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A frit softens over a wide temperature range

Raw materials often have a specific melting temperature (or they melt quickly over a narrow temperature range). We can use the GLFL test to demonstrate the development of melt fluidity between a frit and a raw material. On the left we see five flows of boron Ferro Frit 3195, across 200 degrees F. Its melting pattern is slow and continuous: It starts flowing at 1550F (although it began to turn to a glass at 1500F) and is falling off the bottom of the runway by 1750F. The Gerstley Borate (GB), on the other hand, goes from no melting at 1600F to flowing off the bottom by 1625F! But GB has a complex melting pattern, there is more to its story. Notice the flow at 1625F is not transparent, that is because the Ulexite mineral within GB has melted but its Colemanite has not. Later, at 1700F, the Colemanite melts and the glass becomes transparent. Technicians call this melting behaviour "phase transition", that does not happen with the frit.

Melt flow tests showing the a frit melting from 1550-1750F, Gerstley Borate from 1600-1625F.

Links

Glossary Frit
Frits are used in ceramic glazes for a wide range of reasons. They are man-made materials of controlled chemistry with many advantages or raw materials.
Glossary Melting Temperature
The melting temperature of ceramic glazes is a product of many complex factors. The manner of melting can be a slow softening or a sudden liquifying.
Articles The Chemistry, Physics and Manufacturing of Glaze Frits
A detailed discussion of the oxides and their purposes, crystallization, phase separation, thermal expansion, solubility, opacity, matteness, batching, melting.
Articles What Determines a Glaze's Firing Temperature?
The oxides contributed by glaze materials determine its chemistry. The chemistry is the main factor determining melting behaviour. But the particle sizes, shapes and mineralogies also come in to play.
Tests Frit Fusibility Test
Oxides B2O3 - Boric Oxide
Materials Ferro Frit 3195
Materials Gerstley Borate
Temperatures Common frits begin melting (1400F-)

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