Array ( [status] => 200 [status_message] => Material item [data] => Array ( [material_id] => 3395 [moddate] => 2023-03-10 20:43:42 [name] => Mason 6304 Violet Chrome Tin [keywords] => [metadescrip] => An encapsulated purple stain. Purple is very difficult in ceramic glazes and this stain delivers incredible color in glossy glazes. [chem_formula] => [casnumber] => [searchkey] => [unity] => [ratio] => [ord] => [minedat] => [notes] => Chrome Tin Pink Sphene, a reaction product of high temperature calcination in which Calcium (II) Oxide, Tin (IV) Oxide, Silicon (IV) Oxide, and Chromium (III) Oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of tin sphene. Its composition may include either or both of the modifiers B2O3 and PbO. [links] => Array ( [typecode] => Array ( [0] => Array ( [link] => typecode/STN [descrip] => [label] => Ceramic Stain [ord] => 0 ) ) [supplier] => Array ( [0] => Array ( [link] => supplier/Mason+Color+Works+Inc [label] => Mason Color Works Inc [ord] => 0 ) ) [url] => Array ( [0] => Array ( [link] => url/1720 [label] => http://www.masoncolor.com/ceramic-stains/purples/6304-violet-chrome-tin [descrip] => Mason 6304 stain page [note] => [ord] => 0 ) ) ) [pictures] => Array ( [2187] => Array ( [z] => AWQAEXMTQW [alttag] => Mugs with red and purple glaze stains [titletag] => [title] => When using stains, customize the percentage, host glaze and firing schedule [notes] => These are G2926B clear glazes with stains added and fired at cone 6. The one on the left has 11% Mason 6021 encapsulated red. It is pebbling the surface (even with 2% zircon), it may be at the upper end of its firing range. Possible solutions are faster firing up and down to give the stain less chance to decompose. Or firing at cone 5 instead. Or a drop-and-hold firing schedule. Or a lower percentage, that could impart a bit of variation where it is thicker and thinner (like the purple one). A different host glaze, perhaps one with less boron. The purple one has 10% Mason 6304, it is not affecting the glossy glaze surface. But the percentage needs to be higher to prevent the wash-out of color where it is applied thinner. [filename] => rgaxa5s2cc.jpg [path] => images/pictures/ [fullpath] => /var/www/digitalfire.com/4sight/images/pictures/ [fullurl] => https://digitalfire.com/4sight/images/pictures/ [picture_date] => 2018-06-02 21:38:32 [S3URL] => https://reference.s3.us-west-2.amazonaws.com/images/pictures/rgaxa5s2cc.jpg [S3Date] => 2018-06-02 21:39:02 [timelinephoto] => 1 [ord] => 0 [direction] => out [url] => ) [2318] => Array ( [z] => yvomh6mwyN [alttag] => [titletag] => [title] => Brushing glazes can go on very unevenly, adding stain can help [notes] => Both of these were glazed by brushing. The inside transparent and white glazes are fairly easy to apply evenly but the bright color on the outside left one certainly is not. The problem is a combination of things. It is difficult to apply it evenly with a brush. It is difficult to get it on thick enough. And this commercial glaze does not contain enough of the purple stain (so I added 6 grams of Mason 6304 Violet stain powder to the 2/3 of a jar I had left, and mixed thoroughly). That, more careful brushing, and an extra layer produced the piece on the right! [filename] => yn3ly4jgn4.jpg [path] => images/pictures/ [fullpath] => /var/www/digitalfire.com/4sight/images/pictures/ [fullurl] => https://digitalfire.com/4sight/images/pictures/ [picture_date] => 2019-04-23 13:11:27 [S3URL] => https://reference.s3.us-west-2.amazonaws.com/images/pictures/yn3ly4jgn4.jpg [S3Date] => 2019-04-23 13:18:02 [timelinephoto] => 1 [ord] => 0 [direction] => out [url] => ) [2392] => Array ( [z] => SHe9dcjJXL [alttag] => [titletag] => [title] => G2926B with 10% Mason 6304 Stain on Polar Ice Casting [notes] => 2% zircon also was also added, it helps prevent micro-bubbling. The PLC6DS (drop and soak) firing schedule was used. The G3806 base clear glaze is normally better than G2926B for really bright colors but this stain is an exception. [filename] => jabdmwn7jr.jpeg [path] => images/pictures/ [fullpath] => /var/www/digitalfire.com/4sight/images/pictures/ [fullurl] => https://digitalfire.com/4sight/images/pictures/ [picture_date] => 2019-07-03 17:39:51 [S3URL] => https://reference.s3.us-west-2.amazonaws.com/images/pictures/jabdmwn7jr.jpeg [S3Date] => 2019-07-03 17:42:02 [timelinephoto] => 0 [ord] => 0 [direction] => out [url] => ) [2605] => Array ( [z] => p483ArhNYH [alttag] => Buttons of fired porcelain of many colors [titletag] => [title] => Polar Ice Porcelain with Body Stains - by Robert Barritz [notes] => Robert has done really valuable work in this research, what an amazing range of color! Surfaces are unpolished and unglazed. All are fired to cone 6. Browns are missing, they can be made using iron oxide. For blacks, Mason 6600 is also effective. The blues can be intense using lower percentages than shown here, as low as 2% can be effective. There is an optimal amount for each stain, beyond that, big increases in percentage bring less increase in color intensity. There is another reason to keep stain percentages to a minimum: To reduce the impact on body maturity (and firing shrinkage). Blues, for example, can significantly heighten the degree of vitrification, even melting the porcelain. If you plan to marble different colors, keeping stain percentage as low as possible is even more important, unless you can do fired shrinkage compatibility testing, for example, the EBCT test. Need to develop your own white porcelain? See the link below. [filename] => 6m9mf2c4zi.jpg [path] => images/pictures/ [fullpath] => /var/www/digitalfire.com/4sight/images/pictures/ [fullurl] => https://digitalfire.com/4sight/images/pictures/ [picture_date] => 2020-09-01 10:01:16 [S3URL] => https://reference.s3.us-west-2.amazonaws.com/images/pictures/6m9mf2c4zi.jpg [S3Date] => 2020-09-01 10:03:02 [timelinephoto] => 1 [ord] => 0 [direction] => out [url] => ) ) ) ) Mason 6304 Violet Chrome Tin
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Mason 6304 Violet Chrome Tin

