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Ask the right questions to analyse the real cause of glaze crazing. Do not just treat the symptoms, the real cause is thermal expansion mismatch with the body.
The fired glaze exhibits a network of fine cracks. These may be visible after firing or may need enhancement with ink. Crazing may also appear after some time or after ware has been exposed to thermal shock.
Crazing profoundly affects ware strength. Ceramics are brittle, when cracks start they propagate, especially in vitreous ware. Crazed ware, out of the kiln, is thus pre-cracked and ready to fail. This is an inherent weakness because the cracks provide failure initiation sites, when ware is subjected to stress they jump into action. The author has measured 300-400% reductions in the strength of freshly fired ware with crazed glazes. A cone 01 piece having a well-fitted glaze will be stronger than a cone 10 one with a poorly fitted glaze!
The chemistry profile that creates the most crazing can also be inherently more leachable (e.g. the high KNaO and very low Al2O3 common in crackle glazes make them susceptible to leaching of added metallic colorants).
If the clay under a crazing glaze is porous and soaks up water then safety could also be a concern. The cracks and their access to a possibly porous body below can create a bacteria zoo, requiring extra care in cleaning and sterilizing ware. Containers used to store food are a special concern since a small colony in a crack can become a large culture in the food. If you have any doubt whether this is an important issue ask a commercial food service inspector about the subject. Consider also that the chemistry profile that creates the most crazing is also inherently more leachable (e.g. the high KNaO and very low Al2O3). While most crazed glazes are white or clear, it is common in crackle to add metallic colorants to them, these would be released into food and drink.
This is by far the most common cause of crazing and solution strategies are case studies in glaze chemistry. Often by just looking at a recipe it is obvious it will craze (because it violates common sense recipe limits). Fired ceramic expands and contracts as it is heated. If the fired glaze has a significantly higher coefficient of expansion than the body then no amount of careful firing or thin glazing will avoid the inevitable crazing. If even only one piece crazes (assuming it has reached maturity) it is often a sign that all the other ware in that kiln will eventually craze. Such glazes usually need drastic changes since crazing is a visible manifestation of a fit problem that has already greatly reduced ware strength. Lower temperatures are more sensitive in this respect - there is a narrower range within which a glaze and body will be compatible.
Options to improve glaze fit that do not involve knowing about chemistry.
Glaze thermal expansion is a product of its chemistry (provided it is completely melted). So being able to do the chemistry enables employing by far the most effective method to adjust expansion:
Consider also the elasticity of the glaze as even relatively well-fitted ones can craze if exposed to radical temperature changes. High levels of sodium, potassium and calcium can make the glaze more brittle (the former also increase thermal expansion). Boric oxide is known to improve elasticity.
If the body expansion is too low (i.e. ovenware and flameware bodies) it can be very difficult to fit a glaze that has the desired visual characteristics. Lithium can dramatically reduce the thermal expansion of glazes, but its use requires a lot of testing since its contribution is not linear and it introduces other dynamics that must be considered.
If you are cooling your kiln very slowly to prevent ware from crazing it is likely the glaze does not fit. While it may be true that slower firing seems to solve the problem, time will bring out the crazing that the kiln did not. In fact, if you must slow cool to prevent crazing it is a virtual certainty that your glaze needs to have its thermal expansion reduced.
Generally increased additions of iron and copper oxide to a glaze will reduce crazing (e.g. beyond 1 or 2 percent). Cobalt could have a moderate lowering effect, but since so little is typically used in glazes it will not be significant.
Underfired low-temperature bodies may contain uncombined alkali or alkaline earths that can react with water and cause the body to expand slightly. Check if crazing occurs in a glazed sample after several hours in a pressure cooker (or put a shard into an autoclave). Calcium carbonate is added to talc bodies to minimize moisture expansion. To avoid this it is best to leave a minimum of unglazed body surface and plug that with silicone sealant. Body formulations also often include a small percentage of calcium carbonate which is said to help prevent this phenomenon. Porcelain bodies also often craze glazes if not vitrified enough.
