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Break your addiction to online recipes that don't work or bottled expensive glazes. Learn why glazes fire as they do. Why each material is used. How to create perfect dipping and drying properties. Even some chemistry.
Likely you have already watched lots of Youtube videos and found there are many ways to approach ceramics. Hobbyists and artists often think of clay as a "canvas" and glazes as "paints", they imagine showcasing their painting skills with artistic designs, they enter with an expectation of few issues and creating the exact colors and surfaces they want (from the expensive bottled glazes they assume won't craze or shiver on their bodies). Others enter with the desire to mix their own clays, formulate their own glazes, build their own kilns and they relish the new things learned with each firing. These often embark on mixing recipes found on Pinterest, Glazy or Facebook, hoping they will somehow magically work.
In industry the prevailing culture is more and more toward dependence on suppliers, getting by with the least knowledge possible. We are often amazed at how little knowledge technicians working in huge factories sometimes have!
You may have realized by now that this site is dedicated to fighting these cultures (which we personify as "the glaze dragon"). Understanding glazes better can empower you in many ways.
It is about balance in the chemistry, not saturating it with heavy metals, about firing in the way appropriate for the recipe, about liner glazing. About knowing how to adjust. It’s not rocket science. It’s about not trusting anything with significant percentages of colorants (or things like barium carbonate, lithium carbonate), even commercial glazes, without doing simple leach testing. Just get started taking the new approaches mentioned here and you will become opinionated about leaching in no time!
If you are going to make ceramic ware, put good glazes on it. Remember, a glaze is a lot more than one that just has a pleasing fired appearance. There is no one-glaze-that-works-for-everyone. We cater to people that want to start out right, or have been kicked around long enough that they are ready to learn why, they want to "understand". You will never likely get the glazes you really want until you formulate or adapt them yourself.
The left glaze is "stretched" on the clay so it cracks (it calculates to a high thermal expansion so this is not a surprise). This usually appears after firing but can appear years later. When the lines are close together like this it is more serious. If the effect is intended, it is called "crackle" (but no one would intend this on functional ware). The one on the left calculates much lower - and stays uncrazed indefinitely. Potters, hobbyists and artists invariably bump into this issue whether using commercial glazes or making their own.
"Art language" solutions don't work, at least some technical words are needed to even understand what this simply is: A mismatch in the thermal expansions of glaze and body. Most ceramics expand slightly on heating and contract on cooling. Even though the amount of change is very small, ceramics are brittle so if a glaze is stretched on the ware, it will crack to relieve the stress. Crazing appears when ceramic is cooled and the glaze contracts more than the clay to which it is rigidly attached.
The original cone 6 recipe, WCB, fires to a beautiful brilliant deep blue green (shown in column 2 of this Insight-live screen-shot). But it is crazing and settling badly in the bucket. The crazing is because of high KNaO (potassium and sodium from the high feldspar). The settling is because there is almost no clay. Adjustment 1 (column 3 in the picture) eliminates the feldspar and sources Al2O3 from kaolin and KNaO from Frit 3110 (preserving the glaze's chemistry). To make that happen the amounts of other materials had to be juggled. But the fired test revealed that this one, although very similar, is melting more (because the frit releases its oxides more readily than feldspar). Adjustment 2 (column 4) proposes a 10-part silica addition. SiO2 is the glass former, the more a glaze will accept without losing the intended visual character, the better. The result is less running and more durability and resistance to leaching.
Three cone 6 commercial bottled glazes have been layered. The mug was filled with lemon juice overnight. The white areas indicate leaching has occurred! Why? Glazes need high melt fluidity to produce reactive surfaces like this. While such normally tend to leach metals, supposedly the manufacturers were able to tune the chemistry enough to pass tests. But the overlaps interact, like drug interactions they are new chemistries. Cobalt is clearly leaching. What else? We do not know, these recipes are secret. It is better to make your own transparent or white liner glaze (either as a dipping glaze or brushing glaze). Better to know the recipe to have assurance of adherence to basic recipe limits.
Are commercial glazes really guaranteed food safe? When manufacturers claim adherence to standards like ASTM D-4236 what are they saying? The small amounts of liquid glazes are safe for the artist to brush on. They are not making claims about leaching on finish ware.
