Monthly Tech-Tip from Tony Hansen SignUp

No tracking! No ads! That's why this page loads quickly!

200 mesh | 325 mesh | 3D Design | 3D Printer | 3D Slicer | 3D-Printed Clay | 3D-Printing | Abrasion Ceramics | Acidic Oxides | Agglomeration | Alkali | Alkaline Earths | Amorphous | Apparent porosity | Artware | Ball milling | Bamboo Glaze | Base Glaze | Base-Coat Dipping Glaze | Basic Oxides | Batch Recipe | Bisque | Bit Image | Black Coring | Bleeding colors | Blender Mixing | Blisters | Bloating | Blunging | Bone China | Borate | Boron Blue | Boron Frit | Borosilicate | Breaking Glaze | Brick Making | Brushing Glaze | Calcination | Calculated Thermal Expansion | Candling | Carbon Burnout | Carbon trap glazes | CAS Numbers | Casting-Jiggering | Celadon Glaze | Ceramic | Ceramic Binder | Ceramic Decals | Ceramic Glaze | Ceramic Glaze Defects | Ceramic Ink | Ceramic Material | Ceramic Oxide | Ceramic Slip | Ceramic Stain | Ceramic Tile | Ceramics | Characterization | Chemical Analysis | Chromaticity | Clay | Clay body | Clay Body Porosity | Clay for Ovens and Heaters | Clay Stiffness | Co-efficient of Thermal Expansion | Code Numbering | Coil pottery | Colloid | Colorant | Cone 1 | Cone 5 | Cone 6 | Cone plaque | Copper Red | Cordierite Ceramics | Crackle glaze | Crawling | Crazing | Cristobalite | Cristobalite Inversion | Crucible | Crystalline glazes | Crystallization | Cuerda Seca | Cutlery Marking | Decomposition | Deflocculation | Deoxylidration | Differential thermal analysis | Digitalfire Foresight | Digitalfire Insight | Digitalfire Reference Library | Dimpled glaze | Dip Glazing | Dipping Glaze | Dishwasher Safe | Dolomite Matte | Drop-and-Soak Firing | Drying Crack | Drying Performance | Drying Shrinkage | Dunting | Dust Pressing | Earthenware | Efflorescence | Encapsulated Stain | | Eutectic | Fast Fire Glazes | Fat Glaze | Feldspar Glazes | Fining Agent | Firebrick | Fireclay | Fired Strength | Firing Schedule | Firing Shrinkage | Flameware | Flashing | Flocculation | Fluid Melt Glazes | Flux | Food Safe | Foot Ring | Forming Method | Formula Ratios | Formula Weight | Frit | Fritware | Functional | GHS Safety Data Sheets | Glass vs. Crystalline | Glass-Ceramic Glazes | Glaze Bubbles | Glaze Chemistry | Glaze Compression | Glaze Durability | Glaze fit | Glaze Gelling | Glaze laydown | Glaze Layering | Glaze Mixing | Glaze Recipes | Glaze Shrinkage | Glaze thickness | Globally Harmonized Data Sheets | Glossy Glaze | Green Strength | Grog | Gunmetal glaze | Handles | High Temperature Glaze | Hot Pressing | Incised decoration | Industrial clay body | Ink Jet Printing | Inside-only Glazing | Insight-Live | Interface | Iron Red Glaze | Jasper Ware | Jiggering | Kaki | Kiln Controller | Kiln Firing | Kiln fumes | Kiln venting system | Kiln Wash | Kovar Metal | Laminations | Leaching | Lead in Ceramic Glazes | Leather hard | Lime Popping | Limit Formula | Limit Recipe | Liner Glaze | Liner glazing | Liquid Bright Colors | LOI | Low Temperature Glaze | Majolica | Marbling | Material Substitution | Matte Glaze | Maturity | Maximum Density | MDT | Mechanism | Medium Temperature Glaze | Melt Fluidity | Melting Temperature | Metal Oxides | Metallic Glazes | Micro Organisms | Microwave Safe | Mineral phase | Mineralogy | Mocha glazes | Mohs Hardness | Mole% | Monocottura | Mosaic Tile | Mottled | Mullite Crystals | Native Clay | Non Oxide Ceramics | Oil-spot glaze | Once fire glazing | Opacifier | Opacity | Ovenware | Overglaze | Oxidation Firing | Oxide Formula | Oxide Interaction | Oxide System | Particle orientation | Particle Size Distribution | Particle Sizes | PCE | Permeability | Phase Diagram | Phase Separation | Physical Testing | Pinholing | Plainsman Clays | Plaster Bat | Plaster table | Plasticine | Plasticity | Plucking | Porcelain | Porcelaineous Stoneware | Pour Glazing | Powder Processing | Precipitation | Primary Clay | Primitive Firing | Propane | Propeller Mixer | Pugmill | Pyroceramics | Pyrometric Cone | Quartz Inversion | Raku | Reactive Glazes | Reduction Firing | Reduction Speckle | Refiring Ceramics | Refractory | Refractory Ceramic Coatings | Representative Sample | Respirable Crystalline Silica | Restaurant Ware | Rheology | Rutile Glaze | Salt firing | Sanitary ware | Sculpture | Secondary Clay | Shino Glazes | Shivering | Sieve | Sieve Shaker | Silica:Alumina Ratio | Silk screen printing | Sintering | Slaking | Slip Casting | Slip Trailing | Slipware | Slurry | Slurry Processing | Slurry Up | Soaking | Soluble colors | Soluble Salts | Specific gravity | Splitting | Spray Glazing | Stain Medium | Stoneware | Stull Chart | Sulfate Scum | Sulfates | Surface Area | Surface Tension | Suspension | Tapper Clay | Tenmoku | Terra Cotta | Terra Sigilatta | Test Kiln | Theoretical Material | Thermal Conductivity | Thermal shock | Thermocouple | Thixotropy | Throwing | Tony Hansen | Toxicity | Trafficking | Translucency | Transparent Glazes | Triaxial Glaze Blending | Ultimate Particles | Underglaze | Unity Formula | Upwork | Variegation | Viscosity | Vitreous | Vitrification | Volatiles | Warping | Water in Ceramics | Water Smoking | Water Solubility | Wedging | Whiteware | Wood Ash Glaze | Wood Firing | Zero3 | Zero4 | Zeta Potential

