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Glossy blacks are best made adding a black stain to a quality base transparent

The glaze on the left is called Tenmoku Cone 6 (a popular, and old, CM recipe). It is 20% calcium carbonate, 35% Custer feldspar, 15% OM4 Ball Clay and 30% silica, 10% iron oxide. If you have any experience with glaze you will note two things that a fishy here: There is no boron, lithia or zinc sourcing material. How can this melt enough at cone 6? It looks melted, but the ease of scratching it shows it is not. So, it appears that if we saturate an incompletely melted glaze with a lot of refractory brown colorant on a dark body the effect can be black. A better idea is the glaze on the right. We start with a stable, reliable base transparent, G2926B. Then we add 5% Mason 6666 black stain (stains are smelted at high temperatures, quenched and ground, they are inert and relatively safe). A bonus is we end up with a slurry that is not nearly as messy to use and does not turn into a bucket of jelly.

Glossy blacks are best made adding a black stain to a quality base transparent

Related Pictures

Can a cone 6 functional glaze having only whiting and feldspar melt enough?

Tap picture for full size and resolution

This flow test compares the base and base-plus-iron version of a popular CM recipe called "Tenmoku Cone 6" (20% whiting, 35% Custer feldspar, 15% Ball Clay and 30% silica, 10% iron oxide). Although iron is not a flux in oxidation, it appears to be doing exactly that here (that flow is just bubbling its way down the runway, the white one also fires to a glassy surface on ware). It looks melted in the tray on the right but notice how easily it is scratching on the tile (lower left). This demonstrates that looks can be deceiving. Cone 6 functional glazes always have some percentage of a power flux (like boron, lithia, zinc), otherwise they just do not melt into a hard glass. Maybe a glaze looks melted, but it has poor durability.

Links

Glossary Glaze Durability
Ceramic glazes vary widely in their resistance to wear and leaching by acids and bases. The principle factors that determine durability are the glaze chemistry and firing temperature.
Glossary Melting Temperature
The melting temperature of ceramic glazes is a product of many complex factors. The manner of melting can be a slow softening or a sudden liquifying.
Glossary Mechanism
Identifying the mechanism of a ceramic glaze recipe is the key to moving adjusting it, fixing it, reverse engineering it, even avoiding it!

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