Particle Size Distribution of Ceramic Powders

Description

Understanding the theory behind sieve selection, how to properly sample a powder and how to carry out a particle size distribution test can give you valuable information about a material.

Article

Particle size is one of the most important properties of clays and ceramic minerals. One gram of powdered material can have billions of particles with a surface area of many square meters. A knowledge of not only the average size but how the sizes are distributed, can be very valuable.

The sieve analysis test I recommend is performed by slurrying and soaking a clay sample in water and then washing it through a series of successively finer and finer interlocking screens (this can be done on a plastic or lump clay material by drying and then slaking it thoroughly in water first). This test is important in monitoring consistency of clay and material powders (unlike most of the other tests I recommend, this one does require that you purchase equipment you cannot easily make).

Particle size tests are important in many industries (e.g. cement) and sieves have thus become highly standardized. Usually screens are chosen so that each has an opening with double the area of the one below it. This is referred to as a series because the width of the 'root of two' opening is the root of two (or 1.414) times that of the previous. Screens can be referenced in mesh sizes (a 100 mesh screen has about 100 wires per inch) or dimensions of the opening. They are calibrated from a standard 200 mesh having an opening of 0.0029". A good brass sieve can cost $150 or more and must be treated with care.

Methods of recording and presenting the data are very important and sieve manufacturers provide helpful books. The W.S. Tyler company, for example, is a manufacturer of quality sieves and publishes a very interesting book called 'Testing Sieves and Their Uses'.

Insight-live.com defines a test abbreviated 'SIEV', it clearly defines the procedure to use to perform a particle size appraisal of a material. It also provides information on the reasons why the test should be a part of your standard testing regimen.
One of the most important aspects of doing sieve analysis tests is the matter of selecting a representative specimen to test. It does little good to graph in detail an analysis if the specimen is not typical. The diagram shown here illustrates one method.

Taking A Representative Specimen

In addition to controlling material consistency and spotting impurities, sieve analysis tests are valuable in making formulation decisions. For example, the strongest and best clays are made dense by a good distribution of particle sizes at plus 325 mesh. In this way, there is a good packing in the dried matrix and therefore maximum green strength and minimum low temperature absorption. Bodies with a distribution of particle sizes tend to be comparatively stronger in the fired state and tend to have more robust working and drying properties than those made from the same materials ground to a fine mesh size. Particles of 100 mesh or finer do not generally have a noticeable texture (they feel smooth) but are easily detected by a sieve analysis.

A sieve analysis test can also alert you to trouble. It will show if coarser or agglomerated particles are present in a body presenting the danger of pinholing and premature bloating (especially in oxidation firing if the particles are "undesirables" e.g. coal, plaster, concretions). The open nature of a coarser body can also invite pinholing and pitting in less viscous glazes.

Clays with sand or grog additions in a very fine plastic particle size matrix often lack intermediate sizes and can micro-crack around each large particle. This phenomenon, although invisible to the eye, is evident not only by the dead 'thud' when a piece is tapped with a pen but by a sieve analysis of the raw material. A sieve analysis can be employed to incorporate a coarser clay or a finer grog or sand.

Related Information

A root-of-two series of test sieves

The coarsest screen is at the top, the finest on the bottom. The top one has an opening of 425 microns (thus 425 micron and finer particles will pass through it, +425 micron particles will not). Its opening area is 180,000 square microns (425x425). Going downward, the openings have areas half that of the one above (thus, for the second, the opening area is 300x300=90,000 microns). Structural products industries, like brick, measure coarser particles than this, using 10-70 mesh. Using this series one can produce a standard measurement of the distribution of particle sizes in a material powder. The finer sieves (from 100-325) are only practical for wet processing (where the powder is water washed through the stack). In Insight-live the SIEV test (water washed) uses this series of sieves.

This is what labs use to measure particle size

Two example of high quality brass laboratory sieves

To measure particle size in a slurry or powder you need sieves. This is the most popular type used in labs. They are made from brass by a company named Tyler. The range of screen sizes for testing particle size is very wide (obvious here: the top screen has an opening of 56 mm, the bottom one 0.1 mm - the wires are almost too small to see). You can often buy these used on Ebay for a lot less than new ones, search for "tyler sieve". The finer sieves (especially 200) are fragile and more easily ripped. For potters it is good to have a 50, 100 and 150.

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By Tony Hansen
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