•The secret to cool bodies and glazes is alot of testing.
•The secret to know what to test is material and chemistry knowledge.
•The secret to learning from testing is documentation.
•The place to test, do the chemistry and document is an account at https://insight-live.com
•The place to get the knowledge is https://digitalfire.com
Crawling is where the molten glaze withdraws into 'islands' leaving bare clay patches. The edges of the islands are thickened and smoothly rounded. In moderate cases there are only a few bare patches of clay, in severe cases the glaze forms beads on the clay surface and drips off onto the shelf. The problem is prevalent in once-fire ware and where bisque-applied glazes contain excessive plastic clay content.
Is the glaze shrinking too much during drying?
If the dried glaze forms a network of cracks it is a sign that the glaze is shrinking too much. The fault lines provide places for the crawling to start (especially where the islands the cracks delineate have raised edges that are no longer in contact with the body).
There are a number of possible contributors:
- If very fine-particled materials are present (i.e. zinc, bone ash, light magnesium carbonate) these will contribute to higher shrinkage during drying. Try using calcined zinc, synthetic bone ash or another source of calcia, talc or dolomite to source magnesia instead of magnesium carbonate.
- It is normal to see 20% clays (ball clay, kaolin). If significantly more is present try using a less plastic clay (i.e. kaolin instead of ball clay, low plasticity kaolin instead of high plasticity kaolin, or a mix of calcined and raw kaolin). If you are using Gerstley borate (it is plastic like a clay), try a boron frit. You may need to do calculations to make these adjustments. Ultimately you need to tune the glaze's clay content to achieve a compromise of good hardness and minimal shrinkage while maintaining the chemistry.
- If a glaze has been ball milled for too long it may shrink excessively (for example, zircon opacified glazes can be ground more finely than tin ones). Highly ground glazes may produce a fluffy lay down.
- If a slurry has flocculated (due to changes in water, dry material additions like iron oxide, or addition of an acid, epsom salts, calcium chloride, etc) it will require more water to achieve the same flow and will therefore shrink more during drying and require a longer period to dry. Try using distilled water. Always measure the specific gravity to maintain solids content and use deflocculants/flocculants if necessary to thin/thicken the slurry (you can remove water from an existing glaze slurry by pouring some on a plaster batt, then mixing the water-reduced mass back in).
- Gerstley Borate is plastic and therefore contributes to glaze shrinkage, especially if the recipe also contains kaolin or ball clay. It also tends to gel glazes so they need excessive water. Use boron frits instead.
It is possible to create glaze slurries that gel and flow extremely well, dry hard and do not crack by using the right kaolin (i.e. EPK) or ball clay (i.e. Old Hickory #5, No. 5 Glaze) in adequate amounts. It is very important to realize that many ball clays and kaolins to not produce glazes of good slurry properties, a simple substitution can make a remarkable difference. It may not seem that glaze chemistry is related to this subject of getting the right type and right amount of clay in a recipe. But it very much is. Why? Because the ability to juggle a recipe to source Al2O3 from a clay or a feldspar/frit, as needed, gives you the ability to control the amount of clay in the recipe. Chemistry also gives you the ability to switch between different types of clay (that have different oxide makeups).
Is the glaze's dry-bond with the ware surface inadequate?
The mechanism of the bond between dry glaze and body is simply one of physical contact, the roughness of the ware surface copmbined with the ability of the liquid glaze to flow into all the tiny surface pores and irregularities and the degree to which it is able to dry hard without shrinking too much, these determine its ability to 'hang on'.
- Some surfaces can seem very smooth (e.g. slip cast surfaces), but microscopically they are not. Still, the glaze needs enough fluidity to flow onto and wet the surface well.
- Be flexible, tune the raw clay content. You need enough clay in the glaze mix to both suspend the slurry and toughen the dried layer, more than that and you risk excessive shrinkage and compromise of the bond with the surface. Less and the glaze does not harden and forms a powdery surface. A fool-proof way to reduce shrinkage is to calcine (see the link below) part of the clay. If there is 35% kaolin in the mix, then try using 15% calcined kaolin and 20% raw kaolin. If there is 70% Alberta Slip, try using 35% raw and 35% calcined. Adjust the proportion as you get experience in working with the glaze. One detail: If there is significant clay content, you should adjust for the LOI (weight lost during firing). Kaolin, for example, loses 12% weight on firing, so use 12% less calcined). Alberta Slip and Ravenscrag Slip have 9% LOI.