Normally a glaze/body combination with compatible expansion characteristics will withstand considerable firing and usage abuse without displaying signs of crazing. However, in some cases, a glaze that otherwise 'fits' will craze if applied very thick.
Also, if the kiln is cooled very quickly or unevenly, especially if ware is thicker, the severe stresses can produce crazing. However, remember that a glaze's ability to withstand normal or even quick kiln cooling is an indicator of its ability to resist crazing in normal use.
If pieces must survive considerable thermal shock during use, then both ware and glaze need to have a low and linear thermal expansion curve and they must be compatible. This is difficult to achieve in low-fire ware because little mullite or other low-expansion silicate minerals develop during firing. If your low-fire body contains significant talc, reduce or eliminate it (also adjust glazes to have a lower expansion so they continue to fit the body). If your high-fire body develops non-linear expanding cristobalite during firing, find a way to reduce this.
High-temperature firing is by far the best for the production of low-expansion ware. Many more minerals are available for both body and glaze mixes and higher temperatures produce low-expansion silicates and aluminates that give tough glaze and body matrixes capable of withstanding forces that might otherwise cause crazing.
The left glaze is "stretched" on the clay so it cracks (it calculates to a high thermal expansion so this is not a surprise). This usually appears after firing but can appear years later. When the lines are close together like this it is more serious. If the effect is intended, it is called "crackle" (but no one would intend this on functional ware). The one on the left calculates much lower - and stays uncrazed indefinitely. Potters, hobbyists and artists invariably bump into this issue whether using commercial glazes or making their own.
"Art language" solutions don't work, at least some technical words are needed to even understand what this simply is: A mismatch in the thermal expansions of glaze and body. Most ceramics expand slightly on heating and contract on cooling. Even though the amount of change is very small, ceramics are brittle so if a glaze is stretched on the ware, it will crack to relieve the stress. Crazing appears when ceramic is cooled and the glaze contracts more than the clay to which it is rigidly attached.
The side of this white porcelain test mug is glazed with varying thicknesses of V.C. 71 (a popular silky matte used by potters), then fired to cone 6. Out of the kiln, there was no crazing, and it felt silky and wonderful. But after a 300F/icewater IWCT this happened (it was felt-pen marked and cleaned with acetone). The glaze was apparently elastic enough to handle the gradual cooling in the kiln. However, the recipe has 40% feldspar and low Al2O3 and SiO2, in a cone 6 glaze these are red flags for crazing.
No matter what anyone tells you, glaze fit can rarely be fixed by firing differently (that just delays it). If someone needs to cool their kiln slowly to prevent crazing it simply means the glaze does not fit - its needs to be adjusted to reduce its co-efficient of thermal expansion.
Crazing is a disaster for a production potter. Consider what one said: "I have just recently been contacted by a customer due to small lines in her bowl. I am now terrified residual crazing could be happening to lots of functional pieces I have sold! Nightmare! I have a terrible feeling in my stomach. Could anyone tell me if it is the glaze and if there is anything I can do to alter the recipe?" Don’t let this happen to you. Commercial brushing and dipping glazes are just as likely to craze as ones you mix.
Today, ChatGPT is parroting common wrong suggestions about the cause and solution of the serious issue of crazing. Yet it trained on thousands of internet pages about the subject! Crazed functional ware is defective, and customers will return it. So fixing the problem is serious business, we need correct answers. Consider ChatGPT's suggestions: #1 is wrong. There is no such thing as an "incompatible mix" of ceramic materials. Crazing is an incompatibility in thermal expansions of glaze and body, almost always a result of excessive levels of high-expansion K2O and Na2O in the chemistry of the glaze. The solution is reducing them in favor of other fluxes (the amount per the degree of COE mismatch). #2 is wrong, firing changes don't fix the incompatibility of thermal expansions. #3 is wrong, refiring makes the crazing go away but not the stress of the mismatch, it will for sure return. #4 is completely wrong. Firing higher takes more quartz grains into solution in the melt and should reduce the COE (and mature the body more which often improves fit). And melt fluidity has nothing to do with crazing. Furthermore, if a glaze does not run off the ware, it is not overfired.
