Substitute Ferro Frit 3134, using glaze chemistry, in three glaze types

Can't get frit 3134 for glaze recipes? Can you replace it with frit 3124? No, 3124 has five times the amount of Al₂O₃ (the second most important oxide in glazes) and half the amount of B₂O₃ (the main melter). This ten-minute video presents a glaze chemistry approach that is easier to do than you probably think. On three different recipe types, you will learn to source the needed oxides from two other Ferro frits, 3110 (or Fusion F-75) and 3195 (Fusion F-2) and end up with at least 15% kaolin in each (to suspend the slurry). Each requires a unique approach. Two of the calculations produce improved slurry properties and one yields a recipe of significantly lower cost. If you have a recipe that needs this, get an insight-live.com account, enter it there and I can help you do the calculation.

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You will see examples of replacing unavailable materials (especially frits), fixing various issues (e.g. running, crazing, settling), making them melt more, adjusting matteness, etc. Insight-Live has an extensive help system (the round blue icon on the left) that also deals with fixing real-world problems and understanding glazes and clay bodies.

Is Ferro Frit 3124 a viable substitute for Frit 3134?

Three melt from tests comparing these frits

This is a GLFL test comparing the melt flow of the three materials at 1800F. Frit 3124 is barely out of the starting gate and the other two have crossed the finish line! With frits chemistry is a big deal, they are all about supplying oxides to the melt. Frit 3134 is low-alumina/high-boron, 3124 is medium-alumina/low-boron and 3195 is medium-alumina/high-boron. Boron is the melter. Alumina thickens the melt and hardens the glass. Just from this it appears that Frit 3195 is a better starting point for calculations to replace frit 3134.

These common Ferro frits have distinct uses in traditional ceramics

I used Veegum to form 10 gram GBMF test balls and fired them at cone 08 (1700F). Frits melt really well, they do have an LOI like raw materials. These contain boron (B₂O₃), it is a low expansion super-melter that raw materials don’t have. Frit 3124 (glossy) and 3195 (silky matte) are balanced-chemistry bases (just add 10-15% kaolin for a cone 04 glaze, or more silica+kaolin to go higher). Consider Frit 3110 a man-made low-Al₂O₃ super feldspar. Its high-sodium makes it high thermal expansion. It works really well in bodies and is great to make glazes that craze. The high-MgO Frit 3249 (made for the abrasives industry) has a very-low expansion, it is great for fixing crazing glazes. Frit 3134 is similar to 3124 but without Al₂O₃. Use it where the glaze does not need more Al₂O₃ (e.g. already has enough clay). It is no accident that these are used by potters in North America, they complement each other well (equivalents are made around the world by others). The Gerstley Borate is a natural source of boron (with issues frits do not have).

Links

Materials	Ferro Frit 3134 A frit with 23% B2O3. The most common of frits used in pottery in North America. Around the world, other companies make frits of equivalent chemistry.
Materials	Ferro Frit 3195 A commonly used boron frit, it is a balanced glaze all along at cone 06-02 (with the addition of 10-15% kaolin). Not fully glossy.
Materials	Ferro Frit 3124 A commonly available calcium borosilicate frit.
Media	Substitute Ferro Frit 3134 For Another Frit I use my Insight-live account to do the glaze chemistry to replace Ferro frit 3134 with combinations of three other common Ferro frits. We will see the challenges of doing this in three different types of recipes.
Glossary	Material Substitution Material substitutions in ceramic glaze and body recipes must consider their chemistry, mineralogy and physical properties
Glossary	Frit Frits are used in ceramic glazes for a wide range of reasons. They are man-made glass powders of controlled chemistry with many advantages over raw materials.
Typecodes	Glaze Chemistry Case studies where glaze chemistry was used to solve a problem.

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