|Monthly Tech-Tip |
This recipe, our code 77E14A, contains 6% red iron oxide and 4% tricalcium phosphate. But the color is a product of the chemistry. The glaze is high Al2O3 (from 45 feldspar and 20 kaolin) and low in SiO2 (the recipe has zero silica). This calculates to a 4:1 Al2O3:SiO2 ratio, very low and normally indicative of a matte surface. The iron oxide content of this is half of what is typical in a beyond-tenmoku iron crystal glaze (those having enough iron to saturate the melt and precipitate as crystals during cooling). The color of this is also a product of some sort of iron crystallization, but it is occuring in a low-silica, high-alumina melt with phosphate and alkalis present. Reducing the iron percentage to 4% produces a yellow mustard color (we thus named this "Red Mustard").
This iron crystal glaze is Ravenscrag slip plus 10% iron oxide fired to cone 10R on Plainsman H550. Since Ravenscrag slip is a glaze-by-itself at cone 10, it is an ideal base from which to make a wide range of glazes.
Ravenscrag Slip, by itself, produces a silky transparent glaze at cone 10R. It is an excellent base to which to add colorants and modifiers. This is a simple addition of 10% iron oxide (Ravenscrag Slip already contains 2% iron, making about 12% total Fe2O3). It produces a stunning crystalline fired surface on these two porcelains. We can call this a "Beyond-Tenmoku" (crystals happen because of more iron or a slow cooling rate than a Tenmoku). The 12% iron dissolves in the glaze melt during firing, but during cooling in the kiln, the extra 2% precipitates out to produce these surfaces. The iron also acts as a flux in reduction firing, greatly increasing melt fluidity. Take that last statement seriously: The iron is a flux, the glaze will melt much more. So just adding iron oxide to a glossy transparent will wreck your kiln shelves when it runs down off the ware. Ravenscrag Slip does not melt-to-glossy, it has just enough feldspar to fire to a durable surface, making it a more stable host for the iron addition.
|Materials||Iron Oxide Red|
|Oxides||Fe2O3 - Iron Oxide, Ferric Oxide|
|Oxides||FeO - Ferrous Oxide|
Iron Red Glaze
A type of ceramic glaze, typically fired around 2200F, where iron oxide in the cooling glass precipitates out to form a striking red crystalline mesh on the surface.