- If the dried glaze surface is excessively powdery incorporate more plastic clay (chemistry will be needed to juggle the recipe). Or add a little bentonite. If there is 10% kaolin, for example, consider changing that to 7% kaolin and 3% bentonite (there is a chemistry impact here, but not significant).
- Adding gum to a glaze will harden it and bond it better to bisque, but there is a significant cost: slower drying, dripping. It is best to avoid it if you can, but if you must, heating the ware before glazing can really improve drying.
- If a glaze is flocculated it may lack the necessary fluidity to run into tiny surface irregularities in the bisque and establish a firm foothold. However, some degree of flocculation is valuable, it enables the glaze to set and gel quickly after dipping, this can really accelerate production.
- Wetting agents are available and can be added to the slurry to improve bond. But again, do not substitute these for the basics, the right amount of clay and degree of fluidity.
Does application technique or handling compromise the fragile glaze-body bond?
- Make sure ware is clean and dust free, even oil from ones skin can affect glaze bond.
- If glaze is applied too thickly the forces imposed by its shrinkage will overcome its ability to maintain a bond with the ware surface (especially inside corners or at sudden discontinuities). If a glaze can be applied more thinly, you
should do so.
- Use a fountain glazing machine to do the insides of bowls and containers to achieve a thinner layer.
- If glaze needs to be applied in a thick layer, you can achieve a lower water content by deflocculating the glaze (i.e. with some sodium silicate or Darvan). Use caution with this, it may then tend to dry very slowly or form drips that crack and peel and instigate crawling. It is better to just have the right clay content.
- When applying the glaze in the normal layer thickness be careful to prevent drips that form thicker sections that can crack away during drying. It is practical to 'gel' the glaze slightly (i.e. with vinegar, Epsom salts) so that it 'stays put' after dipping or pouring.
- If a double-layer of glaze needs to be applied be careful that the second does not shrink excessively and pull at the first, compromising its bond with the body. If possible, the upper layer should have less clay, lower shrinkage, should be applied thinner and dry quickly. It may be necessary to bisque each layer on before applying the next. Double-layering typical raw art and pottery glazes is difficult, special consideration must be given. If you have successfully done it in the past without any special attention then you may have simply been very lucky.
- When doing double-layer glazing be careful that the second layer is not flocculated (with an associated high water content). This will rewet the first layer and loosen it from the body. Adding iron oxide, for example, to a glaze will often flocculate it and require the addition of much more water to restore the same fluidity.
- Spraying glaze on in such a way that the glaze-body bond is repeatedly dried and rewetted could a produce shrinkage-expansion cycle that compromises a glaze-bisque bond that could otherwise withstand one drying-shrink cycle.
- Force-drying of the ware can make the glaze visibly crack when it otherwise would not (slower shrinkage associated with slower drying gives it the glaze time to ease body interface tension by micro cracking). Preheating the bisque too much may cause escaping steam to rupture the bond with the ware.
- Rough handling of ware can compromise sections of the glaze body bond.
- For the inside of slip cast ware, consider pouring a thin glaze slurry into the mold of a just-drained piece (perhaps a minute or two after the mold has been drained) and immediately pouring it out again. This base layer can be fired on in the bisque.
Is the glaze drying too slow?
- This often occurs where ware is very thin (e.g. slipcasting or fine porcelain), the bisque is fired to higher density, glaze has a high water content or ware is already wet from a previous glazing (or a combination of these factors). If the glaze dries too slowly the most fragile stages of the adhesion mechanism are extended and cracks or bubbles develop. These low-bond areas instigate crawling during melting. To fix this problem you need to speed up drying. You can do this by preheating the bisque (in a kiln to 150C or more if necessary) before dipping, doing separate interior and exterior glazing (with a drying period in between), applying glaze in a thinner layer, reducing glaze water content, bisquing lower to increase porosity or increasing wall thickness in the ware.
Is the ware once-fire?
- Once-fired ware is prone to crawling because the mechanical glaze-body bond is more difficult to achieve and maintain. If glaze is applied to leather hard ware it must shrink with the body. During the early stages of firing the ware also goes through volume changes and chemical changes that generate gases, these affect the ability of the glaze to hang on.
- When glaze is applied to leather hard ware you must be able to tune its shrinkage by adjusting the amounts and nature of the clays in the recipe while maintaining the overall chemistry (calculations may be needed).
- Once-fire ware must not be fired too quickly, especially through the water-smoking period. Make sure ware is absolutely dry before firing.
