What can you do using glaze chemistry? More than you think!

There is a direct relationship between the way ceramic glazes fire and their chemistry. These green panels in my Insight-live account compare two glaze recipes: A glossy and matte. Grasping their simple chemistry mechanisms is a first step to getting control of your glazes. To fixing problems like crazing, blistering, pinholing, settling, gelling, clouding, leaching, crawling, marking, scratching, powdering. To substituting frits or incorporating available, better or cheaper materials while maintaining the same chemistry. To adjusting melting temperature, gloss, surface character, color. And identifying weaknesses in glazes to avoid problems. And to creating and optimizing base glazes to work with difficult colors or stains and for special effects dependent on opacification, crystallization or variegation. And even to creating glazes from scratch and using your own native materials in the highest possible percentage.

Related Pictures

Click here for case-studies of Insight-Live fixing problems

You will see examples of replacing unavailable materials (especially frits), fixing various issues (e.g. running, crazing, settling), making them melt more, adjusting matteness, etc. Insight-Live has an extensive help system (the round blue icon on the left) that also deals with fixing real-world problems and understanding glazes and clay bodies.

ChatGPT is completely wrong about the cause of glaze crazing!

A ChatGPT answer to a question about crazing

Today, ChatGPT is parroting common wrong suggestions about the cause and solution of the serious issue of crazing. Yet it trained on thousands of internet pages about the subject! Crazed functional ware is defective, and customers will return it. So fixing the problem is serious business, we need correct answers. Consider ChatGPT's suggestions: #1 is wrong. There is no such thing as an "incompatible mix" of ceramic materials. Crazing is an incompatibility in thermal expansions of glaze and body, almost always a result of excessive levels of high-expansion K₂O and Na₂O in the chemistry of the glaze. The solution is reducing them in favor of other fluxes (the amount per the degree of COE mismatch). #2 is wrong, firing changes don't fix the incompatibility of thermal expansions. #3 is wrong, refiring makes the crazing go away but not the stress of the mismatch, it will for sure return. #4 is completely wrong. Firing higher takes more quartz grains into solution in the melt and should reduce the COE (and mature the body more which often improves fit). And melt fluidity has nothing to do with crazing. Furthermore, if a glaze does not run off the ware, it is not overfired.

Links

Troubles	Glaze Pinholes, Pitting Analyze the causes of ceramic glaze pinholing and pitting so your fix is dealing with the real issues, not a symptom.
Troubles	Glaze Blisters Questions and suggestions to help you reason out the real cause of ceramic glaze blistering and bubbling problems and work out a solution
Glossary	Ceramic Material Ceramic materials are employed in the ceramic industry to make glazes, bodies, engobes and refractories. We study them at the mineral, chemical and physical levels.
Glossary	Leaching Ceramic glazes can leach heavy metals into food and drink. This subject is not complex, there are many things anyone can do to deal with this issue
Glossary	Pinholing Pinholing is a common surface defect that occurs with ceramic glazes. The problem emerges from the kiln and can occur erratically in production.
Glossary	Food Safe Be skeptical of claims of food safety from potters who cannot explain or demonstrate why. Investigate the basis of manufacturer claims and labelling and the actual use to which their products are put.
Glossary	Glaze shivering Shivering is a ceramic glaze defect that results in tiny flakes of glaze peeling off edges of ceramic ware. It happens because the thermal expansion of the body is too much higher than the glaze.
Glossary	Glaze Blisters Blistering is a common surface defect that occurs with ceramic glazes. The problem emerges from the kiln and can occur erratically in production. And be difficult to solve.
Glossary	Glaze Chemistry Glaze chemistry is the study of how the oxide chemistry of glazes relate to the way they fire. It accounts for color, surface, hardness, texture, melting temperature, thermal expansion, etc.
Glossary	Base Glaze Understand your a glaze and learn how to adjust and improve it. Build others from that. We have bases for low, medium and high fire.
Tests	Glaze Leaching Test Simple tests to evaluate the stability of a ceramic or pottery glaze against leaching metals in food or drink.
Articles	Where do I start in understanding glazes? Break your addiction to online recipes that don't work or bottled expensive glazes that you could DIY. Learn why glazes fire as they do. Why each material is used. How to create perfect dipping and brushing properties. Even some chemistry.

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