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What to do about lithium carbonate and Gerstley Borate in glazes

Lithium is getting really expensive. These are four recipes submitted by a customer who wonders if there is a substitute. The answer is not simple, each glaze is a unique situation. Fortunately, lithium carbonate is almost always a minor addition (in the first two recipes it is 1% and 3%). Lithium is a powerful low expansion flux, in some cases, a low melting low expansion frit could perform the same function (e.g. Ferro 3249). Even for the 6.5%, as in the third one, this could still work. But in these cases wouldn't it be better to continue using lithium? Even for the last one that has 9%? It's only expensive if you make glazes and don't use them. Perhaps a solution is to make them as brushing glazes, a 1-pint jar only needs about 350g of powder (that is only about 30g for recipe 4).

This situation can also be considered as an opportunity to rationalize the recipes you use. Let's pretend that each of these might be used on functional ware and should measure up to common sense recipe limits. The Gerstley Borate in three of these is also a red flag, that won't be available shortly (calculating how to source B2O3 from frits is better anyway). During that process, you might find that lithium is not even needed. Another issue is thermal expansion. Notice that one of these calculates to 8.5 and another to 9.6! Those are virtually certain to craze. Why not lower that number while removing the Gerstley Borate? Notice that two of these have clay percentages over 70% (Alberta Slip and Gerstley Borate), these are virtually certain to crack on drying (and crawl on firing), that can also be fixed. The percentage of titanium, Zircopax and rutile in the fourth one are guaranteed to make it crystallize heavily on cooling produce problems with cutlery marking and staining.

Four common lithium carbonate glazes

Links

Materials Lithium Carbonate
A powerful melter very valuable in ceramic glazes. It is 40% Li2O and has an LOI of 60% (lost as CO2 on firing). This material in now incredibly expensive.
Materials Gerstley Borate
Gerstley Borate was a natural source of boron for ceramic glazes. It was plastic and melted clear at 1750F. Now we need to replace it. How?
Glossary Calculated Thermal Expansion
The thermal expansion of a glaze can be predicted (relatively) and adjusted using simple glaze chemistry. Body expansion cannot be calculated.

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