|Monthly Tech-Tip |
Modified: 2021-05-25 20:53:42
A base transparent glaze recipe created by Tony Hansen for Plainsman Clays, it fires high gloss and ultra clear with low melt mobility.
|Ferro Frit 3134||25.40|
A cone 6 transparent general purpose base recipe developed at Plainsman Clays by Tony Hansen (see link to go there below, it contains technical and mixing information about the recipe).
This is an adjustment to an original recipe named Perkins Studio Clear (this contains much more SiO2 and uses a frit instead of Gerstley Borate as the boron source). It is just as glossy and transparent, has a less fluid melt (thus will be more durable). With this change this is a really stunning transparent glaze. We have found that this will even tolerate 5% more silica, yet still smooths out well (more silica produces a more durable glass).
We always fire pieces using the C6DSSC firing schedule. That alone greatly reduces surface defects and gives better gloss. If you can also ball mill the glaze, it will be even better (more transparent, more durable, more glossy). This is because 200 mesh particles of silica may not dissolve in the melt (ball milling breaks them down). Another option is to use 400 mesh silica.
In our testing this glaze survives a 300F oven-to-icewater test without crazing on Plainsman M370 (25-Porcelain using Nepheline, Tile#6 Kaolin, silica and Old Hickory ball clay. It is less affected than the original when the application is too thick (minimal bubbles and crazing).
If you just want to mix it the traditional way, then start with 90 water to 100 powder (by weight) and agitate well using a propeller mixer. Then add more water until it is creamy, try it, adjust, etc. However this recipe has the best suspension and application properties when it is thixotropic (that involves mixing it thinner than normal and gelling it using Epsom salts). Target a specific gravity of 1.43-1.44 (equal weights of water and powder should be slightly above this). Then about add 1g of Epsom salts per 1000g powder to increase thixotropy. This should make it creamy and it should gel after a few seconds on standing still (add more Epsom salts if needed, but be careful, it is easy to over-do it).
Since the slurry is not too far from 50:50 water:powder, you could add colors and opacifiers on that basis. For example, 1000g of slurry has about 500g of powder. For white you need 10% zircopax, so that is 50g. This is approximate, but suitable for testing. Later if you decide a mix has promise then mix-from-scratch with the right percentages.
Screen through 80 mesh (tiny wollastonite agglomerates are possible, they will not break down without screening).
Plainsmanclays.com makes this recipe as a premixed powder. The glazes section on their site has additional info.
If this crazes ball milling will help (assuring that all silica grains dissolve and do their work to low thermal expansion). Otherwise see the links below.
This glaze melts early, it may not be suitable for decals (we have had successes and failures with decal firings to cone 022). The problem occurs when tiny sharp-edged blisters form over the surface. We have not identified the cause yet, let us know if you know what it is.
Stains are a much better choice for coloring glazes than raw metal oxides. Other than the great colors they produce here, there are a number of things worth noticing. The percentages may be lower than what you think would be needed, stains are potent colorants. Staining a transparent glaze produces a transparent color, that means it is more intense where the glaze layer is thicker. This is often desirable in highlighting contours and designs. If you add an opacifier, like zircopax, the color will be less intense, producing a pastel shade the more you add. The chrome-tin maroon 6006 does not develop well in this base (alternatives are G2916F or G1214M ). The 6020 manganese alumina pink is also not developing here (it is a body stain). Caution is required with inclusion stains (like #6021), the bubbling here is not likely because it is over fired (it is rated to cone 8), adding 1-2% zircopax normally fixes this issue.
Melt fluidity test showing Perkins Studio clear recipe original (left) and a reformulated version that sources the boron from Ferro Frit 3134 instead of Gerstley Borate (right). The later is less amber in color (indicating less iron) and it melts to very close to the same degree.
The green boxes show cone 6 Perkins Studio Clear (left) beside an adjustment to it that I am working on (right). I am logged in to my account at insight-live.com. In the recipe on the right, code-numbered G2926A, I am using the calculation tools it provides to substitute Frit 3134 for Gerstley Borate (while maintaining the oxide chemistry). A melt-flow GLFL test comparison of the two (bottom left) shows that the GB version has an amber coloration (from its iron) and that it flows a little more (it has already dripped off). The flow test on the upper left shows G2926A flowing beside PGF1 transparent (a tableware glaze used in industry). Its extra flow indicates that it is too fluid, it can accept some silica. This is very good news because the more silica any glaze can accept the harder, more stable and lower expansion it will be. You might be surprised how much it took, yet still melts to a crystal clear. See the article to find out.
