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Dipping glazes peel like this because they contain clay and shrink as they dry (the fact that all of them don't do this is actually amazing). Success is a matter of the shrinkage being low enough, the drying being fast enough, the layer being thin enough, the bisque being absorbent enough, and the bond with the bisque being good enough. Glazes with high clay content, thick applications or multi-layering are the main offenders. Thixotropic slurries apply most evenly and are least likely to go on too thick. Dipping glazes having 15-20% kaolin or ball clay are easiest to slurry up and have the best application and drying properties. Mixing base layers as first-coat dipping glazes is also important.
The problem with this piece: The addition of 7.5% bentonite to make up for the otherwise low raw clay content in the recipe produced a recipe that does not pass a sanity check. When that was replaced with kaolin it worked. There is a crowbar approach to fix these without any other changes: Add CMC gum (e.g. 1%) to make them brushing glazes.
This picture has its own page with more detail, click here to see it.
If I put this on social, I might get 100 comments on the cause. Most would say it's applied too thick. That is not correct. At the top, it is too thick, but not at the bottom (where it is still cracking). Crawling during firing is almost certain.
Before offering any opinion, one needs to sanity check the recipe. This one, GA6-B, contains a lot of clay. Why do dipping glazes contain clay, usually kaolin, ball clay? To suspend the slurry, slow down drying, gel the slurry to make it thixotropic and harden the layer on drying. But their chemistry is also important, clays supply the all-important Al2O3 and SiO2 to the melt (which would otherwise have to come from feldspar). Certain clays excel at suspending. 15-20% EP kaolin, for example, is all that is needed. It’s not that plastic, but sticky and thixotropic (Grolleg and New Zealand kaolins are similar or even better). 10% of a gelling ball clay might be enough. However, 50% of a silty non-plastic clay might be needed. When the clay has too much influence, glazes shrink too much as they dry and then crack like this. Ones lacking clay (or employing one that is not suitable) have poor application properties (for dipping) and are powdery. This glaze has 80% pure raw Alberta Slip. That is a plastic clay, no wonder this is happening! 50% of it needs to be roasted.
Glossary |
Glaze Layering
In hobby ceramics and pottery it is common to layer glazes for visual effects. Using brush-on glazes it is easy. But how to do it with dipping glazes? Or apply brush-ons on to dipped base coats? |
Troubles |
Glaze peeling on drying
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