This reduction celadon is crazing. Why? High feldspar. Feldspar supplies the oxides K2O and Na2O, they contribute the brilliant gloss and great color but the price is very high thermal expansion. Scores of recipes being traded online are high-feldspar, some more than 50%! There are ways to tolerate the high expansion of KNaO, but the vast majority are crazing on all but high quartz bodies. Crazing is a plague for potters. Ware strength suffers dramatically, pieces leak, the glaze can harbor bacteria and customers return pieces. The simplest fix is to transplant the color and opacity mechanism into a better transparent, one that fits your ware (in this glaze, for example, the mechanism is simply an iron addition). Fixing the recipe may also be practical. A 2:1 mix of silica:kaolin has the same Si:Al ratio as most glossy glazes, this glaze could possibly tolerate 10% of that. That would reduce running, improve fit and increase durability. Failing that, the next step is to substitute some of the high-expansion KNaO, the flux, for the low-expansion MgO, that requires doing some glaze chemistry.
These were applied to the bisque as a slurry (suspended by gelling with powdered or dissolved Epsom salts). On the left is Custer feldspar, the right is Covia Nepheline Syenite. Notice the crazing (feldspars, and nepheline syenite, always craze because they are high in K2O and Na2O, these oxides have by far the highest thermal expansions).
Wrong. This cone 10R grey stoneware, H550, is OK if the glaze fits. But this high feldspar glaze on the inside has begun to craze after a year. The greyer coloration around the craze lines indicates that water is soaking into the slightly porous body. And, this mug has lost the ring it had out of the kiln. Imagine your customers returning these pieces! Could they be refired to be as good as new? Perhaps. But they would return to this condition. The practical solution is to reformulate this glaze to reduce its thermal expansion.
Pure MinSpar feldspar fired at cone 6 on Plainsman M370 porcelain. Although it is melting, the crazing is extreme! And expected. Feldspars contain a high percentage of K2O and Na2O (KNaO), these two oxides have the highest thermal expansion of any oxide. By far! Thus, glazes high in feldspar (e.g. 50%) are likely to craze. Using a little glaze chemistry, it is often possible to substitute some of the KNaO for another fluxing oxide having a lower thermal expansion.
The clear glaze on this cone 03 mug survived a 300F-to-ice-water thermal shock without crazing (IWCT test). However, in the process, water was absorbed by the bare foot ring and dispersed into the porous matrix of the lower part of the mug. Moisture expansion occurred as a result and produced the crazing. Over continued use (and rewetting of the base) the entire piece would eventually craze. Calcium carbonate is often added to low fire bodies to prevent this expansion.
These are glazed test bars of two fritted white clay bodies fired at cone 03. The difference: The one on the right contains 13% 200 mesh quartz, the one on the left substitutes that for 13% 200 mesh calcined alumina. Quartz has the highest thermal expansion of any traditional ceramic material. As a result the alumina body does not "squeeze" the glaze (put it under some compression). The result is crazing. There is one other big difference: The silica body has 3% porosity at cone 03, the alumina one has 10%!
Why did the glaze on the tile craze? It is double the thickness of the walls of the mug. Thus, when quenched in ice water (BWIW test), a greater gradient occurs between the hot interior of the clay and the rapidly cooling surface.
This Cone 10 matte mug has been refired to attach decals. The fired matrix of the body is now brittle and dense and contains millions of quartz grains of many sizes. During the refire up through quartz and cristobalite inversions each of them experiences sudden volume increases. This does not happen in the glaze because its quartz particles were dissolved in the melt and converted to silicates during the previous glaze firing. The suddenness of the expansion depends on the rate of temperature increase and its extent depends on the size of the quartz particles. The body's passage through these two zones stretched the glaze and cracked it. Had the glaze fit been better (under some compression) it would likely have been able to survive.
