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1047 | 1048 | 1049 | 1050 | 1051 | 1052 | 1053 | 1042 | 1043 | 1044 | 1045 | 1046 | 1036 | 1037 | 1038 | 1039 | 1040 | 1041 | 1034 | 1035 | 910 | 1032 | 935 | 1030 | 1031 | 1026 | 1027 | 1028 | 1029 | 1024 | 1025 | 1023 | 1021 | 1022 | 1018 | 1019 | 1020 | 1017 | 684 | 1016 | 1015 | 890 | 1014 | 1011 | 1012 | 1013 | 1010 | 1009 | 1008 | 1007 | 660 | 1006 | 690 | 1005 | 1002 | 1003 | 997 | 999 | 1000 | 1001 | 996 | 995 | 994 | 987 | 988 | 989 | 990 | 991 | 992 | 984 | 985 | 986 | 431 | 983 | 982 | 979 | 980 | 981 | 961 | 977 | 978 | 975 | 976 | 972 | 974 | 969 | 970 | 971 | 968 | 911 | 967 | 817 | 850 | 853 | 658 | 659 | 439 | 966 | 964 | 962 | 963 | 960 | 958 | 959 | 957 | 954 | 955 | 956 | 952 | 953 | 949 | 950 | 951 | 947 | 948 | 946 | 945 | 944 | 943 | 942 | 941 | 938 | 936 | 937 | 934 | 931 | 932 | 933 | 752 | 292 | 815 | 816 | 819 | 316 | 832 | 839 | 846 | 847 | 854 | 855 | 863 | 864 | 865 | 362 | 879 | 888 | 891 | 918 | 689 | 716 | 722 | 724 | 741 | 744 | 746 | 749 | 750 | 929 | 927 | 928 | 925 | 926 | 924 | 153 | 923 | 919 | 921 | 916 | 914 | 912 | 908 | 909 | 905 | 906 | 464 | 354 | 904 | 878 | 900 | 893 | 894 | 895 | 896 | 897 | 892 | 898 | 899 | 889 | 351 | 885 | 886 | 880 | 881 | 883 | 884 | 667 | 874 | 875 | 361 | 930 | 940 | 430 | 434 | 873 | 825 | 826 | 828 | 829 | 844 | 845 | 849 | 852 | 856 | 857 | 858 | 859 | 860 | 870 | 697 | 764 | 862 | 861 | 818 | 851 | 663 | 830 | 831 | 833 | 834 | 835 | 836 | 838 | 840 | 842 | 843 | 824 | 837 | 822 | 820 | 801 | 810 | 811 | 812 | 814 | 628 | 656 | 657 | 661 | 664 | 665 | 666 | 668 | 669 | 670 | 674 | 675 | 677 | 678 | 680 | 681 | 682 | 683 | 685 | 686 | 687 | 688 | 691 | 692 | 693 | 694 | 696 | 698 | 699 | 700 | 701 | 702 | 703 | 704 | 705 | 713 | 459 | 717 | 719 | 720 | 721 | 725 | 729 | 731 | 734 | 736 | 737 | 740 | 748 | 751 | 754 | 755 | 756 | 757 | 758 | 759 | 760 | 761 | 762 | 711 | 813 | 809 | 808 | 803 | 804 | 805 | 364 | 802 | 800 | 798 | 796 | 797 | 795 | 791 | 792 | 793 | 794 | 461 | 790 | 787 | 788 | 770 | 771 | 772 | 773 | 774 | 775 | 777 | 782 | 784 | 768 | 769 | 767 | 765 | 766 | 626 | 726 | 727 | 728 | 710 | 706 | 295 | 444 | 484 | 652 | 654 | 655 | 643 | 646 | 647 | 648 | 649 | 650 | 630 | 631 | 633 | 634 | 635 | 638 | 639 | 640 | 564 | 578 | 579 | 582 | 583 | 584 | 587 | 588 | 590 | 591 | 592 | 593 | 594 | 595 | 596 | 597 | 598 | 599 | 600 | 601 | 602 | 603 | 604 | 605 | 606 | 607 | 608 | 609 | 610 | 611 | 613 | 614 | 615 | 616 | 617 | 618 | 619 | 620 | 623 | 438 | 442 | 443 | 447 | 448 | 455 | 465 | 466 | 472 | 473 | 481 | 482 | 483 | 576 | 575 | 562 | 532 | 535 | 537 | 539 | 541 | 543 | 545 | 547 | 551 | 553 | 555 | 513 | 514 | 515 | 516 | 517 | 518 | 519 | 520 | 521 | 522 | 523 | 524 | 525 | 526 | 527 | 528 | 530 | 500 | 501 | 502 | 503 | 504 | 505 | 506 | 507 | 508 | 509 | 511 | 487 | 488 | 489 | 491 | 492 | 495 | 496 | 499 | 458 | 456 | 360 | 294 | 293 | 415 | 416 | 404 | 402 | 398 | 401 | 377 | 386 | 372 | 369 | 368 | 358 | 344 | 353 | 355 | 321 | 322 | 325 | 319 | 257 | 8 | 13 | 14 | 271 | 272 | 33 | 289 | 34 | 35 | 296 | 44 | 45 | 86 | 98 | 100 | 106 | 117 | 139 | 145 | 159 | 182 | 183 | 184 | 185 | 210 | 211 | 212 | 216 | 222 | 223 | 235 | 239 | 240 | 243 | 246 | 248 | 250 | 3587 | 3590 | 3160
Here is why Gillespie Borate crawls some glazes
