Click here for information about DIGITALFIRE Corporation

Monthly Tech-Tip from Tony Hansen

I will send practical posts like these (from thousands I maintain). No ads or tracking. We are troubleshooting the confirm email, for now you will be subscribed immediately (the first monthly email will provide one-click unsubscribe).


Blog

Mason stains in the G2934 matte base glaze at cone 6

Glazed porcelain tiles

Stains can work surprisingly well in matte base glazes like the DIY G2934 recipe. The glass is less transparent and so varying thicknesses do not produce as much variation in tint as glossy bases do. Notice how low many of the stain percentages are here, yet most of the colors are bright. We tested 6600, 6350, 6300, 6021 and 6404 overnight in lemon juice, they all passed leach-free. The 6385 is an error, it should be purple (that being said, do not use it, it is ugly in this base). And chrome-tin pink and maroon stains do not develop the color (e.g. 6006). But our G1214Z1 CaO-matte comes to the rescue, it both works better with some stains and has a more crystal matte surface. The degree-of-matteness of both can be tuned by cooling speed and blending in some G2926B glossy base. And it’s easy to turn any of these into brushing or dipping glazes.

Context: Mason 6021 Red Stain, G2934, Stains Mason, G1214Z1, 5 titanium dioxide in.., G2934 cone 6 DIY.., Mason stains in the.., Here is my setup.., Cone 6, Base Glaze, Ceramic Stain, Medium Temperature

Thursday 20th March 2025

Mason stains in the G2926B base glaze at cone 6

19 glazed porcelain tiles showcasing Mason stain colors

This glaze, G2926B, is our main glossy base recipe. Stains are a much better choice for coloring it than raw metal oxides. Other than the great colors they produce here, there are a number of things worth noticing. Stains are potent; the percentages needed are normally much less than for metal oxides. Staining a transparent glaze produces a transparent color, it is more intense where the laydown is thicker - this is often desirable in highlighting contours and designs. For pastel shades, add an opacifier (e.g. 5-10% Zircopax, more stain might be needed to maintain the color intensity). The chrome-tin maroon 6006 does not develop well in this base (alternatives are G2916F or G1214M). The 6020 manganese alumina pink is also not developing here (it is a body stain). Caution is required with inclusion stains (like #6021). Bubbling, as is happening here, is common - this can be mitigated by adding 1-2% Zircopax. And it’s easy to turn any of these into brushing or dipping glazes.

Context: Stains Mason, Mason 6021 Red Stain, G2926B, Concentrate on One Good.., Mason 6600 Black Stain, When using stains customize.., G2926B cone 6 transparent.., Mason stains in the.., Here is my setup.., Base Glaze, Ceramic Stain, Colorant, Cone 6, Medium Temperature

Thursday 20th March 2025

Gunmetal black mug demos liner glazing Safe glaze inside, decorative one outside

Mother Nature's porcelain black mug

The outside glaze is G2934Y cone 6 black. I use the C6DHSC slow cool firing schedule to get this degree of matteness in the black. The body is the natural MNP (Mother Nature's Porcelain), it vitrifies to zero porosity around cone 4 (yet is stable to cone 8). At cone 6 it produces incredibly strong ware and works well with these two glazes. The inside liner glaze is GA6-B (made using real Albany Slip rather than Alberta Slip in this case). Although the melt characteristics of these two glazes are so different they can be applied to meet in a perfect line at the rims of pieces. Food safety labelling is not what you think it is, do liner glazing to be safe.

Context: Albany Slip, Meet two glazes at.., Feeling good about the.., Liner Glazing

Thursday 20th March 2025

Shrinking glaze = peeling glaze

A glaze is peeling on drying

Dipping glazes peel like this because they contain clay and shrink as they dry (the fact that all of them don't do this is actually amazing). Success is a matter of the shrinkage being low enough, the drying being fast enough, the layer being thin enough, the bisque being absorbent enough, and the bond with the bisque being good enough. Glazes with high clay content, thick applications or multi-layering are the main offenders. Thixotropic slurries apply most evenly and are least likely to go on too thick. Dipping glazes having 15-20% kaolin or ball clay are easiest to slurry up and have the best application and drying properties. Mixing base layers as first-coat dipping glazes is also important.

