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Chemistry plus physics.
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What people have said about Digitalfire- Thank you for all the wonderful work you do for the ceramic community.
- I've read it cover to cover (and some sections two or three times) and I wish more than ever that I had read it before the eighteen months of mixing and testing that I've done.
- Great site you have here, I am the ceramics tech at the University of .. the info. on your site is a great help to my students.
- This is a fantastic source of on-line information. Thank you for permitting me to access the contents.
- After perusing your site for some time, I am really getting the sense of what a valuable resource it is. Thank you for it.
- Thank you for your wonderful site i am new to home made glazes and am teaching myself... your site is so help full thank you.
- I have a background in Geology (BS-1973-New Mexico Tech), and with a few other degrees here and there - and have been doing quite a bit of Pythoning, and hanging-around my wife who does (I think (but then, of COURSE I am biased)) terrific pots... I am always interested in what she does with glazes (especially when I see the mineral-names from my Geology days on the bins in her studio... BUT - as an "engineer", sometimes I want 'more' knowledge - and I find your web-site VERY VERY good at that, it tells me a lot of things - gives me 'value added' and 'information' that I haven't found elsewhere! Especially when I think about 'geo-chem'.
- I love your site and am so grateful for all you have done to help with
glaze formulation/safety.
- Your advice is always helpful and well thought out.
- Go look at Tony Hansens page and look at Insite. Incredible amounts of information. He has a great explanation of .. Shivering ---and the opposite----- Crazing. Cause and solution.
What people have said about Insight-Live- You have done a remarkable job of collecting and compiling useful information regarding ceramic science and technology. Thanks for what you have done and continue doing.
- We appreciate you and your website so much!
- Thank you so much for this site and all the information. It's such a gift to have a reliable, authoritative source of information.
- You are really doing the lords work!
- Thank you for all you have done for the ceramics community, your reference pages are the first place I go when I have questions.
I also really appreciate you being available to help me.
- I just wanted to say, thank you! I’m relatively new to pottery, taking a mostly self-taught approach and I’m at the stage where glazing is in my mind. I don’t want to be (and can’t see myself ever) buying glazes from commercial suppliers. I want to learn my craft with glaze as much as I do with my clay preparation and pottery making. I’ve seen “the dragon” and been uninspired by so much of what I find online and to be honest, in many glaze books. It seems more popular to try and present a mass of glaze possibilities than to offer a learning experience beyond being told a glaze needs a melter, a refractory and a glass-maker. Enough to offer a very basic understanding, but nothing upon which to build the understanding that will allow some degree of mastery (or at least influence) of your glaze making.
I am so pleased to have found digitalfire.com. You’ve shown me exactly how to approach and understand glazing, giving me the foundation for approach I sought. I was thinking of base glazes and what you’ve shown me about working on from those is fantastic and exactly what I was looking for. To have a reliable base glaze to modify and develop to meet different needs; to understand how to shift a melting point or adjust the surface gloss; to come to know how the mechanisms in a glaze and understanding them gives me the route to creating glazes that realize my intentions - wow!
I can’t thank you enough. Rather than having to form a dumb reliance on a book of recipe cards and a bunch of website bookmarks (which I wasn’t wanting to go for) you’ve given me the foundation for a lifelong development and understanding of the glazes I will make, that will become “my” glazes. You have really opened my mind to the whole subject and it doesn’t seem to be a problem that I’m no scientist or chemist. You’ve shared your knowledge in a way that is completely approachable and remarkably easy to understand for someone without any kind of science/chemistry background.
- Thanks Tony. You are offering a very valuable service to the potters.
- I think you have done a great job in developing the on-line version. It is very easy to use. We meet once a month to discuss any glaze problems, test glazes in teams, and I do a presentation on an aspect of glaze chemistry. One day, I said something technical and one of the member's jaw dropped and she said "Hey, I just realized I understood what you said". It was a proud moment.
- Love Insight-live. Have been using it a few months and now that I know my way around a bit, I have come to rely on it. Love having a web based program, since I bounce between Windows on several machines and also a Chromebook.
- Anyway I thank you for your efforts in putting together this wealth of ceramic science in this accessible manner.
| Digitalfire will shut down on June 26. I no longer have the authority to grant exemption to a section in the Terms and Conditions of using material in the Insight-Live account from which I built the source material. While there are ways to comply with the take-down order, they are beyond my means because of how complex and large the site has become in the past 35+ years. It has been a wild ride for a shy prairie boy, thanks to everyone for your support. I will send practical posts like these (from thousands I maintain). No ads or tracking. The first email will provide one-click unsubscribe. Signup is being email-bombed by bots. For now, please subscribe inside your insight-live.com account.
Blog
Same body, same outside glaze.