To make a low SG version of G2934BL I have already weighed out a 340g batch (it contains 5g each of Veegum and CMC gum to gel the slurry and slow the drying). I use 440g of water initially (adjusting that according to experience in brushing behaviour). After shake-mixing all the powder in the plastic bag I pour it into the water on low speed and finish with 20 seconds on high speed. This produces a low specific gravity brushing glaze, it just fills this 500ml jar. In subsequent batches, I adjust the Veegum for more or less gel and the CMC for slower or faster drying. Later I also assess whether the CMC gum is being degraded by microbial attack - often evident if the slurry thins and loses its gel. Since each glaze recipe responds differently and changes differently over time, good notes are essential. We are working on dozens of these at any given time, each is code-numbered in our group account at Insight-live.com. This is so worthwhile doing that I make quality custom labels for each jar!
Yes. In this case the entire outside and inside of the mug need an evenly applied coat of glaze. For hobby this makes sense. But in production cover brushing makes less sense. The right pail has 2 gallons of G2934Y base with 10% Cerdec yellow stain: $135. Cost of brushing jars with the same amount: $600+! And each jar logs 10-15 minutes painting time plus waiting between coats. The one in the pail is a true dipping glaze (unlike many commercial ones that dry slowly and drip-drip-drip). This one dries immediately after dipping in a perfectly even layer (if mixed according to our instructions). And a bonus: This pail can be converted to brushing or base-layering versions using CMC gum.
This is a clear glaze (G2931K) with 10% purple stain (Mason 6385). The mugs are cone 03 porcelain (Zero3). The mug on the left was dipped (at the bisque stage) into a slurry of the glaze (having an appropriate specific gravity and thixotropy). The glaze dried in seconds. The one on the right was painted on (two layers). Like any paint-on glaze, it contains gum (1% CMC). Each layer required several minutes of application time and fifteen minutes of drying time. Yet it is still not evenly applied.
Brushing glazes are great sometimes. But they would be even greater if the recipe was available. Then it would be possible to make it if they decide to discontinue the product. Or if your retailer does not have it. Or to make a dipping glaze version for all the times when that is the better way to apply. The glaze manufacturer did not consider glaze fit with your clay body, if they work well together it is by accident. But if you have transparent and matte base recipes that that work on your clay body then adding stains, variegators and opacifiers is easy. And making a brushing glaze version of any of them. Don't have base recipes??? Let's get started developing them with an account at insight-live.com (and the know-how you will find there)!
These are two pallets (of three) that went on a semi-trailer load to a Plainsman Clays store in Edmonton this week. They are packed with hundreds of bags of powders used to mix glazes. More and more orders for raw ceramic materials are coming in all the time. Maybe you are using lots of bottled glazes but for a cover or a liner glaze it is better to mix your own. And cheaper! And there are lots of recipes and premixed powders here to do it. One of the big advantages is that when you dip ware into a properly mixed slurry it goes on perfectly even, does not run and dries on the bisque in seconds. No bottled glaze can do that.
There is a direct relationship between the way ceramic glazes fire and their chemistry. These green panels in my Insight-live account compare two glaze recipes: A glossy and matte. Grasping their simple chemistry mechanisms is a first step to getting control of your glazes. To fixing problems like crazing, blistering, pinholing, settling, gelling, clouding, leaching, crawling, marking, scratching, powdering. To substituting frits or incorporating available, better or cheaper materials while maintaining the same chemistry. To adjusting melting temperature, gloss, surface character, color. And identifying weaknesses in glazes to avoid problems. And to creating and optimizing base glazes to work with difficult colors or stains and for special effects dependent on opacification, crystallization or variegation. And even to creating glazes from scratch and using your own native materials in the highest possible percentage.