Notes

Chrome Tin Pink Sphene, a reaction product of high temperature calcination in which Calcium (II) Oxide, Tin (IV) Oxide, Silicon (IV) Oxide, and Chromium (III) Oxide in varying amounts are homogeneously and ionically interdiffused to form a crystalline matrix of tin sphene. Its composition may include either or both of the modifiers B2O3 and PbO.

Related Information

When using stains, customize the percentage, host glaze and firing schedule

Tap picture for full size and resolution
Mugs with red and purple glaze stains

These are G2926B clear glazes with stains added and fired at cone 6. The one on the left has 11% Mason 6021 encapsulated red. It is pebbling the surface (even with 2% zircon), it may be at the upper end of its firing range. Possible solutions are faster firing up and down to give the stain less chance to decompose. Or firing at cone 5 instead. Or a drop-and-hold firing schedule. Or a lower percentage, that could impart a bit of variation where it is thicker and thinner (like the purple one). A different host glaze, perhaps one with less boron. The purple one has 10% Mason 6304, it is not affecting the glossy glaze surface. But the percentage needs to be higher to prevent the wash-out of color where it is applied thinner.

Brushing glazes can go on very unevenly, adding stain can help

Tap picture for full size and resolution

Both of these were glazed by brushing. The inside transparent and white glazes are fairly easy to apply evenly but the bright color on the outside left one certainly is not. The problem is a combination of things. It is difficult to apply it evenly with a brush. It is difficult to get it on thick enough. And this commercial glaze does not contain enough of the purple stain (so I added 6 grams of Mason 6304 Violet stain powder to the 2/3 of a jar I had left, and mixed thoroughly). That, more careful brushing, and an extra layer produced the piece on the right!

G2926B with 10% Mason 6304 Stain on Polar Ice Casting

Tap picture for full size and resolution

2% zircon also was also added, it helps prevent micro-bubbling. The PLC6DS (drop and soak) firing schedule was used. The G3806 base clear glaze is normally better than G2926B for really bright colors but this stain is an exception.

Polar Ice Porcelain with Body Stains - by Robert Barritz

Tap picture for full size and resolution
Buttons of fired porcelain of many colors

Robert has done really valuable work in this research, what an amazing range of color! Surfaces are unpolished and unglazed. All are fired to cone 6. Browns are missing, they can be made using iron oxide. For blacks, Mason 6600 is also effective. The blues can be intense using lower percentages than shown here, as low as 2% can be effective. There is an optimal amount for each stain, beyond that, big increases in percentage bring less increase in color intensity. There is another reason to keep stain percentages to a minimum: To reduce the impact on body maturity (and firing shrinkage). Blues, for example, can significantly heighten the degree of vitrification, even melting the porcelain. If you plan to marble different colors, keeping stain percentage as low as possible is even more important, unless you can do fired shrinkage compatibility testing, for example, the EBCT test. Need to develop your own white porcelain? See the link below.

Links

Oxide Analysis Formula
Typecodes Ceramic Stain
URLs http://www.masoncolor.com/ceramic-stains/purples/6304-violet-chrome-tin
Mason 6304 stain page
By Tony Hansen
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