Monthly Tech-Tip from Tony Hansen SignUp

No tracking! No ads!

0.8mm thickness | 200 mesh | 325 mesh | 3D Design | 3D Modeling | 3D Printer | 3D Printing Clay | 3D Slicer | 3D-Printing | Abrasion Ceramics | Acidic Oxides | Agglomeration | AI in Ceramics | Alkali | Alkaline Earths | All-in-one case mold | Amorphous | Apparent porosity | Artware | Ball milling | Bamboo Glaze | Base Glaze | Base-Coat Dipping Glaze | Basic Oxides | Batch Recipe | Bisque | Bit Image | Black Core | Bleeding of colors | Blender Mixing | Blunging | Body Bloating | Body glaze Interface | Body Warping | Bone China | Borate | Boron Blue | Boron Frit | Borosilicate | Breaking Glaze | Brick Making | Brushing Glaze | Calcination | Calculated Thermal Expansion | Candling | Carbon Burnout | Carbon trap glazes | CAS Numbers | Casting-Jiggering | Catch Glaze | Celadon Glaze | Ceramic | Ceramic Binder | Ceramic Decals | Ceramic Glaze | Ceramic Glaze Defects | Ceramic Ink | Ceramic Material | Ceramic Oxide | Ceramic Slip | Ceramic Stain | Ceramic Tile | Ceramic Transfer | Ceramics | Characterization | Chemical Analysis | Chromaticity | Clay | Clay body | Clay Body Porosity | Clay Stiffness | Clays for Ovens and Heaters | Co-efficient of Thermal Expansion | Code Numbering | Coil pottery | Colloid | Colorant | Commercial hobby brushing glazes | Cone 1 | Cone 5 | Cone 6 | Cone plaque | Copper Red | Cordierite Ceramics | Crackle glaze | Cristobalite | Cristobalite Inversion | Crucible | Crystalline glazes | Crystallization | Cuerda Seca | Cutlery Marking | Decomposition | Deflocculation | Deoxylidration | Differential thermal analysis | Digitalfire API | Digitalfire Foresight | Digitalfire Insight | Digitalfire Insight-Live | Digitalfire Reference Library | Digitalfire Taxonomy | Dimpled glaze | Dinnerware Safe | Dip Glazing | Dipping Glaze | Dishwasher Safe | Displacer | Dolomite Matte | Drop-and-Soak Firing | Drying Crack | Drying Performance | Drying Shrinkage | Dunting | Dust Pressing | Earthenware | Efflorescence | Encapsulated Stain | Engobe | Eutectic | Fast Fire Glazes | Fat Glaze | Feldspar Glazes | Fining Agent | Firebrick | Fireclay | Fired Strength | Firing Schedule | Firing Shrinkage | Flameware | Flashing | Flocculation | Fluid Melt Glazes | Flux | Food Safe | Foot Ring | Forming Method | Formula Ratios | Formula Weight | Frit | Fritware | Functional | GHS Safety Data Sheets | Glass vs. Crystalline | Glass-Ceramic Glazes | Glaze Blisters | Glaze Bubbles | Glaze Chemistry | Glaze Compression | Glaze Crawling | Glaze Crazing | Glaze Durability | Glaze fit | Glaze Gelling | Glaze laydown | Glaze Layering | Glaze Mixing | Glaze Recipes | Glaze shivering | Glaze Shrinkage | Glaze thickness | Globally Harmonized Data Sheets | Glossy Glaze | Green Strength | Grog | Gunmetal glaze | High Temperature Glaze | Hot Pressing | Incised decoration | Industrial clay body | Infill and Support | Ink Jet Printing | Inside-only Glazing | Iron Red Glaze | Jasper Ware | Jiggering | Kaki | Kiln Controller | Kiln Firing | Kiln fumes | Kiln venting system | Kiln Wash | Kneading clay | Kovar Metal | Laminations | Leaching | Lead in Ceramic Glazes | Leather hard | Limit Formula | Limit Recipe | Liner Glaze | Liner Glazing | Liquid Bright Colors | LOI | Low Temperature Glaze | Majolica | Marbling | Material Substitution | Matte Glaze | Maturity | Maximum Density | MDT | Mechanism | Medium Temperature Glaze | Melt Fluidity | Melting Temperature | Metal Oxides | Metallic Glazes | Micro Organisms | Microwave Safe | Mineral phase | Mineralogy | Mocha glazes | Mohs Hardness | Mold Natches | Mole% | Monocottura | Mosaic Tile | Mottled | Mullite Crystals | Native Clay | Non Oxide Ceramics | Oil-spot glaze | Once fire glazing | Opacifier | Opacity | Ovenware | Overglaze | Oxidation Firing | Oxide Formula | Oxide Interaction | Oxide System | Particle orientation | Particle Size Distribution | Particle Sizes | PCE | Permeability | Phase Diagram | Phase Separation | Physical Testing | Pinholing | Plainsman Clays | Plaster Bat | Plaster table | Plasticine | Plasticity | Plucking | Porcelain | Porcelaineous Stoneware | Pour Glazing | Pour Spout | Powder Processing | Precipitation | Primary Clay | Primitive Firing | Propane | Propeller Mixer | Pugmill | Pyroceramics | Pyrometric Cone | Quartz Inversion | Raku | Reactive Glazes | Reduction Firing | Reduction Speckle | Refiring Ceramics | Refractory | Refractory Ceramic Coatings | Representative Sample | Restaurant Ware | Rheology | Rutile Blue Glazes | Salt firing | Sanitary ware | Sculpture | Secondary Clay | Shino Glazes | Side Rails | Sieve | Sieve Shaker | Silica:Alumina Ratio | Silk screen printing | Sintering | Slaking | Slip Casting | Slip Trailing | Slipware | Slurry | Slurry Processing | Slurry Up | Soaking | Soluble colors | Soluble Salts | Specific gravity | Splitting | Spray Glazing | Stain Medium | Stoneware | Stull Chart | Sulfate Scum | | Surface Area | Surface Tension | Suspension | Tapper Clay | Tenmoku | Terra Cotta | Terra Sigilatta | Test Kiln | Theoretical Material | Thermal Conductivity | Thermal shock | Thermocouple | Thixotropy | Throwing | Tipping point | Tony Hansen | Toxicity | Trafficking | Translucency | Transparent Glazes | Triaxial Glaze Blending | Ultimate Particles | Underglaze | Unity Formula | Upwork | Variegation | Viscosity | Vitreous | Vitrification | Volatiles | Water Content | Water in Ceramics | Water Smoking | Water Solubility | Wedging | Whiteware | WooCommerce | Wood Ash Glaze | Wood Firing | WordPress | Zero3 | Zero4 | Zeta Potential

