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Glaze Crazing

Crazed ceramic glazes have a network of cracks. Understanding the causes is the most practical way to solve it. 95% of the time the solution is to adjust the thermal expansion of the glaze.

Key phrases linking here: glaze crazing - Learn more

Details

Crazing is the opposite of shivering. It is a mismatch of thermal expansions between body and glaze (where that of the latter is higher). Glaze thermal expansion is a product of the chemistry (provided a glaze is completely melted). By far the most appropriate method to adjust expansion is to reduce the amount of high-expansion oxides (like sodium and potassium) and replace them with similar functioning oxides of lower thermal expansion (using glaze chemistry).

The principal home of information on this issue is in the troubleshooting section in the Crazing topic. Here we will concentrate on recognizing it and avoiding bad advice on dealing with it.

This page mostly assumes you can make your own glazes or are willing to question and assess the fit of commercial ones. Don't assume it is too hard to make a transparent glaze to fit your clay body. Or that it is too difficult to make a brushing glaze. Starting with a good base recipe that fits your clay body puts you ahead of any commercial product.

Bad advice on reducing crazing in stoneware glazes: These are from two popular pages (links below), pretty well every suggestion will not work! These are most treat-the-symptoms approaches but the bottom line is: If there is a thermal expansion mismatch between body and glaze it will reveal itself sooner or later no matter how you adjust firing or glaze thickness to hide the problem. ChatBots regurgitate the following wrong information - so it must appear internet-wide.
-Crazing can be corrected by adding materials with low expansion such as boron or reducing any high expansion materials such as feldspar (wrong, you need to trade oxides, not materials that source them - oxides of high expansion for those of low expansion - feldspar is a complex material, it also sources the most important oxides, SiO2 and Al2O3, these are lost when reducing it).
-Low expansion materials such as borate frit, silica, clay, or talc can be added a few percent at a time to a series of glaze tests (wrong, the most common borate frit, 3134, is very high expansion, the only low expansion common frit is 3249 but it will affect colors and surface character; adding silica only dilutes the KNaO, this only ever works for delayed crazing in gloss glazes melting well enough to tolerate an addition of a refractory powder; clays add SiO2 and Al2O3 so adding them only works if the glaze is short on both and over-melting anyway; adding talc will most often matt the glaze, or, if it is already matte, over-matte it).
-It is better to change one material at a time when trying to correct crazing (wrong, it is almost always best to change two oxides at a time, trading one for another; otherwise add or remove one oxide that is under or oversupplied).
-Increase the silica in the body (that only works if the body is silica-short otherwise it will cost maturity which will increase crazing, otherwise it will reduce maturity and increase crazing).
-Decrease the feldspar, in body or glaze (decreasing feldspar in a stoneware that needs it for maturity will increase crazing, decreasing it in a glaze that almost certainly needs it for melting will render it completely unsuitable).
-Decrease any other material containing sodium or potassium (same problem as reducing feldspar, but worse if the KNaO is more concentrated).
-Increase the boron (there is no useable source of pure B2O3 so you have to add a frit, sourcing enough boron from it will certainly over-melt the glaze or introduce many other oxides that will affect surface character).
-Increase the alumina, i.e. the clay content (clay sources twice as much SiO2 as Al2O3, the only case under which this will work is if the glaze happens to be short on both and their ratio is the same as in the clay).
-Increase lead oxide (no one in their right mind would put pure lead oxide into a glaze, why would any respectable website maintain a page that says this?).
These have in common approaching this problem on the material level, which is mostly wrong, it is a chemistry level issue.

Delayed Crazing: Ware that appears to be OK out-of-the-kiln can later craze. This happens on repeated exposures to sudden cooling during use (e.g. contact with the cold liquids). Ceramics do not perform well under tension, each time the glaze is suddenly stretched, by its thermal contraction on the unyielding body, its bond with the body can be affected. The situation is aggravated when ware is thick because the underlying body adjusts to the temperature change even more slowly. To stress-test your ware use the IWCT test. Any functional ware, from terra cotta to translucent porcelain, should survive this without crazing or shivering.

Crazing is often not easily visible when a glaze is colored or variegated, thus it is wise to use a heavy black marker pen (and then clean it off with methyl hydrate or other solvent) to reveal it. This has the additional benefit of revealing problems with glaze staining (these surfaces are difficult or impossible to clean).

Crazing can also occur in glazes on low-fire ware when the body absorbs water and expands. To avoid this it is best to leave a minimum of unglazed body surface and plug that with silicone sealant. Body formulations also often include calcium carbonate which is said to help prevent this phenomenon.

Related Information

ChatGPT is completely wrong about the cause of glaze crazing!