Engobe

Engobes are high-clay slurries that are applied to leather hard or dry ceramics and fire opaque. They are used for functional or decorative purposes.

Key phrases linking here: engobed, engobes, engobe - Learn more

Details

A white or colored slip applied to clay as a coating. The term "slip" is often used interchangeably with "engobe" but they are not actually the same. Generally, potters talk about slips in the context of decorating, often using the term as a verb. But in industry application of engobes is a process, generally to simply cover an underlying body to improve its appearance and response to glazes. The tile industry uses the largest volumes of engobe by far, these are employed as opaque barriers between less-than-white bodies and the overlying glaze, they are applied by automated pour/dipping methods. Engobes are so valuable to the tile industry because they enable the use of locally available (and therefore much less expensive) red and brown burning bodies (the white engobe provides a surface on which glazes can have the same brilliant colors as on porcelain). The use of these local clays has another key advantage: red-burning bodies vitrify at much lower temperatures, resulting in energy savings. Another area of cost-saving is that glazes need less zircon opacifier (one of the most expensive raw materials used in ceramics). However, there is a downside: This process rewets ware so it can add hours or a day to your drying procedure. However, the benefits can also accelerate other parts of the process.

In terracotta and stoneware processes, engobes are most often applied to leather-hard ware. Perfecting the rheology (specific gravity, viscosity and thixotropy) of a slurry is difficult and delicate. A good wall-mounted variable-speed propeller mixer is invaluable because you can set it to mix the slurry well but not so much that it pulls in air bubbles. The engobe needs a lower specific gravity to dry as fast as possible, be fluid enough to pour and drain well but have a high enough thixotropy to gel and stay in place without drips after application. It is best to have a recipe that recommends a specific gravity and the proportion of powder mix, water and Darvan (or other appropriate deflocculant) to produce that specific gravity (1.5 is good for most potters). If the recipe is right, then after thorough mixing it should be fairly fluid (in need of a flocculant to gel it somewhat). If it is not fluid, measure the specific gravity (by the weighing method, not a hydrometer, they are useless for this). If it is high, add water, measure again and repeat till right. If low, adjust the printed recipe for next time (reducing the water proportion) and proceed (a lower SG will still work, it just dries slower). It is now a balancing act: Enough deflocculant that the slurry is fluid enough to apply evenly and drain well, enough flocculant that it gels after a few moments (so you do not have to wait while it drips-drips-drips). In a gallon-size batch this can mean additions of only drop(s) of flocculant or deflocculant to move it as needed. Trial application on pieces is the best way to determine if the rheology is right. The whole process really is magic once you learn it. One warning: If you overdo a flocculant addition when adjusting the slurry can immediately become lumpy. Do not panic, the addition of a little deflocculant and propeller mixing will bring it back.

In traditional ceramics, engobe application is usually done at the leather hard stage (often followed by various decoration step). It is applied to dust-pressed tile as a curtain over a continuously moving production line or as a powder layer during the pressing of the tile itself. Potters would not generally have the equipment and expertise to apply engobes to dry ware. While it may appear possible to apply engobes to bisque ware (by adding CMC gum to harden and adhere them and VeeGum to gel the slurry somewhat), this is not advisable. The body-engobe-bond will be compromised as the engobe fire-shrinks on a body that has already done so. While thin layers may appear to work, they will likely fail with time because of internal stresses.