- In damp conditions the powdery layer may reabsorb water from the air causing slight expansion of the glaze layer, thereby affecting the adhesion.
Is the problem happening during firing?
- If glaze is applied over stains or oxides that lack flux (e.g. chrome pinks, manganese types, greens, cobalt aluminate) it can be prevented from bonding well with the underlying body. Mix under-glaze stains with a flux medium so that over lying glazes can 'wet' them and form a glassy bond.
- If the glazed ware is put into the kiln wet and therefore dried quickly during the early stages of firing, the glaze layer will tend to crack and curl and crawling can occur.
- If glazed ware is put into a kiln containing heavy damp ware such that early stages of firing occur in very high humidity conditions the glaze could be rewetted and forced through an expansion-shrinkage cycle (that could affect its bond with the body).
- If a glaze contains significant organic materials (i.e. gums, binders) that gas off excessively during firing the bond may be affected. Decomposition of materials like whiting can also generate significant amounts of gas within the glaze layer (try switching to wollastonite, it has not LOI and supplies SiO2 and will allow you to reduce the silica content accordingly).
- Raw zinc oxide is very fine and tends to pull a glaze together during firing, use calcined zinc instead (most zincs sold to potters are calcined).
- If the glaze contains significant zircon opacifier, alumina, some stains, magnesium carbonate, the melt may be much 'stiffer' and flow less. This can affect its ability to resist crawling.
- Watch out for glazes with slightly soluble materials like Gerstley Borate or wood ash. With the former the soluble portion tends to be the borate, which will be absorbed into the bisque during application. Then, during firing, it creates a highly fluid layer between the body and the less developed over glaze, it thereby prevents adhesion of the glaze to the body. Use frit to source boron instead. In addition soluble materials tend to flocculate (thicken) the slurry and attempts to thin them result in higher water content and therefore increased shrinkage.
- If the bisque firing is reduced or not adequately oxidized and excessive gases are generated during certain stages of the glaze firing, these can affect the glaze-body bond.
- The chemistry of glaze may be such that the surface tension of the melt encourages crawling (e.g. high alumina, high tin, significant chrome/manganese colorants, lack of fluxes of low surface tension).
Is there a problem with the body?
- If the clay body contains soluble salts that come to the surface during drying, these can affect the fired melt's ability to form a glassy bond with the body. Precipitate these salts with a small body addition of barium carbonate (for information on how this works search for Barium Carbonate in the materials section).
- As noted above, if the body surface is too smooth, the glaze may not be able to adhere properly.
Is this problem inherent in the type of glaze being used?
Matte glazes are prone to crawling. Why? Because they usually have high Al2O3. The major contributor of that oxide is clay, especially kaolin. Matte glazes commonly have 35% kaolin in the recipe. Use partly calcined material to deal with this problem.
Many pottery glazes have high feldspar and low clay contents, simply because they were improperly formulated. Using chemistry, you can shift the recipe to supply part of the Al2O3 from kaolin instead of the feldspar, reducing the feldspar percentage (this involves corrections in the amount of silica and other materials also).
Slip glazes can have 70, 80 or even 90% of a slip clay in them. Alberta Slip and Ravenscrag slip are examples. These materials melt by themselves to make glazes. But they are clays, they shrink. Follow the instructions from the manufacturer on how to use them properly.
Crawling glaze on slip cast ware is common
This cone 6 white glaze is crawling on the inside and outside of a thin-walled cast piece. This happened because the thick glaze application took a long time to dry, this extended period, coupled with the ability of the thicker glaze layer to assert its shrinkage, compromised the fragile bond between dried glaze and fairly smooth body. To solve this problem the ware could be heated before glazing, the glaze applied thinner, or glazing the inside and outside could be done as separate operations with a drying period between.
Why does the glaze on the right crawl?
This is G2415J Alberta Slip glaze on porcelain at cone 6. Why did the one on the right crawl? Left: thinnest application. Middle: thicker. Right thicker yet and crawling. All of these use a 50:50 calcine:raw mix of Alberta Slip in the recipe. While that appears fine for the two on the left, more calcine is needed to reduce shrinkage for the glaze on the right (perhaps 60:40 calcine:raw). This is a good demonstration of the need to adjust raw clay content for any glaze that tends to crack on drying. Albertaslip.com and Ravenscrag.com both have pages about how to calcine and calculate how much to use to tune the recipe to be perfect.
