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These two specimens are the same terracotta clay fired at cone 03 in the same kiln. The glaze on the left combines 30% frit with five other materials. The one on the right mixes 90% frit with one other material (kaolin). Ulexite is the main source of boron in #1, it decomposes during firing, expelling 30% of its weight as gases, mostly CO2, forming micro-bubbles. Each of the six materials in that recipe has its own melting characteristics; their interaction creates a non-homogeneous glass containing phase separations (discontinuities) that affect the fired surface. In the fritted glaze, by contrast, all the particles soften and melt in unison and produce no gas. Notice that it has also interacted with the body, fluxing and darkening it (thus forming a better interface). And it has passed (and healed) more of the bubbles from the body.

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At low temperatures, potters want transparents with good clarity to support brilliant colors. Especially on terra cotta bodies. A melt flow test like this enables a comparison one cannot do on using glazed test tiles.
These are two low temperature glazes I use at cone 03, G2931F and G2931K. They have the same chemistry. But F gets its boron from Ulexite, a material with a high LOI (notice how the escaping gases have disrupted the downward flow). The frit-sourced boron version on the right flows cleanly and contains almost no obvious bubbles.
So obviously, one would use the K, right? Not exactly. I used the K version successfully on many pieces. In a thin layer, the ulexite seems to act as its own fining agent, like Gerstley Borate, and the bubbles do merge clear well enough.
| Glossary |
Boron Frit
Most ceramic glazes contain B2O3 as the main melter. This oxide is supplied by great variety of frits, thousands of which are available around the world. |
| Glossary |
Glaze Chemistry
Glaze chemistry is the study of how the oxide chemistry of glazes relate to the way they fire. It accounts for color, surface, hardness, texture, melting temperature, thermal expansion, etc. |
| Glossary |
Frit
Frits are used in ceramic glazes for a wide range of reasons. They are man-made glass powders of controlled chemistry with many advantages over raw materials. |
| Glossary |
Phase Separation
Phase separation in glaze melts creates microscopic discontinuities that affect transparency, color variegation, matte surfaces, and reactive glaze effects. |
| Materials |
Frit
Frits are made by melting mixes of raw materials, quenching the melt in water, grinding the pebbles into a powder. Frits have chemistries raw materials cannot. |
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