Engobe consistency will change on storage so mix thoroughly and readjust the degree of gel on each use. Once it has stabilized to the ideal consistency the slurry will gel on storage and resist thinning without propeller mixing. It will also power mix to what appears to be too thin of a consistency, but will gel up quickly to working behaviour.

“Engobe” is a more specific term than “slip”. Potters use slips for decorative purposes, they are normally made from a clay of contrasting color (with added feldspar, bentonite, etc). Potters often 'traffic' slip recipes. By that term, we mean that people often just try a bunch of recipes until they find one that appears to work (without considering any technical considerations). Industrial engobes, on the other hand, are usually designed for a specific body or body type, technicians creating and maintaining recipes are faced with a balancing act and constant production issues on multiple fronts.

Bonding is a key consideration when using engobes. The thicker the layer, or the more layers, the more issues there will be (this gives an advantage to bisque-stage application where very thin layers can be achieved). The challenge starts at the initial application and drying stage. When applied to leather-hard ware the engobe must bond mechanically to the surface during drying and shrink with the body. To do this it needs enough clays and binders to hang on but not so much that it shrinks excessively and cracks during drying. Strangely, engobes having a plasticity (and stickiness) considerably higher than the body seem to bond best during drying. For this reason, it is common to see very high ball clay percentages and additions of as much as 10% bentonite (which slows down drying considerably). That being said, as an engobe's thickness increases its ability to impose its own shrinkage also increases, and, as it does so, it will crack to relieve the stress if applied too thickly. A note about ball clay: If you don't have the one shown in a recipe just try the ones you do have, most ball clays have very similar properties.

Engobes need to be thermal expansion compatible with the body also (but only after their fired shrinkages are matched). This is so that stresses coming with temperature change during service do not lead to flaking off in use. Of course, tableware will experience much more thermal stress than will floor tile, for example. When glaze is applied over an engobe, it is important that the thermal expansions complement each other. In tile, for example, the thermal expansion of the engobe needs to be between that of the body and the glaze.

Engobe recipes found online often look like glazes, but they should not. Engobes are like bodies, there should be little or no frit or boron source in the recipe (except possibly at low temperatures). Excessive flux will compromise the most important attribute: opacity. More important, excessive flux will give the engobe a greater fired shrinkage than the body, introducing stresses that can severely test their bond and weaken the fired marriage. A vitreous engobe might have a fired shrinkage of 15%. Many stoneware bodies can be as little as 5-8%, vitreous bodies up to 10%. Earthenwares can exhibit a wide range of shrinkages depending on the firing temperature. Test bars of body and engobe can be fired at a range of temperatures to measure the fired shrinkages. Or, bi-clay strips can be made, these sandwich the body and engobe in a thin bar that curls during drying and firing to indicate fit or misfit. The lesson: Vitreous engobes on vitreous bodies, non-vitreous ones on non-vitreous bodies.

Thermal expansion compatibility is especially important in commercial products. Engobes cannot stand tensile stresses any better than glazes, so it is normal that an engobe should be under at least some thermal compression (not too much of course, especially if it is applied thickly). If ware is glazed (most common), fit is even more important. There are two interfaces to consider, body-to-engobe and engobe-to-glaze. Thus body/engobe compatibility should be tested separately (without the glaze) and the engobe/glaze compatibility tested (without the body, e.g. using the EBCT test). It is very important to avoid situations where the engobe is under tension from the body and the glaze under compression on the engobe (and vice versa). Engobes do not bond to the body as well as a glaze, so poor fit combinations are more likely to produce peeling and chipping at that interface. Because of the two interfaces and three expansions, it is easy to misdiagnose the cause of failure. The ideal situation is where the glaze has a lower thermal expansion than the engobe (thus being compressed by it) and the engobe lower than the body (and compressed by it). Example COE's reported to us by one tile manufacturer: Body- 200.7, engobe - 196 to 201, glossy glaze - 179 to 181.

Engobes are opaque so that means a relatively thin layer has the potential to be as effective as a thick one. Thus it is advantageous to tune the rheology of the slurry to effect a thinner application. A big benefit is that the leather-hard ware will not soften so much and will stiffen much quicker for further finishing.

Potters have options that are prohibitive in industry (because of cost and difficulty). For example, high percentages of zircon opacifier can be added for whiteness and opacity. Highly plastic and stickier mixes, lower specific gravities can be tolerated (they dry much slower). There is merit to creating a brushing version of your engobe, this enables close control of thickness and coverage. Use only CMC gum (not Veegum CER) to enable keeping the specific gravity as low as possible.

