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Chemistry plus physics. Maintain your recipes, test results, firing schedules, pictures, materials, projects, etc. Access your data from any connected device. Import desktop Insight data (and of other products). Group accounts for industry and education. Private accounts for potters. Get started.

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  • Your website is phenomenal, I love it to get insight on different oxides. I helps me alot, even though we are pretty specialized.
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  • Sir, I'm a big fan and pupil of you from India. I am 27 years old. I always read digitalfire. I share with my mates to understand the ceramic from digital fire.
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  • I think you have done a great job in developing the on-line version. It is very easy to use. We meet once a month to discuss any glaze problems, test glazes in teams, and I do a presentation on an aspect of glaze chemistry. One day, I said something technical and one of the member's jaw dropped and she said "Hey, I just realized I understood what you said". It was a proud moment.
  • THANK YOU SO VERY MUCH for your continuing contributions to the ceramic world! [Yes, all caps is shouting, intentionally so!] I've been following Digital Fire for about 25 years now. Many of those years passed with my studio packed in crates in storage. I now have leads on space to reopen. You've kept my passion alive through your postings.
  • When it comes to new technology, I'm still thrilled with the chainsaw as apposed to an ax. I really do like glaze testing. You see a recipe in a book but it doesn't do you a lot of good until you can see it on a tile.
  • Your work is so thorough and helpful Tony. When I read your articles I suddenly feel I know nothing, despite working professionally with ceramics since 1997!
  • I am a high school senior AP ceramics student investigating glaze chemistry and rheology. I spend a great deal of my free time browsing the digitalfire reference library, and would have never developed the passion I have for ceramics chemistry had I not come across it.
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Blog

Glaze cracking during drying? Wash it off and then do this.

Glaze spider web cracking on drying

If your pottery glaze is doing on drying then it will crawl during firing. Wash it off, dry the ware. Then check the water content. If the glaze has worked fine in the past then it is likely going on too thick because the specific gravity is too high - just repeat cycles of adding a little water and dip testing (make it thixotropic if needed). But that was not the issue here. Glazes need clay to suspend and harden them, but too much clay means trouble. This was Ravenscrag Slip, a clay, being used pure as a cone 10R glaze. The glaze appeared to go in perfectly and it dried to the touch in ~20 seconds. But shrinkage continues after that, revealing after a couple of minutes. Fixing the issue was a matter of adding some roasted Ravencrag Slip to the bucket. That reduced the shrinkage and therefore the cracking. Any glaze containing excessive kaolin can be fixed the same way (trade some of the raw kaolin for calcined kaolin). Some glazes that contain plenty of clay also have bentonite - a simple fix for these is to simply remove the bentonite.

Context: Calcined Kaolin, Calcination, Crawling

Friday 5th December 2025

Custer Feldspar vs Nepheline Syenite at cone 8 oxidation

Feldspar and nepheline melting

Although Nepheline Syenite and Custer Feldspar are used as effective body maturing agents and fluxes in glazes past cone 6, curiously, neither of them melt well by themselves. Thus, both of these come 6 melt fluidity tests add 20% Ferro Frit 3134 to get them flowing. This is a 2021 shipment of the feldspar and a 2022 shipment of the nepheline.

Context: Custer Feldspar, Nepheline Syenite, Casting pure nepheline syenite.., Pure nepheline syenite mug..

Thursday 27th November 2025

Low fire ware cracking during firing. Why?

Low fire ware cracking in half during firing

Most low-fire bodies contain talc. It is added for the express purpose of increasing thermal expansion. The natural quartz particles present do the same. These are good for glaze fit but bad for ware like this. There are also sudden volume changes associated with cristobalite, but it forms (from quartz) at stoneware temperatures so should not be a concern in terra cotta or a white low fire body. You could fiddle with the clay recipe or change bodies, but better to change the firing schedule. The quartz in stonewares goes through a sudden volume change between 950-1150F on the way down. Quartz particles in low fire bodies will do the same. A simple fix is to slow down the entire cooling cycle like this potter did. Or, learn to program your kiln to approach this range more slowly, then ease down through it. No electronic controller? Learn a switch-setting-schedule to approximate this down-ramp (buy a pyrometer if needed).