These cone 6 porcelain mugs are hybrid. Three coats of a commercial glaze painted on outside (Amaco PC-30) and my own liner glaze poured in and out on the inside (G2926B). When commercial glazes (made by one company) fit a stoneware or porcelain (made by another company), without crazing or shivering, it is purely an accident! So use them on the outside. But for inside food surfaces make or mix your own. When you know the recipe you can tune the thermal expansion. And the degree of melt. And the application properties. And you can use quality materials to source a balanced chemistry. The place to start understanding your glazes, organize testing and development and document everything is an account at Insight-live.com.
These two pieces are fired at cone 6. The base transparent glaze is the same (G2926B Plainsman transparent). The amount of encapsulated red stain is the same (11% Mason 6021 Dark Red). But two things are different. Number 1: 2% zircon has been added to the upper glaze. The stain manufacturers recommend this, saying that it makes for brighter color. However that is not what we see here. What we do see is the particles of unmelting zircon are acting as seed and collection points for the bubbles (the larger ones produced are escaping). Number 2: The firing schedule. The top one has been fired to approach cone 6 and 100F/hr, held for five minutes at 2200F (cone 6 as verified in our kiln by cones), dropped quickly to 2100F and held for 30 minutes.
G2926B has proven to be my most durable, crystal clear, non-crazing, easy-to-use general purpose cone 6 base glaze (from dozens I developed). However, some porcelains (e.g. Plainsman P300) need an even lower thermal expansion. G2926S adjusts "B" (by adding low-expansion MgO at the expense of high-expansion KNaO). Yet it has the same gloss. The insides of these P300 mugs use it (with 10% added Zircopax to make white). "S" is not an all-purpose recipe, it could shiver on high silica bodies, use it if G2926B fails an IWCT test for crazing. These mugs were fired using the PLC6DS firing schedule, the outside glazes are G2934Y silky matte with added stains.
When you mix it right it will be thixotropic, that is, it will gel slightly and hold itself on the ware after dipping. This state can only be achieved if there is enough water for the epsom salts to do their magic. The watery nature of the slurry is nice for measuring specific gravity using a hydrometer (normally they don't float freely enough if the slurry is creamy). We normally recommend a specific gravity of 1.44 for this glaze, but in this case it seemed watery enough at 1.46. On use it will become clear if 1.46 is OK. How? It will go on the ware too thick. If that happens just add water to 1.44 and add more epson salts to gel it back up.
We started by adding 500 grams of the G2926B Whiteware base clear to 250g of water and 100g of Laguna gum solution. It was possible to stir all the powder in without a mixer. There were a few lumps left but they broke down overnight (yielding about 550 ml at 1.58 specific gravity). For the black we added 30g more of Mason 6666 stain (6%) and for white 50g of zircopax (10%). This increased the specific gravity to 1.63, higher than pretty well any commercial brushing glaze (if needed, there is plenty of room to add water to thin it for better application properties). The black recipe costs about 1.37 cents/ml for us to make (compared to Amaco C-1 Obsidian @ 3.92 cents/ml to buy). But the situation gets even better: If we were to add enough water to bring the specific gravity down to the 1.4 of C-1 there would be far more than 550ml.
2% zircon also was also added, it helps prevent micro-bubbling. The PLC6DS (drop and soak) firing schedule was used. The G3806 base clear glaze is normally better than G2926B for really bright colors but this stain is an exception.
Potters often store glazes for long periods so tiny spherical precipitate particles can form. These were found in a months-old bucket (about 2 gallons). These can appear over time, depending on factors like temperature, electrolytes in your water or solubility in the materials (likely, the frit is slightly soluble). The glaze slurry should be screened periodically (or immediately if you note the particles when glazing a piece). This is an 80 mesh sieve. Note the brush, using one of these gets the glaze through the screen much quicker than using a rubber spatula. The loss of material on the screen is tiny and inconsequential to the glaze.
The flow on the left is an adjusted Perkins Frit Clear (we substituted frit for Gerstley Borate). It is a cone 6 transparent that appeared to work well. However it did not survive a 300F oven-to-icewater IWCT test without crazing on Plainsman M370. The amount of flow (which increases a little in the frit version) indicates that it is plenty fluid enough to accept some silica. So we added 10% (that is the flow on the right). Now it survives the thermal shock test and still fires absolutely crystal clear.
These two glazes are both brilliant glass-like super-transparents. But on this high-iron stoneware only one is working. Why? G3806C (on the outside of the piece on the left) melts more, it is fluid and much more runny. This melt fluidity gives it the capacity to pass the micro-bubbles generated by the body during firing. G2926B (right) works great on porcelain but it cannot clear the clouds of micro-bubbles coming out of this body. Even the glassy smooth surface has been affected. The moral: You need two base transparents in which to put your colors, opacifiers and variegators. Reactive glazes need melt fluidity to develop those interesting surfaces. But they are more tricky to use and do not fire as durable.