But the inside transparent glaze is different
Glazing black clay bodies stained with manganese is just about impossible with typical transparent glazes. The glaze over-fluxes the clay surface and ruins the color. Worse, if it accelerates surface maturity, the body can blister or generate LOI gases that blister the glaze. How about transparent glazes over a black engobe instead? At least the body color is not lost. But the wrong transparent glaze can do what you see here (inside left).
These mugs are a buff stoneware, Plainsman M340. A black engobe was applied by pouring the inside and dipping the outside two-thirds of the way down.
Left: A L3954F black engobe was applied inside and upper exterior at leather hard. After firing to cone 6 using the PLC6DS schedule, G2926B—which is crystal clear on M340 itself—became completely clouded over the engobe because bubbles generated during firing remained trapped in the melt.
Right: The entire mug was dipped in GA6-B. The Alberta Slip particles and the melt characteristics of GA6-B promote bubble coalescence and escape, producing an exceptionally glossy jet-black surface over the same engobe.
Monday 8th June 2026
Here is what dipping engobes can do:
Go on even. In one coat. Stay put.
When you learn to make and use engobes correctly, they make magic possible. Here I am turning a dark rustic body into a smooth white one (rear mugs) and a white body into a dark one (front). The engobes have been applied at the leather-hard stage. That is the perfect time, the engobe and body are clay bodies, designed to fit each other; they dry together and fire together creating an inseparable bond.
Handles have been applied, and they have dried to stiff leather hard. Engobe was poured in, poured out, then the mugs were pressed, lip down, into it and extracted. No dwell time was needed. This dipping engobe is DIY thixotropic (not available commercially anywhere). That means I tuned it just before use, to just the right degree of gel (enough for it to drain to the right thickness, then gel just as the last few drops fall from the rim). Honestly, these are a beauty to behold at this stage, the silky, drip-free surface is just so perfect.
Context: L3954B, How stop dripping and.., Here s how I.., Why your supplier does.., Why your supplier does..
Monday 8th June 2026
No glaze chemistry needed
At least not right away
You have 147 glaze recipes. How can you get your head around all of them? Is glaze chemistry needed? No, that's a "maybe" way in the future. Right now, you need to start organized documentation. The recipe for each. A few pictures of each fired on different clay bodies, different thicknesses. Perhaps slow and fast-cooled firing. This is what an account at Insight-live does well. What it does even better is tracking your testing. The first step is to assign each recipe a proper code number (replacing these) and write that on all test specimens and buckets. From this point on, learn. Record every observation you make about each in its notes.
Through all of this, constant use in the studio (or factory) will never stop surfacing problems (e.g. settling in the bucket, crazing, running, blistering, material issues, etc.). The seriousness of each will determine the level of attack. First, identify the mechanism of the desired fired result. If it is a base recipe plus additions of colorants, opacifiers or variegators, then check if the base of one of the other glazes has a similar surface texture and character. If so, then could the additives in the troublesome one be used with the better base? If not, then it's time to sanity check the recipe and bring out the heavy guns of at least looking at the chemistry. But in Insight-live, you only need to turn on the display of the unity formula (there is nothing else to do). Next, make sure each material in the recipe links to one in the material database (so the calculated formula is accurate). Then compare the calculated unity formula with a limit formula (often a simple sanity check, like with the recipe, quickly spots oxides that are in excess or are short.
Thursday 4th June 2026
A transparent glaze is going satin:
Is it the feldspar and kaolin substitutions?
A potter reports that a switch from G-200 feldspar to Mahavir, and EPK to Imerys kaolin, has resulted in this transparent glaze becoming more satin. Is that possible? Yes. Because this glaze is on a unity formula tipping point.
To see it, you do not need to know how to do glaze chemistry, just how to display the calculated unity formulas side-by-side. My Insight-live shows them here. The material change has little effect. But there is an anomaly: 0.29 MgO. That is magnesia matte territory. The MgO is very likely there to help bring the thermal expansion as low as possible (to avoid crazing). For people who cool their kilns relatively quickly, this fires glossy. But a material change could well affect the cooling rate needed to maintain the gloss. That being said, the potter may also be firing slower, yet attributing the mattness to the materials. Or it could be a combination of both.
This is a popular glaze, among others in the book "Mastering Glazes". In Ron Roy's circumstances, and for many others, it is glossy. But for this potter, a small change (in the recipe materials and also likely in firing) has produced this issue.
Context: MGBase3, Tipping point
Thursday 4th June 2026
Alberta Slip as a functional honey-transparent base:
The glaze I reach for again and again
Are glazes food safe just because they carry a label?