A good example of the superiority of a frit
Both of these glazes were made as 1000 gram batches and then mixed with the necessary amount of water to produce a slurry of the correct consistency. The one on the left is a fritted glaze with 20% kaolin, the one on the right is a Gerstley Borate based raw glaze (30% GB + feldspar, silica, ball clay). The GB glaze required much more water and gelled shortly after (it also tends to dry slowly and crack during drying on the ware). The fritted glaze has very good slurry and application properties.
Can you actually throw a Gerstley Borate glaze? Yes!
Worthington Clear is a popular low fire transparent glaze recipe. It has 55% Gerstley Borate plus 30% kaolin (Gerstley Borate melts at a very low temperature because it sources lots of boron). GB is also very plastic, like a clay. I have thrown a pot from this recipe! This explains why high Gerstley Borate glazes often dry so slowly and shrink and crack during drying. When recipes also contain a plastic clay the shirinkage is even worse. GB is also slightly soluble, over time it gels glaze slurries. Countless potters struggle with Gerstley Borate recipes. How could we fix this one? First, substitute all or part of the raw kaolin for calcined kaolin (using 10% less because it has zero LOI). Second: It is possible to calculate a recipe having the same chemistry but sourcing the magic melting oxide, boron, from a frit instead.
The same engobe. Same water content. What is the difference?
The engobe on the left, even though it has a fairly low water content, is running off the leather hard clay, dripping and drying slowly. The one on the right has been flocculated with epsom salts, giving it thixotropy (ability to gel when not in motion but flow when in motion). Now there are no drips, there are no thin or thick sections. It gels after a few seconds and can be uprighted and set on the shelf for drying.
Adding water actually made this white engobe run less? How?
The white slip (applied to a leather hard cup) on the left is dripping downward from the rim (even though it was held upside down for a couple of minutes!). Yet that slurry was viscous with a 1.48 specific gravity, on mixer-off the motion stopped immediately. Why? Because it was not thixotropic (it did not gel). The fix? I watered it down to 1.46 (making it very thin and runny) and did a cycle of adding a pinch of epsom salts (about 0.5 gm) and mixing vigorously watching for it to thicken enough to stop motion in about 1 second on mixer shut-off (bounce backward!). It is extremely difficult not to overdo the epsom salts (gelling it too much) so I keep ungelled slurry aside and pour some back in to dilute to overgelled batch. That works perfect to fine-tune the degree of thixotropy so it gels after about 10-15 seconds of sitting. So to apply it I stir it, wait a couple of seconds and dip the mug. By the time I pull it out it is ready to gel and hold in place.
Do not glaze bisque ware when it is too wet
These mugs are quite thin walled. A glaze has just been applied to the inside. Notice how it has water logged the bisque (you can see the contrast at the base, where the clay is a little thicker and has not changed color yet). Although there may be enough absorbency that a glaze could be applied now, it would still not be a good idea because it would completely waterlog the piece and result in a very long drying time. This is bad, not only because of process logistics, but also because slow drying glazes almost always crack and lift from the bisque (causing crawling).
Crawling of the glaze on a typical sanitary ware porcelain item
The original recipe had a very low clay content, sourcing almost all of its Al2O3 from feldspar instead. Although the glaze slurry was maintained at 1.78 specific gravity (an incredibly high value) and thus would have had very low shrinkage, it did not stick and harden well enough to the ware. The suggested change sources much more of the Al2O3 from kaolin and substitutes other fluxes for part of the lost K2O (since the glaze also had a high thermal expansion).
Glaze cracking during drying? Wash it off and change the process or glaze.
If your drying glaze is doing what you see on the left, do not smooth it with your finger and hope for the best. It is going to crawl during firing. Wash it off, dry the ware and change your glaze or process. This is Ravenscrag Slip being used pure as a glaze, it is shrinking too much so I simply add some calcined material to the bucket. That reduces the shrinkage and therefore the cracking (trade some of the kaolin in your glaze for calcined kaolin to do the same thing). Glazes need clay to suspend and harden them, but if your glaze has 20%+ kaolin and also bentonite, drop the bentonite (not needed). Other causes: Double-layering. Putting it on too thick. May be flocculating (high water content). Slow drying (try bisquing lower, heating before dipping; or glaze inside, dry it, then glaze outside).
Out Bound Links
In Bound Links
Glaze Pinholing, Pitting
Analyze the causes of ceramic glaze pinholing and ...
A condition where glaze separates into clumps or i...
In ceramics, a suspension is a mix of insoluble mi...
By Tony Hansen