Context: Manually programming a Bartlett.., Dunting, Quartz Inversion, Cristobalite Inversion, Cristobalite

Sunday 23rd November 2025

Non-plastic clay is required here

No potter could use it

Multipart metal mold jiggering machines

Potters love plastic clay. On the wheel it enables pulling larger, more overhang, thinner walled pieces. For beginners it can make the difference between success or a collapsed lump of mud. The downside is high drying shrinkage and danger of cracking. But potters know how to exercise care in drying to get success anyway.

This industrial jiggering machine has the opposite priority: Ability to hold shape immediately after forming and to dry crack-free quickly. The secret is low plasticity stiff clay (notice how it splits around the edges when flattened). Notice, in the video, how much water is used yet it does not stick to the heated metal mold. Note also how the machine avoids tearing it by applying pressure slowly right to the end. Even then, the vertical splitting on the outer belly and the crumbly way it cuts verify its poor plasticity.

Context: Video on Instragram shows..

Saturday 22nd November 2025

Thrown pieces made from pure Grolleg and EP kaolins

This is how you compare plasticities

Mugs thrown from two pure kaolins

These have just been thrown on the wheel. I find it to be a foolproof method of comparing the plasticity of two clays. They were slurried up and dewatered to about the same moisture content and the same amount was thrown to compare the size achievable. While the Grolleg is stickier and dewaters a little slower, it is not nearly as plastic as EPK (which itself is not that plastic compared to others). Curiously, New Zealand kaolin (halloysite) is quite a bit less plastic than the Grolleg but it responds to plasticity augmentation (in porcelain recipes) just as well as Grolleg (similar amounts of bentonite producing similar plasticities). And, bodies containing EPK also need about the same amount of bentonite to produce plasticity suitable for throwing large forms. So, the plasticity that a kaolin appears to have by itself is not completely indicative of what it will contribute to a body (if augmented with bentonite). The EPK used here is the darker and more plastic of the two varieties we receive.

Context: EP Kaolin, EPK fired bar top..

Wednesday 19th November 2025

The ultimate example of delayed crazing: 90 years!

Glaze chemistry is the key to understanding it

A restoration project faced a tile-matching challenge. At installation in a bathroom 90 years ago, the tiles were not crazed. But between then and now it happened (shown inset upper right). Now, a restoration specialist is tasked with duplicating the aged effect (one unsuccessful attempt is shown here). The shade, opacity, degree of matteness, bubble-free matrix and surface character of the original are all real challenges. Duplicating the crazing is even more difficult. Why? Matching "time-crazing" with a crackle glaze pattern will be temporary (it will craze much more after installation).

The reason why functional mattes seldom craze can be seen in the chemistry. This chart compares the thermal expansions of the oxides that combine to form the fired glaze matrix. ~80%+ of the makeup of almost all common base glazes (without colorants, opacifiers) is SiO2 and Al2O3 (orange bars). Mattes almost always need a low Si:Al ratio (e.g. below 6:1). The rest is fluxing oxides to melt them (the blue bars + B2O3). Here is the problem with making a crazing matte: Almost all crazing is caused by high levels of K2O and/or Na2O (the top two bars on the graph). But they produce high gloss (as can be seen in this test tile). The main matting fluxes and agents are MgO, CaO, SrO, BaO; they have a low COE (and don't craze glazes). Further, both zircon and tin oxide, the opacifiers needed, also have low thermal expansions!

Other possibilities of making crazed matte:
-A matte glaze can have a high SiO2:Al2O3 ratio and craze if it is very melt fluid (containing lots of KNaO) and cooled slowly so that micro-crystals cover the surface. The downside is unpleasantness to the touch.
-Glossy glazes can be matted by the addition of micron-fine alumina (e.g. 800 mesh, this is done in the tile industry).
-A low expansion body with no ball clay or silica (e.g. just kaolin and feldspar with enough bentonite to get the needed plasticity) will craze most glazes. Adding pyrophyllite will further lower its COE.
-Print the lines on the tile (using ceramic transfers) and use a translucent matte glaze (like G2934).