Fired at cone 6. A melt fluidity comparison (behind) shows the G3808A clear base is much more fluid. While G2926B is a very good crystal clear transparent by itself (and with some colorants), with 2% added copper oxide it is unable to heal all the surface defects (caused by the escaping gases as the copper decomposes). The G3808A, by itself, is too fluid (to the point it will run down off the ware onto the shelf during firing). But that fluidity is needed to develop the copper blue effect (actually, this one is a little more fluid that it needs to be). Because copper blue and green glazes need fluid bases, strategies are needed to avoid them running off the ware. That normally involves thinner application, use on more horizontal surfaces or away from the lower parts of verticals.
These porcelain mugs were decorated with the same underglazes (applied at leather hard), then bisque fired, dipped in clear glaze and fired to cone 6. While the G2926B clear glaze (left) is a durable and a great super glossy transparent for general use, its melt fluidity is not enough to clear the micro-bubbles generated by the underglazes. G3806C (right) has a more fluid melt and is a much better choice to transmit the underglaze colors. But I still applied G2926B on the inside of the mug on the right, it has a lower thermal expansion and is less likely to craze.
Lower Expansion version of G2926B Cone 6 Clear Glaze
G2926B Cone 6 Transparent Glaze at PlainsmanClays.com
G3806C/G2926B Cone 6 Transparent Glazes
Thixotropy is a property of ceramic slurries. Thixotropic suspensions flow when you want them to and then gel after sitting for a few moments. This phenomenon is helpful in getting even, drip free coverage.
Every glossy ceramic glaze is actually a base transparent with added opacifiers and colorants. So understand how to make a good transparent, then build other glazes on it.
Understanding your transparent glaze and learning how to adjust its melt fluidity, thermal expansion, color response, etc is a base on which to build all your other glazes.
In ceramics, the specific gravity of casting slurries and glazes tells us their water-to-solids. Body slurries especially require tight control of this property for performance reasons.
A way of establishing guideline for each oxide in the chemistry for different ceramic glaze types. Understanding the roles of each oxide and the limits of this approach are a key to effectively using these guidelines.
High Gloss Glazes
A transcript of a presentation at the 3rd Whitewares conference at Alfred University in the spring of 2000 by Richard Eppler.
Reducing the Firing Temperature of a Glaze From Cone 10 to 6
Moving a cone 10 high temperature glaze down to cone 5-6 can require major surgery on the recipe or the transplantation of the color and surface mechanisms into a similar cone 6 base glaze.
Concentrate on One Good Glaze
It is better to understand and have control of one good base glaze than be at the mercy of dozens of imported recipes that do not work. There is a lot more to being a good glaze than fired appearance.
Where Do I Start?
Break your addiction to online recipes that don't work. Get control. Learn why glazes fire as they do. Why each material is used. Some chemistry. How to create perfect dipping and drying properties. Be empowered. Adjust recipes with issues rather than sta
How to Liner-Glaze a Mug
A step-by-step process to put a liner glaze in a mug that meets in a perfect line with the outside glaze at the rim.
G2926S - Low Expansion version of G2926B
Low expansion version of Plainsman Clays/Digitalfire G2926B cone 6 clear base glaze
G1214M - Original Cone 6 Base Glossy Glaze
A recipe developed by Tony Hansen in the 1980s. Its was popular because of the simplicity of the recipe and how well it worked with chrome-tin stains.
G2934 - Matte Glaze Base for Cone 6
A base MgO matte glaze recipe fires to a hard utilitarian surface and has very good working properties. Blend in the glossy if it is too matte.
G3806C - Cone 6 Clear Fluid-Melt Clear Base Glaze
A base fluid-melt glaze recipe developed by Tony Hansen. With colorant additions it forms reactive melts that variegate and run. It is more resistant to crazing than others.
GR6-A - Ravenscrag Cone 6 Clear Glossy Base
This Plainsman Cone 6 Ravenscrag Slip base is just the pure material with 20% added frit to make it melt to a glossy natural clear.
Cone 6 Drop-and-Soak Firing Schedule
How I Improved a Popular Cone 6 Clear Glaze Using Insight-Live
How I found a ceramic glaze recipe on Facebook, substituted a frit for the Gerstley Borate, added the extra SiO2 it needed and got a fabulous more durable cone 6 clear.
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