be glossy, creating a matte glaze that is also functional is not an easy task.
Glossary Mechanism
Identifying the mechanism of a ceramic glaze recipe is the key to moving adjusting it, fixing it, reverse engineering it, even avoiding it!
Glossary Glaze Chemistry
Glaze chemistry is the study of how the oxide chemistry of glazes relate to the way they fire. It accounts for color, surface, hardness, texture, melting temperature, thermal expansion, etc.
Glossary Insight-Live
A cloud-hosted ceramics-targetted LIMS (lab info management system) enabling collection, organization and learning from data to develop, adjust and study their recipes, materials and processes.
Oxides MgO - Magnesium Oxide, Magnesia
Oxides CaO - Calcium Oxide, Calcia
Recipes G2928C - Ravenscrag Silky Matte for Cone 6
Plainsman Cone 6 Ravenscrag Slip based glaze. It can be found among others at http://ravenscrag.com.
Recipes G1214Z1 - Cone 6 Silky Matte
This glaze was born as a demonstration of how to use chemistry to convert a glossy cone 6 glaze into a matte.
Materials Calcined Kaolin

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