Related Information

The difference between a slip and an engobe

Tap picture for full size

L3685U slurry was applied to the insides of both of these mugs. But on the left it is a "slip", on the right an "engobe". Why? The left mug only has a thin layer, applied by painting a gummed version on (at leather hard stage). On the right a gelled slurry was poured into the leather hard piece, poured out and the rim dipped (creating a much thicker layer with more power to impose its own drying and firing shrinkage). So it is much more important that the latter be compatible with the underlying body. The EBCT test is used to measure how compatible the body and engobe are.

The covering power of an engobe is amazing. If they are not over-fluxed.

Tap picture for full size

This cone 6 mug is made from a black clay (containing 10% burnt umber). The engobe on the inside, L3954B, is covered by a clear glaze. The color is the same as if the engobe were on a white or buff firing stoneware. Engobes get their covering power from the fact that they do not melt. If you see an engobe with lots of frit it will likely melt too much, be suspicious.

L3954B Engobe with 20% zircon added

Tap picture for full size

On a buff stoneware at cone 6 under a transparent glaze. On the left, no zircon was added.

The value of a white vitreous engobe over terra cotta at cone 03

Tap picture for full size

At cone 03 many terra cottas will fire quite dense and stoneware-like. The lip of the mug on the left is covered with a vitreous white engobe (L3685U) under the glaze (G1916Q). Red bodies are much stronger at low temperatures, but do not lend themselves well to the bright glaze colors that work so well at that range. Putting an engobe on as a base enables decoration with colored slips and a clear over glaze. One caution: The engobe needs to have the same firing shrinkage as the body, to use a vitreous engobe the body needs a frit addition to be vitreous also. If you put a vitreous engobe on a porous earthenware its firing shrinkage will put it under tension and the poor bond with the body will mean quick or eventual failure.

Stain-based black engobe is clean to use!

Tap picture for full size

Stains are fired, inert particles of a relatively large ultimate size. Unlike that, raw oxide powders, like iron or manganese, have much finer sizes and are thus extremely dirty to use. This plaster slab is being used to dewater these 15% black engobes for shrinkage testing. The slurry on the right has just been poured, the one on the left has just been peeled up (it was spread across almost the entire surface). Notice it has left no stain (the marks on the outer edge wash off easily). What does this mean? It means that using this engobe is much, much cleaner than using a body or slip colored using raw or burnt umber, iron, manganese or cobalt.

Good engobes fire very opaque, they can be applied very thinly

Tap picture for full size
A black engobed leather hard mug

This black engobe, L3954B, is on a cone 6 buff stoneware (at leather hard stage). Because a thin layer works well with this high-opacity engobe it is possible for the slurry to be more fluid, less gelled. An immediate benefit of this is that it dries more quickly (enabling handling of the piece within a few hours). Another benefit is a much more even coverage than would be possible with more a viscous consistency. The thinner layer also means much fewer issues with flaking during drying. However application of the engobe takes patience, waiting for drips to stop and gelling to set in and hold it in place.

What an engobe does for even glaze laydown

Tap picture for full size

This stoneware jar is made from a large particle size body with grog added. It was engobed on the inside and over the lip at the leather hard stage and bisque fired. Now it has been dip-glazed inside and out. Because the clay is so porous, lots of air must escape from inside the wall as the matrix soaks up water from the freshly applied glaze. But the air is being channeled into pathways and concentrated into surface irregularities created by the coarse particles in the matrix. At each of the escape sites a bubble appeared (then healed into a depression when it burst). But the engobe on the inside creates a homogeneous surface that distributes air escape uniformly, it does not have a single blister.

Stage 1 of engobing a cone 6 red stoneware mug

Tap picture for full size

On the right is what it will look like when fired with a clear glaze on the inside and amber-clear on the outside. On the left it has dried and is ready for a little fix-up before bisque firing.

A Cone 6 white engobe works miracles on these dark and buff burning bodies

Tap picture for full size

Left is Plainsman M340. Right is M390. Each mug has been white-engobed inside, using L3954B, and half-way down the outside. The insides have been glazed using G2926B clear. The inside surface has more depth and has a richer appearance than could be achieved using a white glaze (especially over the dark burning body). The outside of the left one is Alberta Slip base GA6-B. The outside glaze on the right is the clear plus 4% iron oxide. This technique of using the engobe enables porcelain-like functional surfaces on the insides and striking visual contrast and character on the outside of the dark body mug.