The stoneware is made from sedimentary clays mined in a in southwestern Saskatchewan quarry, they have a higher quartz grain content and enough natural feldspar to produce functional density (the practical porosity is about 2.5%). The porcelain on the right is a 45:35:20 kaolin:feldspar:silica blend (there is enough feldspar for about 0.5% porosity). The stoneware has more quartz particles to impose their high thermal expansion because fewer are taken into solution by the feldspar. That means that the body has a whole can put the squeeze on the glaze to prevent it from crazing.
This is an example of serious crazing in a glaze. The lines have gotten darker with use of the bowl! That means the color is organic, from food. This cannot be healthy.
These are Amaco bottled glazes, a transparent and a decorative on a porcelain at cone 6. The glaze fit is poor, severely weakening the piece. I tapped this lightly with a spoon about 2 cm below the rim. It sounded like I was hitting a wet sack of rocks! And the handle fell off! Another few taps and the piece broke like auto-glass. This type of functional ware is entirely unacceptable. The IWCT test, which anyone can do, can help assess the risk.
If you buy commercial bottled brushing glazes then there is nothing you can do to adjust the recipe. When they fit a clay body (without crazing) it is just by accident (since the clay body and glaze manufacturer do not cooperate to ensure fit). Unfortunately, it is common for them to craze.
These two glazes look the same, they are both cone 6 satin mattes. On the same porcelain. But the matteness "mechanism" of the one on the left, VC71, is a low Si:Al ratio melted by zinc and sodium. The mechanism of the one on the right, G2934, is high MgO melted by enough boron to also have plenty of SiO2 and Al2O3. The "baggage" of the mechanism on the left is high thermal expansion and crazing (drastically reducing strength and providing a space for a germ zoo). If your ware develops this your customers will bring it back for replacement. No change in firing will fix this, the body and glaze are not expansion compatible. Period.
Crazing in glazes is common in this type of ware but since the body is fired well into vitrification this is not considered a problem (the unique aesthetics of this type of ware trump such issues). Salt glazes, by their very nature, are high in sodium. Since Na2O has such high thermal expansion pieces are almost guaranteed to craze. This was from kiln at the Medalta artist in residence program
Why? Firing temperature, schedule and atmosphere affect the result. Dilatometers are only useful when manufacturers monitor bodies AND glazes over time and in the same firing conditions. Calculated values for glazes are only relative (not absolute). The best way to fit glazes to your clay bodies is by testing, evaluation, adjustment and retesting. For example, if a glaze crazes, adjust its recipe to bring the expansion down (your account at Insight-live has the tools and guides to do this). Then fire a glazed piece and thermal stress it (300F-to-ice-water IWCT test). If it still crazes, move it further. If you have a base glossy glaze that fits (and made of the same materials), try comparing its calculated expansion as a guide. Can you calculate body expansion from oxide chemistry? Definitely not, because bodies do not melt.
Cone 6 transparent glaze testing to fit Plainsman M370: Left and right: Perkins Studio Clear. The far left one is a very thick application. Center: Kittens Clear. The porcelain for all is Plainsman P300. Why? Because P300 is much more likely to craze the glaze because it has a lower silica content (about 17% and only kaolin whereas M370 has 24% silica plus the free quartz that comes with the 20% ball clay it also contains). If a thick layer works on P300 it is a shoe-in to fit M370. If it also passes the oven:icewater test.
This is severe crazing (at cone 10R). It is happening because of the chemistry of the glaze, not the firing. The first option to check when fixing crazing is: Can the glaze accept an addition of SiO2? This glaze is an excellent candidate for that because the melt is highly fluid, it will surely be able to dissolve extra SiO2. But it could also accept Al2O3 because it is highly glossy (a little extra Al2O3 will not matte it and would also reduce expansion and increase fired hardness and durability). What to do then? I would start with a 10% addition of a mix of two parts silica to one part kaolin (this mix has a 10:1 SiO2:Al2O3 ratio, about the same as most glossy glazes).
