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Is Mexican Terra-cotta pottery lead-glazed? Yes.

This piece was bought in Sinaloa in 2020. The merchant said it was made in Puebla. The lead test procedure involves leaving white vinegar in the piece overnight, pouring some of that into a test tube, dipping a cotton swab into a reagent solution and then stirring the vinegar. The color indicates lead content. As you can see, it has turned black, indicating heavy concentration of lead. This pottery is a tradition in Mexican culture and is used for food and liquid surfaces everywhere. There are manufacturers trying to make stoneware that retains the traditional appearance, but few people use it. Further refiring tests demonstrated that these are fired around 1700-1750F, a temperature sufficient to melt pure lead bisilicate into a glossy transparent but the body is still very soft and porous.

A lead-glazed handled cup still common sold in markets in Mexico

Related Pictures

Refiring a terra cotta piece has darkened the color

Two halves of a terra co

This piece was made in Puebla, Mexico by a potter using traditional techniques. I have sawed it in half and refired one half at 1850F (orton cone 04). That half (the right one) has not shrunk, that means it has not exceeded the temperature of the original firing (the piece was likely glazed in the dry state, not bisque fired). Notice how the refire has darkened the body color. This is probably happening because the lead bisilicate glaze is maturing the surface of the clay (without the glaze it would take a much higher temperature to darken it to this extent, and, that would also entail shrinkage to a dramatically smaller size).

Ferro Frit 3602 melt flow over many temperatures

A 9 gram ball of frit melts and flows downward more and more as temperature increases.

This demonstrates the amazing melt behaviour of lead-as-a-flux for ceramic glazes. Not only does it melt early, but it softens slowly over a 300F range of temperatures before it goes off the end of the runway on this GLFL test. Then, when fired 200F hotter than that, it remains a stable, clear and uncrazed glass. Beginning around 1750F, this becomes a transparent glaze, by itself.

Links

Hazards Lead Toxicology


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