Absolutely jet-black cone 6 engobe on M340

Tap picture for full size
A buff stoneware mug with black engobe

This is the L3954B engobe. 15% Mason 6600 black body stain has been added (instead of the normal 10% Zircopax for white). Of course, a cover glaze is needed, but even without it is absolutely coal black (so a lesser stain % is possible). Lots of information is available for L3954B (including mixing and adjustment instructions). Engobes are tricky to use, follow the links below to learn more. L3954B is designed to work on regular Plainsman M340 (this piece), M390 and Coffee Clay, these bodies dry better than porcelains and are much less expensive, coating them with an engobe to get a surface like this makes a lot of sense. This engobe is actually a highly plastic body, but it does not contain enough feldspar to be a porcelain (this is on purpose to match the firing shrinkage of the stonewares). This can be adjusted to fit any stoneware.

Four drops of Davan deflocculant fixed the problem!

Tap picture for full size

This is a white engobe (L3954B) drying on two dark burning cone 6 stoneware leather-hard mugs (Plainsman M390). Those lumps are on the left cannot be screened out, they are agglomerates. That slip has excessive flocculant (powdered Epsom salts are added to gel it so that it stays put on the piece after dipping). About 4 drops of Darvan were added to one gallon of the slurry, this immediately made it smooth and a perfect consistency for application. It remains stable on ware (without runs). Engobes require tight control to have the right viscosity and thixotropy (which can be achieved over a range of specific gravities (about 1.45-1.6). When they are right they are a joy to use, when they are not ware is ruined.

Here’s how we make a brushing engobe

Tap picture for full size
Engobe mixing in a blender

This brushing engobe is thick and gooey (because it contains CMC gum), so it is practically impossible to sieve. While our propeller mixer was not able to break up the tiny agglomerates of New Zealand kaolin 30 seconds of bender mixing made it as smooth as silk. To make this liter of brushing engobe we use 800g of powder and 10g of CMC gum in 800g of water. It does not require Veegum (like glazes) because it already contains plenty of clay. The CMC gum greatly improves the brushing properties so additions of stain make it useful for colored underglazes also. For best performance we apply them to leather hard ware.

Adding water actually made this white engobe run less? How?

Tap picture for full size

The white slip (applied to a leather hard cup) on the left is dripping downward from the rim (even though it was held upside down for a couple of minutes!). Yet that slurry was very viscous with a 1.48 specific gravity. Why? Because it was not thixotropic. The fix? I watered it down to 1.46 (making it runny) and added pinches of powdered epsom salts (while mixing vigorously) until it thickened enough to stop motion in about 1-2 seconds on mixer shut-off. But that stop-motion is followed by a bounce-back. That is the thixotropy. It is easy overdo the epsom salts (gelling it too much), I add a drop or two of Darvan to rethin it if needed. When the engobe is right it gels after about 10 seconds of sitting, so I can stir it, dip and extract the mug, shake to drain it and then it gels and holds in place. Keep in mind, this is a pottery project. In industry they deflocculate engobes to reduce water content. But a deflocculated slurry can still be gelled (if it is runny).

I want this engobe to gel in ten seconds. Why?

Tap picture for full size

It is going to be applied to leather hard earthenware and it needs to be thixotropic (gelled when not in motion, liquid when in motion). Why? I do not want it to run down from the rims of the mugs after dipping. The process: Stir the engobe, pour-fill the mug, pour it out and push it upside down into the engobe. If I can pull it back out before the 10 second gel-time is up I get a perfectly even layer that does not move. A good test is to stir it then pull out the spatula slowly. If it hangs on in a even layer with only a few drips it is perfect. Achieving this behaviour requires very careful additions of powdered epsom salts (and thorough mixing between). As the slip approaches this 10 second threshold even a slight bit more salts will turn it into a bucket of jelly (if that happens I add a drop or two of Darvan). This process works across a range of specific gravities (about 1.45-1.6), the higher the SG the trickier it is (but the faster it dries).

Fitting an engobe: It is about the data!

Tap picture for full size
Fired test bars of a terra cotta body

Physical data. Data about the working, drying and firing properties that can measured. These test bars show how stable this unusual terra cotta body, L4170B, is across a wide temperature range (from cone 8 down to 06)! Using the SBAB test procedure, I measured the shrinkage and porosity of each bar (and recorded the data in my Insight-live group account, it displays it like the black and red chart shown). I also made test bars of a super-white engobe, L3685Z3, and compiled the same data. That enabled two approaches to fitting engobe-to-body. First, isolate a temperature at which both have the same fired shrinkage, and are therefore compatible. Unfortunately there isn't one, the white engobe has much lower fired shrinkage at all practical temperatures! Option 2 is to add frit to the white engobe to make it as vitreous as the body. I started with a 5% addition of Ferro Frit 3110. At my target temperature, cone 02, that increased the shrinkage from 2.1% to 5.5% (this red body is 4.3%). So 5% frit is too much. So, the next move is clear, I will try 3% frit. It will only be necessary to test it at the one temperature. Because both engobe and body and not volatile, I am confident in just testing at cone 02.

