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Orange-peel or pebbly glaze surface. Why?

This is a cone 10 glossy glaze. It has the chemistry that suggests it should be crystal clear and smooth. But there are multiple issues with the materials supplying that chemistry: Strontium carbonate, talc and calcium carbonate. Each has a significant LOI and produces gases decomposition. When the gases need to come out at the wrong time it turns the glaze into a Swiss cheeze of micro-bubbles. A study to isolate which of these three materials is the problem might make it possible to adjust the firing to accommodate it. But probably not. The most obvious solution is to just use non-gassing sources MgO, SrO, CaO and BaO (which will require some calculation). There is a good reason to do this: The glaze contains some boron frit, that is likely kick-starting melting much earlier than a standard raw-material-only cone 10 glaze. That fluid melt may not only be trapping gases from the body but creating a perfect environment to trap all the bubbles coming out of those carbonates and talc. All of this being said, a drop and hold firing schedule could also smooth it out a lot.

An orange peel textured glaze

Links

Materials Strontium Carbonate
A pure source of SrO for ceramic glazes. It contains 70% SrO and has an LOI of 30% (released as CO2 during firing).
Materials Talc
A source of MgO for ceramic glazes, a flux or thermal expansion additive in clay bodies, also used in the manufacture of cordierite.
Materials Calcium Carbonate
In ceramics, calcium carbonate is primarily a source of CaO in raw stoneware and porcelain glazes.
Troubles Orange Peel Surface
Orange peel is a defect or physical property of ceramic glazes
Troubles Glaze Blisters
Questions and suggestions to help you reason out the real cause of ceramic glaze blistering and bubbling problems and work out a solution
Glossary LOI
Loss on Ignition is a number that appears on the data sheets of ceramic materials. It refers to the amount of weight the material loses as it decomposes to release water vapor and various gases during firing.

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