Context: Turning delayed crazing into.., Glaze Crazing

Monday 10th November 2025

Potter goes full DIY and makes her own porcelain

The best thing happens: Failure on the third mix!

Blistered porcelain mug

Super white translucent porcelains are expensive, approaching $200/box in some countries! Even so, variation in properties is common (certainly not good for a "tipping point body" that is difficult to make). The idea of making your own clay body is actually feasible here. Yet Kirsty Kash, maker of this mug, told me that this amount of DIY was something she had never really considered, thinking it would be too complicated without guidance. But ongoing issues with the commercial clay gave her the motivation to give it a try (using a recipe similar to L3778D). She weighed out the materials, slurried up the mix using a propeller mixer, finished by blender mixing and then dewatered on a super-clean plaster bat.

By the third batch, something good happened: The porcelain blistered (tiny bumps on the surface). Subsequent correspondence brought the realization that this type of body is "walking a recipe tightrope" that requires control of the percentage of the key ingredient: Feldspar. It determines the maturity of the fired product. Too much brings blisters, too little and translucency is lost. Simple testing is all that is needed to determine the needed amount. More good news: The change enabled increasing the kaolin percentage by the same amount. That, in turn, enabled reducing the percentage of veegum (reducing the cost).

Her comment a few days ago was inspiring: "I'm getting to know my material so intimately. I have been learning SO much." When I suggested she might end up buying commercial again she responded: "I just bought large bags of all the materials and plan to keep going. I like having the control and being less reliant on the boxed clay. You've converted me!".

Context: Formulating a Porcelain, Agglomeration of New Zealand.., Kirsty Kash Ceramics, Digitalfire Insight-Live

Saturday 8th November 2025

A grog addition makes thermal shock resistance worse?

I tested this in a low COE Pyrax:Kaolin body

Pyrax (Pyrophillite) is a mineral having a very low thermal expansion. It stands to reason that if we can maximize its percentage in a body and not fire the body to a point that changes the crystal structure, it will be resistant to thermal-shock cracking. To that end, I mixed it with only kaolin (ball clay would add some quartz that would increase thermal expansion). I made slip-cast pieces of similar thickness for testing. I fired them to cone 2 (after finding that by cone 4, shock-resistance begins to decline). As you can see from the video, the addition of grog actually harms the performance! The higher the Pyrax, the better. To get a real appreciation for how well this body endures differential heat stress, wait till the end to see how a glazed porcelain piece compares.

Context: Pyrophyllite, Thermal shock

Wednesday 5th November 2025

Two base clear glazes with 2% copper:

One is bubbling and one is not.

Copper is bubbling a pottery glaze

By itself, without copper, the G2926B recipe (right) produces a better and more durable glass (comparing the cups in the back). But a 2% copper addition, front, turns its surface to a mass of unhealed bubble-escapes. The G3808A recipe, on the left, develops much more melt fluidity, the extra mobility enables the bubbles, created by the decomposing copper, to coalesce, grow, break at the surface and heal before the melt stiffens too much.

Context: G3806C, More copper can produce.., Transparent Glazes, Leaching, Base Glaze, Fluid Melt Glazes

Wednesday 5th November 2025

Why would a glaze turn into a jelly like this?

This is one of the things Gerstley Borate commonly does (when its percentage is high enough). It is also highly thixotropic - this can be stirred vigorously to thin it, yet within seconds it turns back to jelly again. This is part of the reason it is often referred to as “ghastly borate”. Side effects of this include high water content, slow drying, excessive shrinkage on drying, cracking and crawling. To attempt a fix, I deflocculated it with Darvan. It was stable enough to dip bisque ware, with difficulty (but pieces dried very slowly). But overnight it has turned back into a gel. What can be done with a mess like this? Start over, with three options:
1. Identify the mechanism to isolate the base recipe and substitute another.
2. Replace the Gerstley Borate with an equivalent that does not do this (Gillespie Borate).
3. Do a little chemistry to source the B2O3 from a frit instead (e.g. in an account at insight-live.com).

Context: Gerstley Borate, Glaze Gelling, Getting Frustrated With a..

Wednesday 5th November 2025



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