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A ChatGPT answer to a question about crazing

Today, ChatGPT is parroting common wrong suggestions about the cause and solution of the serious issue of crazing. Yet it trained on thousands of internet pages about the subject! Crazed functional ware is defective, and customers will return it. So fixing the problem is serious business, we need correct answers. Consider ChatGPT's suggestions: #1 is wrong. There is no such thing as an "incompatible mix" of ceramic materials. Crazing is an incompatibility in thermal expansions of glaze and body, almost always a result of excessive levels of high-expansion K2O and Na2O in the chemistry of the glaze. The solution is reducing them in favor of other fluxes (the amount per the degree of COE mismatch). #2 is wrong, firing changes don't fix the incompatibility of thermal expansions. #3 is wrong, refiring makes the crazing go away but not the stress of the mismatch, it will for sure return. #4 is completely wrong. Firing higher takes more quartz grains into solution in the melt and should reduce the COE (and mature the body more which often improves fit). And melt fluidity has nothing to do with crazing. Furthermore, if a glaze does not run off the ware, it is not overfired.

This is crazing. Crazing is bad on functional ware.

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A crazing glaze on a porcelain mug

The left glaze is "stretched" on the clay so it cracks (it calculates to a high thermal expansion so this is not a surprise). This usually appears after firing but can appear years later. When the lines are close together like this it is more serious. If the effect is intended, it is called "crackle" (but no one would intend this on functional ware). The one on the left calculates much lower - and stays uncrazed indefinitely. Potters, hobbyists and artists invariably bump into this issue whether using commercial glazes or making their own.

"Art language" solutions don't work, at least some technical words are needed to even understand what this simply is: A mismatch in the thermal expansions of glaze and body. Most ceramics expand slightly on heating and contract on cooling. Even though the amount of change is very small, ceramics are brittle so if a glaze is stretched on the ware, it will crack to relieve the stress. Crazing appears when ceramic is cooled and the glaze contracts more than the clay to which it is rigidly attached.

No crazing out of the kiln. But an ice-water test did this.

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Crazing mug

The side of this white porcelain test mug is glazed with varying thicknesses of V.C. 71 (a popular silky matte used by potters), then fired to cone 6. Out of the kiln, there was no crazing, and it felt silky and wonderful. But after a 300F/icewater IWCT this happened (it was felt-pen marked and cleaned with acetone). The glaze was apparently elastic enough to handle the gradual cooling in the kiln. However, the recipe has 40% feldspar and low Al2O3 and SiO2, in a cone 6 glaze these are red flags for crazing.

No matter what anyone tells you, glaze fit can rarely be fixed by firing differently (that just delays it). If someone needs to cool their kiln slowly to prevent crazing it simply means the glaze does not fit - its needs to be adjusted to reduce its co-efficient of thermal expansion.

Turning delayed crazing into immediate crazing

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This is a cone 04 clay (Plainsman Buffstone) with a transparent glaze (G1916Q which is 65% Frit 3195, 20% Frit 3110, 15% EPK). On coming out of the kiln, the glaze looked fine, crystal clear, no crazing. However, when heated to 300F and then immersed into ice water this happens. This is the IWCT test. At lower temperatures, where bodies are porous, water immediately penetrates the cracks and begins to waterlog the body below. Fixing the problem was easy: Substitute the low expansion Frit 3249 for high expansion Frit 3110.

Links

Troubles Glaze Crazing
Ask the right questions to analyse the real cause of glaze crazing. Do not just treat the symptoms, the real cause is thermal expansion mismatch with the body.
Glossary Glaze shivering
Shivering is a ceramic glaze defect that results in tiny flakes of glaze peeling off edges of ceramic ware. It happens because the thermal expansion of the body is too much higher than the glaze.
Glossary Crackle glaze
Crackle glazes have a crack pattern that is a product of thermal expansion mismatch between body and glaze. They are not suitable on functional ware.
Glossary Glaze Compression
In ceramics, glazes are under compression when they have a lower thermal expansion that the body they are on. A little compression is good, alot is bad.
Glossary Glaze fit
In ceramics, glaze fit refers to the thermal expansion compatibility between glaze and clay body. When the fit is not good the glaze forms a crack pattern or flakes off on contours.
Glossary Feldspar Glazes
Feldspar is a natural mineral that, by itself, is the most similar to a high temperature stoneware glaze. Thus it is common to see alot of it in glaze recipes. Actually, too much.
Glossary Thermal shock
When sudden changes in temperature cause dimensional changes ceramics often fail because of their brittle nature. Yet some ceramics are highly resistant.
Articles Is Your Fired Ware Safe?
Glazed ware can be a safety hazard to end users because it may leach metals into food and drink, it could harbor bacteria and it could flake of in knife-edged pieces.
URLs https://www.eieinstruments.com/tiles_&_ceramics_testing_instruments/autoclave_test/tiles-autoclave-crazing-test-autoclave-for-website
Tiles Autoclave - Crazing Test Autoclave
URLs https://ceramicartsnetwork.org/daily/article/common-glaze-faults-and-how-to-correct-them
Common Glaze Faults and How to Correct Them - Five wrong answers (from Dec 2023)
URLs https://ceramicartsnetwork.org/daily/article/How-to-Correct-Five-Common-Ceramic-Glaze-Defects
How to Correct Five Common Ceramic Glaze Defects - Five wrong answers recycled from the book "Ceramic Spectrum".
By Tony Hansen
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