Modification Date: 2018-01-11 08:36:24
A base MgO matte glaze recipe fires to a hard utilitarian surface and has very good working properties. Blend in the glossy if it is too matte.
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This glaze is a cone 6 dolomite matte. It is the product of a series of tests to determine the best levels of SiO2 and Al2O3 in a boron fluxed (but not boron saturated) clear using a high level of MgO to create the matte. In its current state it does not cutlery mark and has good (but not too much melt flow) and thus creates a good glass (in our circumstances). The development process for this glaze showcases the value of looking at glazes as formulas of oxides rather than recipes of materials.
This is a dolomite matte for cone 6. The calcined kaolin is needed to supply the Al2O3 but not increase the drying shrinkage. Notice also, that although a matte, this recipe has a high silica content. However, the matteness mechanism is somewhat fragile (it will be more matte for some people, more glossy for others; due to material (especially with local dolomites), process and firing differences). In addition, certain colors will matte it more and others will gloss it more. For most people a simple addition of G2926B (M370 transparent ultra clear base recipe) will increase the gloss. Start by adding 10% and testing (since this and the gloss mix to about the same specific gravity, just measuring by volume of slurry is a fairly accurate way to judge the percent addition). Be prepared to adjust each color variation to fine tune its degree of gloss.
In our circumstances, this recipe has very good suspension and application properties. It dries hard, does not crack during drying, does not settle hard in the bucket and applies evenly and dries quickly. If you do not have EP Kaolin, just substitute. That may require adjusting the raw:calcine proportions. If it settles convert some of the calcined kaolin to raw. If it does not dry hard enough or does not suspend well, use more raw kaolin and less calcined. However because the raw kaolin has 12% weight loss on firing, more is needed to supply the same amount of SiO2 and Al2O3 to the fired glaze. For example, if you drop the calcined kaolin by 5 you need to increase the raw kaolin by 5.6 to maintain the same overall chemistry (5 + (5 x 12% / 100 = 5.6). If your kaolin is not too plastic you might be able to use all raw kaolin (18.3 + 13.9 + (13.9 x 12% / 100) = 34. But beware, the glaze could crack on drying (and thus crawl on firing).
To prepare it for use, add the powder to water and mix until it flows well. Screen through 80 mesh (there are tiny agglomerates that will not break down without screening). Adjust the amount of water to get a consistency such that on extraction from a 1-2 second dip the glaze hangs on in an even layer without dripping and dries in less than 10 seconds. We have found that a 1.4 specific gravity is about right (gives a 13 second Ford Cup viscosity). The slurry needs to be slightly gelled to achieve this, so don't use too much water. Adjust your bisque temperature to get more porosity (if the glaze dries to slow) or less (if it dries too fast).
Although this is a matte glaze it flows well (it is well melted). If it pinholes for you the solution lies elsewhere. Bisque ware as high as possible. If you gel the slurry a little, or preheat the ware, you can bisque even higher. Try applying a thinner glaze layer and use whatever technique necessary to get an even and quality laydown. If still needed, consider using the double-soak firing schedule.
Plainsmanclays.com makes this recipe as a premixed powder.
This glaze is firing to a surface that some people are claiming is too dry. We have created an equivalent recipe that sources the MgO from a frit and talc, G2934Y (see link below). It has a better melt fluidity (and thus is less opaque), a much lower LOI and the surface is just slightly more silky. Both react to stains in the same way.
G2934 is a popular matte for cone 6 (far left). It is not matte because it is not melting enough or is covered with micro-crystals, it is an MgO matte (a mechanism produces a more pleasant surface that cutlery marks and stains less). But what if it is too matte for you? This recipe requires accurate firings, did your kiln really go to cone 6? Proven by a firing cone? If it did, then we need plan B: Add some glossy to shine it up a bit. I fired these ten-gram balls of glaze to cone 6 on porcelain tiles, they melted down into nice buttons that display the surface well. Top row proceeding right: 10%, 20%, 30%, 40% G2926B added (100% far right). Bottom: G2916F in the same proportions. The effects are similar but the top one produces a more pebbly surface.
These are Mason stains added to the cone 6 G2934 silky MgO matte liner base glaze (with tin, zircopax and various stains added). The brightest colors (6600, 6350, 6300, 6021, 6404) were tested overnight in lemon juice without visible changes. It is known that MgO mattes are less prone to acid attack that CaO mattes. Caution is required with inclusion stains (like #6021), if they are rated to cone 8 they may already begin bubbling at cone 6 is some host glazes.