This Gemini-generated mug could conceivably exist yet carry these labels. Yet experienced ceramic technicians would immediately be suspicious. The glaze is highly fluid and heavily crystallized; both suggest low or very low Al2O3 levels (it is the key oxide that makes glazes durable). If the interior color were produced using a cadmium-containing encapsulated stain, cadmium-release testing would be essential before claiming the ware is food safe. This is clearly engineered for visual effects rather than durability. None of those characteristics prove it is unsafe, but they do mean that labels like "nontoxic" are not substitutes for actual leach testing. A glaze can be made entirely from materials classified as nontoxic and still fail to meet the durability standards expected of functional foodware.
Context: Commercial glazes on decorative.., ASTM D-4236 - Standard..
Thursday 4th June 2026
Should I glaze the outside of this mug now? No!
This bisque mug has been glazed on the inside. But the bisque has absorbed water from that glaze, and this thin-walled mug is now waterlogged as a result (except at the thicker base). It does not have the absorbency needed to build up a thick enough layer of glaze on the outside. Even if it did, the water from the two glazes would wet the bisque so much that its drying time would be greatly extended. This is a problem because the mechanism of attachment of glaze to the body is fragile and works best when the glaze dries quickly. When drying is too very slow, bubbling and cracking often occur (leading to crawling in the firing).
Context: Does bisque ware need.., Glaze thickness
Monday 1st June 2026
Yixing teapot making. Is it magic?
Or highly evolved craft and science?
The Yixing teapot craftsmen appear to break all the rules and yet produce impossibly delicate and symmetrical pieces. Hao-Tong Yan, one of those craftsmen, and I have been trying to understand the technical reasons for how this amazing craft is possible. It turns out not to be magic, but actually a highly evolved understanding of a very unusual material. Here are some of the things that we are coming to understand (which is making it possible to create a facsimile of the clay in North America).
-The Yixing ore can have the appearance of being like rocks, yet they make a workable clay body from it.
-The clay appears highly plastic yet is not; the workability is coming from surprising places.
-The clay is stiff enough to resist deformation, yet is cohesive enough to join seamlessly.
-Craftsmen flatten the clay with a mallet, instead of rolling it, yet it does not stick to the board.
-Sections are simply glued with slip, yet they hold.
-The clay burnishes, yet is not smooth.
-Fired ware is smooth, yet the soft clay appears sandy.
-The fired surface is glossy, yet there is no glaze.
-The fired clay appears super dense yet does have porosity.
Context: Yixing Clay Teapots on.., Stunning video of Yixing..
Saturday 30th May 2026
2026: ChatGPT is doing credible troubleshooting
I uploaded a screenshot of this recipe panel from Insight-live and asked ChatGPT why sanitaryware using this glaze is dunting. Its response is impressive, good enough to provide remediation ideas.
-It notes things about the recipe that are unusual. For example, that the Al2O3 of 0.69 and Si:Al only 4:1, plus 13% calcined alumina, make this glaze more like a refractory enamel than a normal glaze.
-Its observation that crystallization could mean the real thermal expansion may be different from the calculated one, maybe much lower.
-Barium carbonate decomposition does not seem like something that would contribute to dunting, but its presence is strange for such a glaze.
Based on its answer, I think the 13% calcined alumina is the wild card, which is way too much for any glaze to dissolve, something to deal with first.
Context: ChatGPT was completely wrong.., ChatGPT is surprisingly wrong.., Two ChatBots square off.., Does ChatGPT know the.., Sanitary ware
Tuesday 26th May 2026
Crystalline glazes normally craze:
Here is one way to fix that
The mug on the left, made by Holly McKeen, is a typical cone 10 Grolleg kaolin mullite porcelain (highly vitrified, low in residual quartz). Its glaze is crazed. Crystalline glazes are high in Na2O, making crazing virtually certain. Since most pieces are decorative, crystal glazers just accept this as part of the process. But these are functional mugs, the glaze needs to fit (if only for ware strength).
But what if the thermal expansion of the body could be significantly raised? The body on the right is Crystal Ice, it contains 40% silica (vs 20-25% in a typical porcelain). The percentage of Nepheline has been reduced, lowering vitrification to about 1.5% porosity. As a result, more quartz survives undissolved and less mullite develops, raising the body’s thermal expansion. The result is a body with a much higher thermal expansion, so it can not only relieve the glaze tension but actually put a squeeze on it. There is a downside: These are less resistant to dunting and thermal shock failure during use.
Could the glaze be adjusted instead? Yes. Some of the Na2O could be substituted for Li2O, the latter is also a strong melter but has a much lower thermal expansion. Glaze chemistry could be used to source it from Spodumene (to avoid solubility issues with lithium carbonate). However, zinc-silicate crystalline glazes are very sensitive systems, so the more lithia is introduced the more likely the effect on the firing window, crystal size/density and background clarity.
Context: Crystalline glazes, Calculated Thermal Expansion
Tuesday 26th May 2026
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