The problem with this piece: The addition of 7.5% bentonite to make up for the otherwise low raw clay content in the recipe produced a recipe that does not pass a sanity check. When that was replaced with kaolin it worked. There is a crowbar approach to fix these without any other changes: Add CMC gum (e.g. 1%) to make them brushing glazes.

Context: Glaze Layering, Glaze peeling on drying..

Friday 14th March 2025

A potter fixes a leaching glaze problem

A potter fixes a leaching glaze

G1214Z1 is a popular cone 6 calcium matte glaze recipe. It has very high melt fluidity, enabling a fine grained crystalline matte surface to develop during cooling. A potter was steered to this recipe after finding that G2934 magnesia matte fired too variegated when stained blue. However, her first effort with this failed a leaching test. She had a secret weapon: An account at Insight-live.com, where recipes and their calculated oxide formulas can be compared side-by-side. Leaching glazes are most often runny because they contain excessive fluxing oxides. She simply increased the SiO2, it is the glass that makes up the lion's share of all glazes (higher amounts of it characterize glossy glazes). Al2O3 couples with it to improve durability (and the Si:Al ratio is a factor in the degree of matteness). With an accompanying small increase in the B2O3, the magic glass:flux that makes most cone 6 glazes possible, the got the result on the right. The good news: It passed the GLLE test for leaching. There is a lesson here: She had to compromise the degree of matteness a little to get the food safe product. A benefit is that it is also less prone to cutlery marking. Happily, it turned out that much less blue stain was needed.

Context: G1214Z1, G1214Z matte glaze melt..

Friday 7th March 2025

Testing a new brand of dolomite

Melt fluidity of high dolomite glaze

Dolomite is a key material for glazes, especially mattes. We were forced to adopt a new brand and needed confidence it was equivalent. Three tests were done to compare the old long-time-use material (IMASCO Sirdar) with a new one (LHoist Dolowhite). The first melt flow tester compares them in a very high dolomite cone 6 recipe formulated for this purpose; the new material runs just slightly more. The second tester is uses the G2934 cone 6 MgO matte recipe with 5% black stain; the new material runs a little less here. The third test is the high dolomite glaze on a dark burning clay to see the translucency and compare the surface character. They are very close. These three gave us the confidence to proceed.

Context: Dolomite, Glaze Melt Flow -.., Downloadable 3D model for.., Material Substitution, Melt Fluidity

Wednesday 5th March 2025

Melt fluidity differences are not obvious by just comparing glazed ware

The glaze on two porcelain mugs looks the same, but the melt flow is very different

These two Plainsman M370 test mugs were fired at cone 6, the left one with G2934 matte glaze, the right one with G2934Y4 matte. They look and feel identical in the hand. The two glazes have the same chemistry. But they employ different materials to source that chemistry. The secret of of the matteness is high MgO (magnesia content). In the glaze on the left MgO is sourced by dolomite, a lot of it. The glaze on the right sources it from a special frit, Ferro 3249. The impact of this difference is visible in the melt fluidity tester, the fritted one is melting and flowing much better. On other clays, especially stonewares, the G2934 can have a dry surface that cutlery marks. Thicker applications make it worse. But the Y version exhibits no such issues. Its mattness, durability, cleanability and hardness are so good that it is being used in floor tile.

Context: G2934Y, Downloadable 3D model for.., G2934Y variations for fired.., Melt Fluidity

Tuesday 4th March 2025

This flow tester indicates copper is not fluxing or bubbling this glaze

Copper carbonate fluxing testing

These cone 6 glazes are the same (G3806G), except the one on the right has 3.5% copper carbonate added. Copper is commonly fluxes glazes, making them melt more. But in this case it is not, the clear base is running just as much as the stained one. Either the percentage is not high enough or the host transparent glaze is resistant. Another observation: I was suspicious that the micro-bubbles in the glass matrix were coming from the copper carbonate gassing during firing. But not so, as you can see on this melt fluidity tester, the flow on the left has many more (it appears less melted because of this). In this specific glaze it seems probable that the copper bubbles (generated as it decomposes) act as a fining agent to coagulate and help clear the others.

Context: Copper Carbonate, Melt Fluidity

Tuesday 4th March 2025

3D-printing artifacts on a slip cast M370C bottle. A problem?