How to test if an engobe fits a clay body

Tap picture for full size

This is part of a project to fit an engobe (slip) onto a terra cotta at cone 02 using the EBCT test.
Left: On drying the red body curls the bi-clay strip toward itself, but on firing it goes the other way!
Right: SHAB test bars of the white slip and red body enable comparing their drying and firing shrinkages.
Center back: A mug with the white engobe and a transparent overglaze. The slip is going translucent under the glaze because it is too vitreous. Its higher fired shrinkage curls the bi-clay bars toward itself. Reducing the frit will reduce the firing shrinkage and make it more opaque (because it will melt less).
Front: A different, more vitreous red body (Zero3 stoneware) fits the slip better (the strips dry and fire straight).

Bi-Clay strips test compatibility between engobe and body

Tap picture for full size

Slips and engobes are fool-proof, right? Just mix the recipe you found on the internet, or that someone else recommends, and you are good to go. Wrong! Low fire slips need to be compatible with the body in two principle ways: drying and firing. Terra cotta bodies have low shrinkage at cone 06-04 (but high at cone 02). The percentage of frit in the engobe determines its firing shrinkage at each of those temperatures. Too much and the engobe is stretched on, too little and it is under compression. The lower the frit the less the glass-bonding with the body and the more chance of flaking if they do fit well (either during the firing or after the customer stresses your product). The engobe also needs to shrink with the body during drying. How can you measure compatibility? Bi-body strips. First I prepare a plastic sample of the engobe. Then I roll 4 mm thick slabs of it and the body, lay them face-to-face and roll that down to 4 mm again. I cut 2.5x12 cm bars and dry and fire them. The curling indicates misfit. This engobe needs more plastic clay (so it dry-shrinks more) and less frit (to shrink less on firing).

Potters can learn from how glazes are fit on ceramic tile

Tap picture for full size

These are thermal expansion curves for body, engobe and glaze (from a dilatometer, a device that measures it against increasing temperature). The upper line is the body. The center line is the engobe. The lower line is the glaze. The ceramic tile industry is very conscious, not only of glaze-fit but also engobe-fit. Engobes (slips) are employed to cover brown or red burning bodies so they glaze like a porcelain. Typically technicians tune the formulation of the engobe to have an expansion between the body and glaze. The body is highest so that during cooling, as it contracts, it puts a squeeze on the engobe (the engobe thus never finds itself under tension). The glaze has the lowest expansion, it is under a state of compression by the engobe (and slightly more by the body). This equilibrium enables the tile to wear for many years without crazing or shivering. Chart courtesy of Mohamed Abdelmagid.

Should you use a porcelain as an engobe on stoneware?

Tap picture for full size

This is how bad the fit can actually be. In the front is a bi-clay EBCT test strip of a grogged cone 10R sculpture clay sandwiched with a porcelain. After drying this bar was relatively straight. But during firing the porcelain has a much higher fired shrinkage and it pulls the bar toward itself. During cooling, the sculpture clay has a higher thermal expansion and it pushes from its side bending the bar further. This bar is a time bomb, just waiting for a mechanical or thermal stress to bust it into a hundred pieces. Admittedly, putting a thin layer of this onto a piece of heavy ware is not going to bend it. But will it flake off when exposed to stresses (like freeze thaw, being put in an oven, having a hot liquid poured into it, being bumped).

Glaze under excessive compression can flake off the engobe

Tap picture for full size

The amber glaze on the outside of the left mug contains 20% super-low thermal expansion Ferro Frit 3249 as the melter. With no underlying engobe it can form enough of a bond with the body that it does not flake off at the rim (even though it is under excessive compression because its low thermal expansion). This flaking is called "shivering". The engobe, which does not melt like a glaze, has a more fragile bond with the body (and the glaze is pushing enough to make that bond fail). The mug on the right employs 20% Frit 3195 melter instead, producing a glaze that fits better. I hammered both of these rims repeatedly with a metal object to stress them, that one on the right definitely fits better.

Shivering on a transparent over an engobe

Tap picture for full size

Example of a glaze (G1916J) shivering on the rim of a mug. But the situation is not as it might appear. This is a low quartz cone 03 vitreous red body having a lower-than-typical thermal expansion. The white slip (or engobe) has a moderate amount of quartz and is thus put under some compression by the body. But the compression is not enough to shiver off (e.g. at the rim) when by itself. However the covering glaze has an even lower expansion exerting added compression on the slip. This causes a failure at the slip-body interface.

