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An example of how calcium carbonate can cause blistering as it decomposes during firing. This is a cone 6 Ferro Frit 3249 based transparent (G2867) with 15% calcium carbonate added (there is no blistering without it). Calcium carbonate has a very high loss on ignition (LOI) and for this glaze, the gases of its decomposition are coming out at the wrong time. While there likely exists a firing schedule that takes this into account and could mature it to a perfect surface, the glaze is high in MgO, it has a high surface tension. That is likely enabling bubbles to form and hold better.
Low-fire glazes must be able to pass the bubbles they and the underlying bodies generate (or clouds of micro-bubbles will turn them white). This cone 04 flow tester makes it evident that 3825B has a higher melt fluidity (A has not even dripped onto the tile). And its higher surface tension is demonstrated by how the flow meets the runway at a perpendicular angle (it is also full of entrained micro-bubbles). Notice that A, by contrast, meanders down the runway, a broad, flat and relatively clear river. Low-fire glazes, for example, must pass many more bubbles than their high-temperature counterparts, the low surface tension of A aids that. A is Amaco LG-10. B is Crysanthos SG213 (Spectrum 700 behaves similarly, although flowing less). These two represent very different chemistry approaches to making a clear glaze. Which is better? Both have advantages and disadvantages - this property has implications, just not for bubble clouding, but on other issues involving glaze performance and even defects.
Glossary |
Decomposition
In ceramic manufacture, knowing about the how and when materials decompose during firing is important in production troubleshooting and optimization |
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Glossary |
Surface Tension
In ceramics, surface tension is discussed in two contexts: The glaze melt and the glaze suspension. In both, the quality of the glaze surface is impacted. |
Materials |
Calcium Carbonate
In ceramics, calcium carbonate is primarily a source of CaO in raw stoneware and porcelain glazes. |
Articles |
Firing: What Happens to Ceramic Ware in a Firing Kiln
Understanding more about changes taking place in the ware at each stage of a firing helps tune the curve and atmosphere to produce better ware |
Troubles |
Glaze Blisters
Questions and suggestions to help you reason out the real cause of ceramic glaze blistering and bubbling problems and work out a solution |
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