3D printing artifacts on slipcast ceramic bottles

Here is why the stair-casing artifacts are not the problem many people think. These are stonewares fired at cone 6 oxidation. The dark one is M370C with 10% added raw umber. The other is M370C. Both are glazed using GA6-B Alberta Slip amber transparent. The wood-grain texture on the right is an artifact of 3D-printing - the case mold was printed flat rather than upright. Strangely, that is the bottle people want! But the production prototype bottle is the one on the left and the stair casing is barely visible. Additionally, these are prototypes, the production molds would either be made by printing the model upright or by casting a plaster model of a bottle half, smoothing and soaping it, attaching it to a clamping baseplate and then setting up 3D printed railing around it.

Context: GA6-B, This GA6-B glaze is.., 3D printing artifacts on.., 3DP

Thursday 27th February 2025

Rutile blue cone 6 glaze: Fast vs slow cool firing

Rutile blue glaze cooled fast and slow

Same clay body: Plainsman Coffee Clay. Same glaze: MA6-C rutile blue. But the mug on the left was fired in the PLC6DS schedule (normally that one does not produce this much blue, but the heavily pigmented clay brings it out). The one on the right was fired in the C6DHSC schedule. That schedule also improves the gloss and surface quality of the inside GA6-B liner glaze.

Context: Titanium instead of rutile.., Plainsman Cone 6 Slow..

Wednesday 26th February 2025

Contact Me

Use the contact form at the bottom on almost all the pages on this site or let's have a together.

Other ways to Support My Work

Subscribe to Insight-Live.com. It is about doing testing and development, not letting the information slip away. Starts at $15 for 6 months.

Help Me on Social

Tony Hansen
Follow me on

Test, Document, Learn, Repeat in your account at insight-live.com

Login to your online account

Chemistry plus physics. Maintain your recipes, test results, firing schedules, pictures, materials, projects, etc. Access your data from any connected device. Import desktop Insight data (and of other products). Group accounts for industry and education. Private accounts for potters. Get started.

Conquer the Glaze Dragon With Digitalfire Reference info and software

Download for Mac, PC, Linux

Interactive glaze chemistry for the desktop. Free (no longer in development but still maintained, M1 Mac version now available). Download here or in the Files panel within your Insight-live.com account.


What people have said about Digitalfire

  • I have visited your website for many years to get ceramic information - your website is excellent ... Thanks again for all the great info on your website - hopefully one day I can repay you for your outstanding resourse.
  • First of all I'd like to congratulate you for the incredible source of information and Guidelines in your website. We are changing our fast-firing process (cold to cold in 4.5 hours) to a slow-firing process (cold to cold in 24.0 hours) and all our glaze formulas have lost their acid resistant characteristic, after dipping in 24 hrs at Ph1.3.
  • Hi Tony, First, your website is the most knowledgeable and accurate information available on the internet today. THANK-YOU!
  • Great site btw. Besides getting married its the next best thing I did.
  • Ceramicmaterials.info is a fantastic resource!
  • High marks for the web site!
  • I cannot express how refreshing it is to no longer be dependent on textbook recipes.

What people have said about Insight-Live

  • The program is brilliant and I am thoroughly enjoying it!
  • I am a ceramic manufacturing manager, and before this position, I had no training on ceramics. I was taught our recipes, but none of it was explained. The dragon ran amok. After reading through your articles and descriptions, I feel I have learned so much about my own products, and I have a foundation for changing, improving, and troubleshooting my materials issues that I wouldn't have had otherwise. They taught us in engineering school that we all stand on the shoulders of giants, because we all get to use knowledge and tools at a moment's notice that took others years to develop. Thank you for sharing all that you have, so the rest of us can stand on your shoulders to do our work that much better.
  • Brilliant!
  • I take this opportunity to appreciate your efforts in sharing all the information related to ceramics on the Digital Fire website. It is really helpful. I am from India. We work towards reducing mining for natural resources by 60% through making (fired) recycled ceramic products.
  • Also thank you for the quality of your website, I've learned so much from it.
  • When it comes to new technology, I'm still thrilled with the chainsaw as apposed to an ax. I really do like glaze testing. You see a recipe in a book but it doesn't do you a lot of good until you can see it on a tile.
  • Your work is so thorough and helpful Tony. When I read your articles I suddenly feel I know nothing, despite working professionally with ceramics since 1997!



https://digitalfire.com, All Rights Reserved
Privacy Policy

1