Too much frit in an engobe and it will lose opacity and whiteness

Tap picture for full size

The white slip on the left is an adjustment to the popular Fish Sauce slip (L3685A: 8% Frit 3110 replaces 8% Pyrax to make it harder and fire-bond to the body better). The one on the right (L3685C with 15% frit) is becoming translucent, obviously it will have a higher firing shrinkage than the body (a common cause of shivering at lips and contour changes). The slip is basically a very plastic white body. Since these are not nearly as vitreous as red ones at low fire they need help to mature and a frit is the natural answer. With the right amount the fired shrinkage of body and slip can be matched and the slip will be opaque. This underscores the need to tune the maturity of an engobe to the body and temperature. Although zircon could be added to the one on the right to opacify and whiten it, that would not fix the mismatch in fired shrinkage between it and the body.

One way to avoid drying cracks on handle-joins of engobed mugs

Tap picture for full size

The foot ring on these leather-hard mugs has already been trimmed. At the stiff-leather-hard stage an engobe was applied to the inside. This rewets the bodies of the mugs, almost to the same point as freshly-thrown. But the handles did not get rewetted. To re-dry these mugs to the point of being able to turn them over will take 4-6 more hours. But by that time the handles will be too dry. To prevent that I waxed them after trimming (leaving a just the inside handle-curves bare). That slows their drying down enough to keep them even with the body of the mug. Keeping all parts of a piece at the same water content throughout the process, that is a key to successful drying.

Double-slip layer incised decoration: A challenge in slip-body fitting

Tap picture for full size

An example of a white engobe (L3685T) applied over a red clay body (L3724F), then a red engobe (also L3724F) applied over the white. The incised design reveals the white inter-layer. This is a tricky procedure, you have to make sure the two slips are well fitted to the body (and each other), having a compatible drying shrinkage, firing shrinkage, thermal expansion and quartz inversion behavior. This is much more complex that for glazes, they have no firing shrinkage and drying shrinkage only needs to be low enough for bisque application. Glazes also do not have quartz inversion issues.

Underglazes melting very differently at cone 8

Tap picture for full size

Commercial underglaze colors fired in a flow tester. Underglazes need to melt enough to bond with the underlying body, but not so much that edges of designs bleed excessively into the overlying glaze. A regular glaze would melt enough to run well down the runway on this tester, but an underglaze should not flow at all. The green one here is clearly not sufficiently developed, its base needs more frit. The black is much too melted, its base needs less frit. The pink and blue are also melting too much. Clearly, underglazes recipes need individual attention so they melt to the same degree.

Bleeding underglaze. Why?

Tap picture for full size

This cobalt underglaze is bleeding into the transparent glaze that covers it. This is happening either because the underglaze is too highly fluxed, the over glaze has too high of a melt fluidity or the firing is being soaked too long. Engobes used under the glaze (underglazes) need to be formulated for the specific temperature and colorant they will host, cobalt is known for this problem so it needs to be hosted in a less vitreous engobe medium. When medium-colorant compounds melt too much they bleed, if too little they do not bond to the body well enough. Vigilance is needed to made sure the formulation is right.

What happens when engobe fired shrinkage is too high?

Tap picture for full size
Engobe misfit crack pattern inside a mug

The white engobe on the inside of this mug does not fit, that is what these cracks are about. The misfit can be demonstrated using EBCT test bars (shown in the foreground). This pair sandwich the engobe and body as a bi-clay strip, they are dried and fired with alternative sides up. A bend demonstrates differences in the fired shrinkage of body and engobe. On drying these stayed relatively flat but after firing at cone 10R, the engobe's higher shrinkage pulled them concave. On this mug, made from the same clay and engobe, the latter has done likewise, shrinking more than the body and creating a crack pattern that even the glaze could not hide. This was a development version of L3954N that contained too much nepheline syenite.

When engobing ware stick handles on well, avoid acute angles

Tap picture for full size

The handle on this mug joined the wall at an acute angle. The wet engobe was applied to the leather-hard piece and took hours to dry (rewetting and softening the whole piece in the process). During that time the engobe was able to exploit the join and penetrate into it (the crack diverted straight into the soft weakened wall). Notice how the engobe has pooled at the join in the other two mugs also (although they did not fail). Engobes typically have a high water content and experiences like this teach us to take precautions when using them.

What happens when you apply an engobe to dry ware

Tap picture for full size

This engobe has high plasticity, high water content and is sticky, it is intended for use on leather-hard ware. The leather hard clay absorbs a little of the water from the engobe (softening somewhat) and just waits for it to catch up. Then the two shrink and dry together, forming a good bond. If the piece is dry, however, the wet engobe quickly slakes and wets the surface, pulling pieces away as it shrinks.

