Hectorite

Description: Hectorite

Oxide	Analysis	Formula
SiO2	53.75%	1.23
Al2O3	0.35%	-
MgO	25.50%	0.87
CaO	0.35%	0.01
Li2O	1.20%	0.06
Na2O	3.00%	0.07
K2O	0.15%	-
H2O	14.40%	n/a
Cl	0.30%	n/a
Oxide Weight		115.60
Formula Weight		135.52

Notes

Hectorite - (Mg,Li)3 Si₄O10 (OH)2 Na0.3 (H₂O)4 is lithium magnesium sodium montmorillonite (bentonite is largely sodium calcium magnesium montmorillonite). Typically hectorite contains much less iron and titanium than bentonite and contains almost no alumina (being essentially a hydrated silicate). In addition, it is very high in magnesia compared to other clays.

While 1-2% iron content in regular bentonite has minimal effect on fired whiteness, tiny amounts of titanium do affect translucency, making otherwise whiteware look grey. This is attributed to fibrous rutile crystals in the porcelain matrix. In addition, titanium can react with any iron present to produce Fe/Ti spinel which is intensely black in colour.

The purest kaolins are also the least plastic, plastic ball clays are high in Fe/Ti. This makes hectorite an interesting material for the best white porcelain.

Analysis from Handbook of Mineralogy, 2001.

Related Information

Links

Materials	Hectabrite White magnesium-rich surface-modified highly purified sodium hectorite clay 4-5 times more efficient than raw bentonite.
Materials	Attapulgite
Materials	Bentonite Bentonite can make a clay body instantly plastic, only 2-3% can have a big effect. It also suspends slurries so they don't settle out and slows down drying.
Materials	Hectalite 200
Materials	Hectalite GM
Materials	Bentone MA
Typecodes	Clay Other Clays that are not kaolins, ball clays or bentonites. For example, stoneware clays are mixtures of all of the above plus quartz, feldspar, mica and other minerals. There are also many clays that have high plasticity like bentonite but are much different mineralogically.
Minerals	Hectorite An uncommon fine-grained highly plastic clay mineral related to bentonite. Named after Hector, CA. F
Articles	Formulating a Porcelain The principles behind formulating a porcelain are quite simple. You just need to know the purpose of each material, a starting recipe and a testing regimen.

By Tony Hansen
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