These are cone 6 Alberta Slip recipes that have been brushed onto the outsides of these mugs (three coats gave very thick coverage). Recipes are GA6-C Rutile Blue on the outside of the left mug, GA6-F Alberta Slip Oatmeal on the outside of the center mug and GA6-F Oatmeal over G2926B black on the outside of the right mug). These are examples of high specific gravity brushing glazes. One-pint jars are made using 500g of glaze powder, 280g of water and 75g of Laguna CMC gum solution (equivalent to 1%). Because no Veegum is being used this blender mixes to a slurry of super high 1.6 specific gravity (SG). Commercial glazes have a much lower specific gravity (thus much more water), giving better paintability and gelling but requiring more coats. Still, this approach is good for Alberta Slip because it is highly plastic and comprises the bulk of the recipe. The gum removes the need to roast 50% of it and the plasticity of the Alberta Slip helps suspend the slurry.
These cone 6 porcelain mugs are hybrid. Three coats of a commercial glaze painted on the outside (Amaco PC-30) and my own liner glaze, G2926B, poured in and out on the inside. When commercial glazes (made by one company) fit a stoneware or porcelain (made by another company) it is by accident, neither company designed for the other! For inside food surfaces make or mix a liner glaze already proven to fit your clay body, one that sanity-checks well (as a dipping glaze or a brushing glaze). In your own recipes you can use quality materials that you know deliver no toxic compounds to the glass and that are proportioned to deliver a balanced chemistry. Read and watch our liner glazing step-by-step and liner glazing video for details on how to make glazes meet at the rim like this.
This is what you need to be independent, to create your own manufacturing company in your garage in 2021 Some of the prices are "instead of" rather than additive. There are many approaches to glazes, the more you are willing to learn the better you will be able to make your own (and save a lot). We recommend the cone 6 range using a small test kiln (like this 220v ConeArt GX119, don't scrimp on this, go for quality and the practicality of a Genesis controller). A kiln you can fire often and inexpensively is a key enabler to learning, developing techniques, products, designs, durable and decorative surfaces, solving problems. It can be fired multiple times a day. And it is big enough for mugs and similar sizes. It will get you into the habit of using some of your creativity for experimenting. It will give you the successes early on that will inspire you to press on learning. When you are ready, then get a big kiln and hit-the-ground-running. This potter's wheel is the best available and will last a lifetime, these often appreciate in value over time. And, build yourself a good plaster table. You will use it constantly. Not shown here is a propeller mixer, also an important tool. And you will need a sink equipped with a sink trap (Gleco Trap).
Books and web pages with flashy pictures are the centrepiece of an addiction-ecosystem to recipes that often just don't work. Maybe these are "tried" by a lot of people. But are they "true"? Most are so-called "reactive glazes", outside normal practice - to produce visual interest they run, variegate, crystallize, pool, break, tint, go metallic, etc. But this happens at a cost. And inside special procedures and firing schedules that need explaining. It is not obvious these are understood by the recipe authors or sharers. And these recipes are dated and contain troublesome and unavailable materials. We use frits now to source boron. Stains are superior to raw colorants, even in glazes like this. Many of these will craze badly. And many will not suspend in the bucket. And will run during firing. Reactive glazes have other common issues: Blistering, leaching, cutlery marking, fuming. Trying colors in differing amounts in different base recipes is a good idea. But the project is most beneficial when it shows color response in terms of quality recipes of contrasting chemistries. The point of all of this: Understand a few glazes and develop them, rather than throwing spaghetti against the wall hoping something sticks. Commercial reactive glazes are an alternative also.
Material prices are sky rocketing. And, the more complex your supplier's supply chain the more likely they won't be able to deliver. How can you adapt to coming disruption, even turn it into a benefit? Learn to create base recipes for your glazes and even clay bodies. Learn now how to substitute frits and other materials in glazes (get the chemistry of frits you use now so you are ready). Even better: Learn to see your glaze as an oxide formula. Then calculate formula-to-batch to use whatever materials you can get. Learn how to adjust glazes for thermal expansion, temperature, surface, color, etc. And your clay bodies? Develop an organized physical testing regimen now to accumulate data on their properties, learn to understand how each material in the recipe contributes to those properties. Armed with that data you will be able to adjust recipes to adapt to changing supplies.