Sulfates

Soluble sulfates in clay produce efflorescence, an unsightly scum that mars the fired surface of structural and functional ceramic products.

Key phrases linking here: sulphates, sulfates - Learn more

Details

Sodium, potassium, magnesium sulfates can be found in many clays. These are soluble and migrate to the surface during drying. Soluble salts can be iron stained, but often are white. Depending on the temperature of the firing and the nature of the salt, they can leave scum on the surface (often called 'efflorescence') that ranges from dry white to melted, glossy brown. Heavy clay industries can tolerate clays with higher sulphate contents, but other industries, such as tile, need lower contents). When the clay is fired to vitrification, the salt can act as a micro-thin glaze and actually harden and give a sheen to the surface. On foot rings it can also result in plucking problems.

Related Information

Soluble salts on a range of different cone 6 fired clay brown/tan bodies


The concentrations are not serious and are typical of what you might find on a commercial body.

A DFAC drying test disk of a terra cotta pottery clay from St. Ignacio, Sinaloa, Mexico


A clay drying performance test

This clay is used by traditional potters in the Mazatlan, Sinaloa, Mexico area. This DFAC test exhibits a very wide main crack and many edge cracks. These combine to indicate high shrinkage (a product of very high plasticity). Although the clay has some coarser grains that help channel water out, this is a very poor showing for drying performance - no large-scale manufacturer could tolerate this. But potters can and the Mexican craftsmen use it with success! How? By adapting their drying procedures. The high dry strength of this material is also a factor that helps prevent cracking. Almost any clay can be dried if the process is done evenly. And almost any can be cracked if done unevenly enough. This DFAC test is also a good indicator of the amount of soluble salts present (the slightly darker band around the perimeter), this is minimal so not scumming should appear on fired products.

How bad can efflorescence of soluble salts on fired ceramic be?


Soluble salts on terra cotta cup

Like this! This terra cotta clay matures to good strength around 1950F. Notice how the soluble salts have concentrated on the outer and most visible surface. The piece was dried upside down so of course, all the water had to escape through that route. A complicating factor is how handling of the piece at the leather hard stage has made it even more unsightly. This problem is common in many terra cotta materials but can also surface in others. Barium carbonate can be used to precipitate the salts inside the clay matrix so they do not come to the surface on drying. There is good news: Solubles salt deposition can actually be much worse than you see here.

Links

Articles Organic Matter in Clays: Detailed Overview
A detailed look at what materials contain organics, what its effects are in firing (e.g. black core), what to do to deal with the problem and how to measure the amount of organics in a clay material.
Glossary Deflocculation
Deflocculation is the magic behind the ceramic casting process, it enables slurries having impossibly low water contents and ware having amazingly low drying shrinkage
Glossary Efflorescence
A common problem with dry and fired ceramic. It is evident by the presence of a light or dark colored scum on the dry or fired surface.
Glossary Plucking
A firing issue in ceramics where the foot rings of vitreous ware stick to the kiln shelf. Removing them leaves sharp fragments glued to the shelf.
Materials Barium Carbonate
A pure source of BaO for ceramic glazes. This is 77% BaO and has an LOI of 23% (lost at CO2 on firing).
Hazards The Use of Barium in Clay Bodies
Considerations regarding the use of barium carbonate in pottery and structural clay bodies for precipitation of soluble salts.
By Tony Hansen
Follow me on

Got a Question?

Buy me a coffee and we can talk

 



https://digitalfire.com, All Rights Reserved
Privacy Policy