G2926B (center and right) is a clear cone 6 glaze created by simply adding 10% silica to Perkins Studio clear (a glaze that had a slight tendency delay-craze on common porcelains we use). Amazingly that glaze tolerated the silica addition very well, continuing to fire to an ultra gloss crystal clear. That change eliminated the crazing issues on most of our bodies. The cup on the right is one of them, that body is vitreous, near-zero-porosity, and fits most glazes. Why? Because it has 24% silica in the recipe. The center porcelain is also dense and vitreous, but it only has 17% silica, that is why it is crazing this glaze. Then I added 5% more silica to the glaze, it continued to produce an ultra smooth glossy, and applied it to the 17% body on the left. Why did not fix the crazing? That silica addition to the glaze only reduces the calculated expansion from 6.0 to 5.9, clearly not enough to fix the problem. So, the obvious solution seems to be use the porcelain on the right. Are you wondering why adding silica to a body raises its thermal expansion, and adding it to a glaze lowers it? Mineralogy is the reason.
The glaze is 10% calcium carbonate added to Ravenscrag slip. Ravenscrag Slip does not craze when used by itself as a glaze at cone 10R on this body, so why would adding a relatively low expansion flux like CaO make it craze? This is an excellent example of the value of looking at the chemistry (the three are shown side-by-side in my account at Insight-live.com). The added CaO pushes the very-low-expansion Al2O3 and SiO2 down by 30% (in the unity formula), so the much higher expansion of all the others drives the COE of the whole way up. And talc? It contains SiO2 (so the SiO2 is not driven down nearly as much) and its MgO has a much lower expansion than CaO does.
This mug is pinging loudly and literally self-destructing in front of my eyes! Why? The glaze is under so much compression (the inside is pushing outward, the outside inward). Spiral cracks are developing all the way up the side. Small razor-sharp flakes are shivering off convex contours. Why? I accidentally fired a low-temperate talc body at cone 6 (the glaze is the Alberta Slip base cone 6 glossy). The clay body is not overly mature, but it just has an extremely high thermal expansion (talc is added to increase the expansion to fit low fire commercial glazes, they would craze without it). Shivering is serious, it is a mismatch of thermal expansion between body and glaze. It can happen at any temperature.
This glaze, "Bamboo Cone 10%", contains 50% potash feldspar. Don't do that. That much feldspar oversupplies K2O and Na2O, they have the highest thermal expansions of all oxides, by far. These are needed and valuable - but not too much. The result here: Crazing. This glaze used to work on this body, H550. The previous version of H550 was firing near the bloating point of the body, about 1% porosity, so the recipe had to be changed to provide more margin for error. The new recipe has a more practical 2.0-2.5% porosity, it has no danger of bloating or warping and still has excellent maturity and strength. This glaze was crazing before and pieces did not leak because the body was dense enough - so they were still water tight. But now it does not work. The solution is to do something that should have been done before: Use a silky matte base recipe that does not craze. We recommend our G2571A base (below right) - the Zircopax, rutile and iron oxide in the original can be added to it instead.
Articles |
Demonstrating Glaze Fit Issues to Students
Glaze and body can both be adjusted to solve crazing and shivering problems. This describes a simple project to create body glaze combinations guaranteed to craze and shiver to demonstrate the principles involved. |
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Articles |
Crazing in Stoneware Glazes: Treating the Causes, Not the Symptoms
Band-aid solutions to crazing are often recommended by authors, but these do not get at the root cause of the problem, a thermal expansion mismatch between glaze and body. |
Articles |
Understanding Thermal Expansion in Ceramic Glazes
Understanding thermal expansion is the key to dealing with crazing or shivering. There is a rich mans and poor mans way to fit glazes, the latter might be better. |
Articles |
Adjusting Glaze Expansion by Calculation to Solve Shivering
This page demonstrates how you might use INSIGHT software to do calculations that will help you increase the thermal expansion of a glaze while having minimal impact on other properties. |
Articles |
The Effect of Glaze Fit on Fired Ware Strength
The fit between body and glaze is like a marriage, if is is strong the marriage can survive problems. Likewise ceramic ware with well fitting glaze is much stronger than you think it might be, and vice versa. |
Articles |
G1916M Cone 06-04 transparent glaze
This is a frit based boron glaze that is easily adjustable in thermal expansion, a good base for color and a starting point to go on to more specialized glazes. |
Articles |
Is Your Fired Ware Safe?
