|Monthly Tech-Tip |
These are actually two different cone 6 base glazes to which I add a black stain. I trust them because I formulated and perfected them myself: G2926B clear and GA6-B Alberta Slip base. They are durable, fit my clay bodies, melt well yet can host a stain without loss of gloss. I even know the chemistry, both have plenty of SiO2 and Al2O3, that is a hallmark of durability. I fired these using the PLC6DS schedule. I add 5% black stain to the former and 4% to the latter, both yield a jet-black. The GA6-B requires ball milling. Stains are inherently much safer to use than raw metal oxide colorants because they are sintered as colorant/stabilizer blends. And much less is needed. Contrast that with raw metal oxides, it is common to find black recipes containing up to 15% of blends of nickel, cobalt, iron and manganese! At times the manganese alone can be 8% or more! So, I feel relatively safe using these coloured glazes on a surface that will be exposed to hot and acidic liquids.
Often the answer is yes. This glaze looks too matte, too metallic, too crystalline. This picture was sent to me by a worried person who had bought it and noticed it discolouring on the inside. The potter may very well have considered this safe just because it was fired to cone 10. It is common among potters to overload glazes with raw metal oxide blends, often 15% or more (e.g. manganese, copper, iron, nickel, cobalt). These percentages cannot be held in solution in the melt as it cools and solidifies, so they precipitate out and crystallize, especially if the glaze is not melting well or has insufficient SiO2. The crystalline forms of these metals might look nice to some people, but the glaze is likely to leach them. It is better to use a ceramic stain to create a black like this, adding it to a stable matte base glaze (one that melts well and has sufficient SiO2 and Al2O3 to create a durable glass). The concept of a limit recipe is helpful in eyeballing recipes for their likelihood of leaching.
These were left overnight in vinegar and lemon juice. The top two are G3914A (GA6-B Alberta Slip base with 4% Mason 6600 black stain). Fired at cone 6. There is no sign of leaching (Drano and bleach likewise did not leach this). The bottom two are G2926B transparent with 10% manganese dioxide and 5% copper oxide added (also cone 6). G2926B is a proven base that does not show signs of leaching in any of the four liquids (containers lined with it were used for all tests). Not only was this not nearly as black, but the vinegar and lemon juice matted and blued it in an overnight soak (clearly visible on the top halves). Obviously, compared to raw metal oxides, a ceramic stain is a safer and much better way to produce a black functional surface.
Are Your Glazes Food Safe or are They Leachable?
Many potters do not think about leaching, but times are changing. What is the chemistry of stability? There are simple ways to check for leaching, and fix crazing.
Ceramic stains are manufactured powders. They are used as an alternative to employing metal oxide powders and have many advantages.