Material prices were sky rocketing (and still are). Prepared glaze manufacturers have complex international supply chains. Now might be the time to start learning how to weigh out the ingredients to make your own. Armed with good base glazes that fit your clay body (without crazing or shivering) you will be more resilient to supply issues. Add stains, opacifiers and variegators to the bases to make anything you want. That being said, ingredients in those recipes may become unavailable! That underscores a need to go to the next step and "understand" glaze ingredients. And even improve and adjust recipes. It is not rocket science, it is just work accompanied by organized record-keeping and good labeling.
This recipe is from page 2 of the booklet: "15 Tried & True Cone 6 Glaze Recipes". Click the following code, G3955, to see more information on how it compares with G2934 and G1214Z1 mattes. This flow test and these test tiles were in the same kiln, fired at cone 6 using our PLC6DS schedule. The defining characteristic of N505 is its extreme melt fluidity - it runs because it is overtired at cone 6. Still, the surface on the tile (lower right) is arguably more interesting than G2934. Some felt pen marking reveals why: The micro surface is much rougher. To its credit, although it does stain easier, it can still be cleaned with effort.
From the chemistry, shown on Insight-Live side-by-side screenshot. It has very low Al2O3 and SiO2 - that turns on some red and yellow lights. One could hope to have melt fluidity and great functionality, but they pretty well never go together. This glaze should fire glossy - the 6% magnesium carbonate is the mechanism of the matteness - MagCarb is super refractory, it may not be dissolving in the. melt. The glaze should cutlery mark (although it seemed hard in our testing). Most important, low Si:Al levels always carry the risk of leaching - exercise caution adding any significant percentage of heavy metal pigments. Crazing is another possible issue over melted glaze.
You will see examples of replacing unavailable materials (especially frits), fixing various issues (e.g. running, crazing, settling), making them melt more, adjusting matteness, etc. Insight-Live has an extensive help system (the round blue icon on the left) that also deals with fixing real-world problems and understanding glazes and clay bodies.
These are cone 6 commercial glazes made by a popular US manufacturer. The body is a cone 6 casting porcelain made by another popular manufacturer. Zoom the photo to see they are all crazing! Which company is at fault? Neither is able to assure a match of their product to others. The pattern we see here points the finger first at the body. Mid-fire porcelains craze glazes if they lack sufficient silica (20% is minimum). It is difficult for manufacturers to achieve this since more feldspar, at the expense of silica, is needed to vitrify the body. And the recipe of the porcelain is proprietary. You already have a propeller mixer, scale and containers so why not mix your own porcelain from a recipe (e.g. L3778D or derivative)? Glaze fit is also a matter of chance. Mixing your own transparent brushing glaze or dipping glaze would provide another level of control (e.g. G2926B or derivative).
I used Veegum to form 10 gram GBMF test balls and fired them at cone 08 (1700F). Frits melt really well, they do have an LOI like raw materials. These contain boron (B2O3), it is a low expansion super-melter that raw materials don’t have. Frit 3124 (glossy) and 3195 (silky matte) are balanced-chemistry bases (just add 10-15% kaolin for a cone 04 glaze, or more silica+kaolin to go higher). Consider Frit 3110 a man-made low-Al2O3 super feldspar. Its high-sodium makes it high thermal expansion. It works really well in bodies and is great to make glazes that craze. The high-MgO Frit 3249 (made for the abrasives industry) has a very-low expansion, it is great for fixing crazing glazes. Frit 3134 is similar to 3124 but without Al2O3. Use it where the glaze does not need more Al2O3 (e.g. already has enough clay). It is no accident that these are used by potters in North America, they complement each other well (equivalents are made around the world by others). The Gerstley Borate is a natural source of boron (with issues frits do not have).
These GLFL tests and GBMF tests for melt-flow compare 6 unconventionally fluxed glazes with a traditional cone 6 moderately boron fluxed (+soda/calcia/magnesia) base (far left Plainsman G2926B). The objective is to achieve higher melt fluidity for a more brilliant surface and for more reactive response with colorant and variegator additions (with awareness of downsides of this). Classified by most active fluxes they are:
G3814 - Moderate zinc, no boron
G2938 - High-soda+lithia+strontium
G3808 - High boron+soda (Gerstley Borate based)
G3808A - 3808 chemistry sourced from frits
G3813 - Boron+zinc+lithia
G3806B - Soda+zinc+strontium+boron (mixed oxide effect)
This series of tests was done to choose a recipe, that while more fluid, will have a minimum of the problems associated with such (e.g. crazing, blistering, low run volatility, susceptibility to leaching). As a final step the recipe will be adjusted as needed. We eventually evolved the G3806B, after many iterations settled on G3806E or G3806F as best for now.