Glazed ware can be a safety hazard to end users because it may leach metals into food and drink, it could harbor bacteria and it could flake of in knife-edged pieces. |
Articles |
Are Your Glazes Food Safe or are They Leachable?
Many potters do not think about leaching, but times are changing. What is the chemistry of stability? There are simple ways to check for leaching, and fix crazing. |
Articles |
Crazing and Bacteria: Is There a Hazard?
A post to a discussion on the clayart group by Gavin Stairs regarding the food safety of crazed ware. |
Materials |
Feldspar
In ceramics, feldspars are used in glazes and clay bodies. They vitrify stonewares and porcelains. They supply KNaO flux to glazes to help them melt. |
Media |
Desktop Insight 3 - Dealing With Crazing
Learn what crazing is, how it is related to glaze chemistry, how INSIGHT calculates thermal expansion and how to substitute high expansion oxides (e.g. Na2O, K2O) with lower expansion ones (e.g. MgO, Li2O, B2O3). |
Media |
A Broken Glaze Meets Insight-Live and a Magic Material
Use Insight-Live.com to do major surgery on a feldspar saturated cone 10R glaze recipe with multiple issues: blistering, pinholing, crazing, settling, dusting and possibly leaching! |
Media |
Analysing a Crazing, Cutlery-marking Glaze Using Insight-Live
A high-nepheline, zero-silica cone 8 silky matte pottery glaze is cutlery marking and crazing. Let's take a closer look and determine why? |
Media |
Remove Gerstley Borate and Improve a Popular Cone 6 Clear Glaze
How I found a ceramic glaze recipe on Facebook, substituted a frit for the Gerstley Borate, added the extra SiO2 it needed and got a fabulous more durable cone 6 clear. |
Glossary |
Glaze Crazing
Crazed ceramic glazes have a network of cracks. Understanding the causes is the most practical way to solve it. 95% of the time the solution is to adjust the thermal expansion of the glaze. |
Glossary |
Co-efficient of Thermal Expansion
The co-efficient of thermal expansion of ceramic bodies and glazes determines how well they fit each other and their ability to survive sudden heating and cooling without cracking. |
Glossary |
Glaze shivering
Shivering is a ceramic glaze defect that results in tiny flakes of glaze peeling off edges of ceramic ware. It happens because the thermal expansion of the body is too much higher than the glaze. |
Glossary |
Calculated Thermal Expansion
The thermal expansion of a glaze can be predicted (relatively) and adjusted using simple glaze chemistry. Body expansion cannot be calculated. |
Troubles |
Glaze Shivering
Ask the right questions to analyse the real cause of glaze shivering. Do not just treat the symptoms, the real cause is thermal expansion mismatch with the body. |
URLs |
https://ceramicartsnetwork.org/ceramics-monthly/ceramics-monthly-article/Techno-File-Dirty-Dishes#
Bacterial survival studies done on crazed glazes yield surprising results. But also an oversight. |
URLs |
http://www.astm.org/Standards/C424.htm
ASTM C424 - 93(2012) Standard Test Method for Crazing Resistance |
URLs |
http://www.astm.org/Standards/C554.htm
ASTM C554 - Thermal Shock Test Method for Crazing Resistance |
Tests |
300F:Ice Water Crazing Test
Ceramic glazes that do not fit the body often do not craze until later. This progressively stresses the fit until failure point, thus giving it a score |
Tests |
Boiling Water:Ice Water Glaze Fit Test
Ceramic glazes that do not fit the body often do not craze until later. This test stresses the fit, thus revealing if it is likely to craze later. |
Oxides | Na2O - Sodium Oxide, Soda |
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