This is a variation on the 50:30:20 cone 6 very fluid-melt pottery glaze recipe. I reduced the Gillespie Borate (GB) to 37% instead of the original 50% (thus bringing the B2O3 from 0.63 down to 0.5). My objective was to reduce the melt fluidity. But the crawling was so bad in this that it is almost unusable. The reason was not obvious until I fired a sample to 1550F and 1650F. At the former, the integrity of the glaze layer is great, but by 1650F it melts suddenly and does this. It is not difficult to see why these “puzzle pieces” with curled up edges might pull inward to create "glaze islands" characteristic of glaze crawling. This is happening even though the percentage of Gillespie Borate is lower. Not surprisingly, Ulexite mineral, which GB almost certainly contains, is also known for suddenly shrinking and melting.
I tried to solve another problem at the same time. GB is plastic on its own, and thus hardens the layer and suspends slurries well. Thus, the 15% kaolin in the recipe unnecessarily increases the drying shrinkage. So I substituted calcined kaolin. While it helped with that problem that was small consolation.
Related Pictures
Gerstley Borate vs. Gillespie Borate at 1550F (840C)
This picture has its own page with more detail, click here to see it.
The GLFL test ball of pure Gerstley Borate has shrunk and vitrified to a porcelain state here at 1550F (the ball is half the original size and gets even smaller by 1600F). Not surprisingly, Gerstley Borate has a significant LOI; it finishes off-gassing at about 1400F, which enables the high shrinkage that occurs between 1350 and 1600F. Gillespie Borate, on the other hand, is obviously here experiencing an overlap between the gassing and melting phases (it is already melting while gasses of decomposition are being expelled). That means that glazes having a high percentage of it are going to do this as they are heated through this range in a firing. It was not clear at first how this might affect glazes but it became evident later: Crawling and spitting.
Gillespie Borate is doing something very strange at 1700F
This picture has its own page with more detail, click here to see it.
On the left is G2826A3, a cone 6 transparent glaze (an improvement on the 50:30:20 classic Gerstley Borate base transparent recipe, substituting Gillespie Borate, reducing its percentage and increasing SiO2). Despite the improvements it exhibits this strange cracking and crawling. The G2826A1 on the right uses a frit to source the boron instead, clearly a better idea. These tiles were fired to 1700F. The problem is likely the ulexite mineral in the Gillespie Borate - it is known for this behavior of suddenly shrinking and then suddenly melting (the latter of which is just starting). Since Gillespie Borate is plastic and suspends slurries well, I thought calcined kaolin would be better than raw kaolin in the G2826A3 recipe (to minimize drying shrinkage). However, it did not improve the situation. All of this being said, this recipe is still working reasonably well at cone 6 (stopping and holding it at 1700F may exaggerate the problem).
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Gillespie Borate
A Gerstley Borate substitute that became available during the early 2000s and is still available in 2023. |
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