If you think one slip fits any body, think again

Tap picture for full size

This flake shivered off the rim of a low fire terra cotta mug. It is Fishsauce slip. It is about 2 inches long and has razor sharp edges. This is not the sort of thing you would want to be falling into your coffee or food and then eating! This flake did give evidence that it was loosening so there was little danger of me consuming it, but smaller flakes can go unnoticed. Slips (or engobes) must be drying compatible, have the same firing shrinkage, the same thermal expansion and be quartz inversion compatible with the body. It is easy to ignore all that and pretend that it works, but the bond between engobe and body is fragile at low fire and easily compromised by the above incompatibilities. Slips must be fitted to the specific body, glaze and temperature; that involves a testing program and often a little chemistry. I have documented online how to I adapted this slip to Plainsman Terrastone 2 using my account at insight-live.com.

Inner engobe separating at the rim

Tap picture for full size

This is the only place we have noted separation with this engobe and body. The engobe was gelled and the piece was drained upside down. So this edge was thicker. The separation occurs at the concave contour a couple of mm down (and breaks away to that point). The engobe is more plastic than the clay and thus shrinks more. Normally the extra stickiness from the extra plasticity is an asset, but not always.

An engobe is shivering off the rim of a low temperature mug

Tap picture for full size

Classic terra cotta bodies are not vitreous, so engobes used on them need to have similar low fired shrinkage. But when terra cottas are fired above cone 04 they start to mature and fired shrinkage increases quickly, flaking off engobes that do not have sufficient added frit (to increase their shrinkage). Even if an under-compression engobe can hang on, the extra stresses of an overglaze of lower thermal expansion can compromise the engobe:body bond. That has happened on the center mug. That engobe has less frit (10% vs. 15% for the others). The clear glaze on the left has high thermal expansion and is crazing, while the engobe:body bond can tolerate that it, is obviously not desirable.

This is what happens if you apply a non-gummed engobe to bisque ware

Tap picture for full size

The drying shrinkage of the engobe (and stickiness that goes with that) are important for adherence during application at the leather hard stage. And also to shrinking with the body during the drying process. But not on bisque ware. If, however, the engobe is gummed it can often adhere to the bisque (but the fired bond with the body will not be as good as when applied at leather hard stage).

Inbound Photo Links


Black porcelain engobe
Brushing engobe fitted to this white porcelain turns it black


A must-have: Laboratory variable speed propeller mixer


When two clays are joined are they compatible?

Two samples, the same engobe runs but not the other
The same engobe. Same water content. What is the difference?


How much does a glaze need to melt before it sticks to the body well?

Links

Articles Monoporosa or Single Fired Wall Tiles
A history, technical description of the process and body and glaze materials overview of the monoporosa single fire glazed wall tile process from the man who invented it.
Glossary Slip Trailing
A technique used by potters to decorate ware. Neutral and colored slips, clay in thick paste form, are trailed onto the ware (in raised lines and strokes) to create tactile designs.
Glossary Underglaze
A intensely pigmented and highly opaque brushing compound meant to be applied to leather hard pottery and covered with a transparent overglaze.
Glossary Thixotropy
Thixotropy is a property of ceramic slurries. Thixotropic suspensions flow when you want them to and then gel after sitting for a few moments. This phenomenon is helpful in getting even, drip free glaze coverage.
Glossary Terra Sigilatta
Terra Sigilatta is a sedimentation process used by potters to remove coarse particles from a clay powder. It enables burnishing and gloss surfaces without the use of glaze.
Glossary Firing Shrinkage
During drying, clay particles draw together and shrinkage occurs. During firing the matrix densifies and shrinkage continues. More vitreous bodies shrink more.
Glossary Interface
In ceramics, the zone of adherence between glaze to the underlying body is called the clay-glaze interface. The integrity of this interface is important to strength and functionality.
Media Adjusting the Thixotropy of an Engobe for Pottery
How to fine-tune the thixotropy of a ceramic engobe for pottery
Media How to Apply a White Slip to Terra Cotta Ware
I will show you some secrets of making a base engobe (or slip) apply to leather hard terracotta ware in a thick, perfectly even layer.
Tests Engobe Body Compatibility Test
A bi-clay test strip curls to demonstrate the drying and fired compatibility or fit of an engobe (or slip) on a ceramic body or of two bodies for marbling.
Recipes L3954N - Cone 10R Base White Engobe Recipe
Cone 10 reduction black engobe for stonewares (not porcelains).
Hazards Manganese in Clay Bodies
Manganese is used to stain clays (using black) and to impart fired speckling (as a decorative effect). It is dangerous?
URLs https://www.smac.it/en/dettaglio.php?idprod=220
Reverso engobe printer for tile backs
By Tony Hansen
Follow me on

Got a Question?

Buy me a coffee and we can talk



https://digitalfire.com, All Rights Reserved
Privacy Policy