Articles |
G1214M Cone 5-7 20x5 glossy transparent glaze
This is a base transparent glaze recipe developed for cone 6. It is known as the 20x5 or 20 by 5 recipe. It is a simple 5 material at 20% each mix and it makes a good home base from which to rationalize adjustments. |
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Articles |
G1916M Cone 06-04 transparent glaze
This is a frit based boron glaze that is easily adjustable in thermal expansion, a good base for color and a starting point to go on to more specialized glazes. |
Articles |
Working with children
Go in with both eyes open if you are planning to work with clay with a group of children! A lot can go wrong but it can be unforgettable for them when it goes right. |
Projects |
Oxides
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Projects |
Recipes
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Glossary |
Glaze Chemistry
Glaze chemistry is the study of how the oxide chemistry of glazes relate to the way they fire. It accounts for color, surface, hardness, texture, melting temperature, thermal expansion, etc. |
Glossary |
Thixotropy
Thixotropy is a property of ceramic slurries of high water content. Thixotropic suspensions flow when moving but gel after sitting (for a few moments more depending on application). This phenomenon is helpful in getting even, drip-free glaze coverage. |
Glossary |
Limit Formula
A way of establishing guideline for each oxide in the chemistry for different ceramic glaze types. Understanding the roles of each oxide and the limits of this approach are a key to effectively using these guidelines. |
Glossary |
Glaze Recipes
Stop! Think! Do not get addicted to the trafficking in online glaze recipes. Learn to make your own or adjust/adapt/fix what you find online. |
Glossary |
Ceramic Oxide
In glaze chemistry, the oxide is the basic unit of formulas and analyses. Knowledge of what materials supply an oxide and of how it affects the fired glass or glaze is a key to control. |
Glossary |
Decomposition
In ceramic manufacture, knowing about the how and when materials decompose during firing is important in production troubleshooting and optimization |
Glossary |
Mechanism
Identifying the mechanism of a ceramic glaze recipe is the key to moving adjusting it, fixing it, reverse engineering it, even avoiding it! |
Glossary |
Brushing Glaze
Hobbyists and increasing numbers of potters use commercial paint-on glazes. It's convenient, there are lots of visual effects. There are also issues compared to dipping glazes. You can also make your own. |
Glossary |
Rheology
In ceramics, this term refers to the flow and gel properties of a glaze or body suspension (made from water and mineral powders, with possible additives, deflocculants, modifiers). |
Glossary |
Glaze Mixing
In ceramics, glazes are developed and mixed as recipes of made-made and natural powdered materials. Many potters mix their own, you can to. There are many advantages. |
Glossary |
Reactive Glazes
In ceramics, reactive glazes have variegated surfaces that are a product of more melt fluidity and the presence of opacifiers, crystallizers and phase changers. |
Glossary |
Digitalfire Taxonomy
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Glossary |
Base Glaze
Understand your a glaze and learn how to adjust and improve it. Build others from that. We have bases for low, medium and high fire. |
URLs |
https://digitalfire.com/videos
Tutorial Videos at Digitalfire |
Recipes |
G2926B - Cone 6 Whiteware/Porcelain transparent glaze
A base transparent glaze recipe created by Tony Hansen for Plainsman Clays, it fires high gloss and ultra clear with low melt mobility. |
Recipes |
G2934 - Matte Glaze Base for Cone 6
A base MgO matte glaze recipe fires to a hard utilitarian surface and has very good working properties. Blend in the glossy if it is too matte. |
Recipes |
G2931K - Low Fire Fritted Zero3 Transparent Glaze
A cone 03-02 clear medium-expansio glaze developed from Worthington Clear. |
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