Matte glazes have a fragile mechanism. That means the same recipe will be more matte for some people, more glossy for others (due to material, process and firing differences). In addition, certain colors will matte the base more and others will gloss it more. It is therefore critical for matte glaze recipes to have adjustability (a way to change the degree of gloss), both for circumstances and colors. This recipe is Plainsman G2934 base matte with 6% Mason 6600 black stain added. It has been formulated to be on the more matte side of the scale so that for most people a simple addition of G2926B (M370 transparent ultra clear base recipe) will increase the gloss. That means users need to be prepared to adjust each color of the matte to fine-tune its degree of gloss. Here you can see 5:95, 10:90, 15:85 and 20:80 blends of the matte:gloss recipe bases.
A melt fluidity comparison between two cone 6 matte glazes. G2934 is an MgO saturated boron fluxed glaze that melts to the right degree, forms a good glass, has a low thermal expansion, resists leaching and does not cutlery mark. G2000 is a much-trafficked cone 6 recipe, it is fluxed by zinc to produce a surface mesh of micro-crystals that not only mattes but also opacifies the glaze. But it forms a poor glass, runs too much, cutlery marks badly, stains easily, crazes and is likely not food safe! The G2934 recipe is google-searchable and a good demonstration of how the high-MgO matte mechanism (from talc) creates a silky surface at cone 6 oxidation the same as it does at cone 10 reduction (from dolomite). However it does need a tin or zircon addition to be white.
Left: a cone 6 matte glaze (G2934 with no colorant). Middle: 5% Mason 6006 chrome-tin red stain added. Right: 5% Mason 6021 encapsulated red stain added. Why is there absolutely no color in the center glaze? This host recipe does not have the needed chemistry to develop the #6006 chrome-tin color (it lacks sufficient CaO and has alot of MgO). Yet this same matte glaze intensifies the #6021 encapsulated stain at only 5% (using 20% or more encapsulated stain is to develop the color is not unusual).
G2934 cone 6 matte (left) with 10% zircopax (center), 4% tin oxide (right). Although the cutlery marks clean off all of them, clearly the zircopax version has the worst problem and is the most difficult to clean. To make the best possible quality white it is wise to line blend in a glossy glaze to create a compromise between the most matteness possible yet a surface that does not mark or stain.
Left: G2934 cone 6 matte glaze with 3% Mason 6300 blue stain. Right: An additional 4% tin added. Notice how an opacified color does not have depth and therefore is lighter in color. Also it does not break to different shades at the edges of contours the way the transparent color does.
These mugs have just finished immersion into ice water from 300F. Twice. The LA Matt is crazing but the G2924 is still good. And its surface is more silky and more pleasant to the touch. It is whiter because of a 4% tin oxide addition. This is a glaze surface that would be excellent on most cone 6 porcelains. Remember, if you need to adjust the matteness, just add a little glossy to the batch.
These 10 gram balls were fired and melted down onto a tile. The one the left is the original G2934 Plainsman Cone 6 MgO matte with 6% stain. On the right the adjustment has a 20% glossy glaze addition to make it a little less matte. Notice the increased flow (the ball has flattened more) with the addition of the glossy. In addition, while the percentage of stain is actually less (on the right), the color appears darker! Tuning the degree of matteness when making color additions to a base is almost always necessary to achieve a glaze that does not cutlery mark.
An example of how a spoon can cutlery mark a glaze. This is a popular middle temperature recipe used by potters. The mechanism of its matteness is a high percentage of zinc oxide that creates a well-melted glaze that fosters the growth of a mesh of surface micro-crystals. However these crystals create tiny angular protrusions that abrade metal, leaving a mark. Notice the other matte flow on the left (G2934), it not only has a better surface (more silky feel) but also melts much less (its mechanism is high MgO in a boron fluxed base). It is does not cutlery mark at all!
The top glaze is VC71, a popular matte cone 6 glaze used by potters. Bottom is G2934 matte, a public domain recipe produced by Plainsman Clays. The latter is a high-MgO matte, it melts well and does not cutlery mark or stain easily. As evidence that it is a true matte, notice that it is still matte when fired to cone 7 or 8. VC71, while having a similar pleasant silky matte surface at cone 6, converts to a glossy if fired higher. This suggests that the cone 6 matteness is due to incomplete melting. For the same reason, it is whiter in color (as soon as it begins to melt and have depth the color darkens).
These cone 6 porcelain mugs have glossy liner glazes and matte outers: VC71 (left) crazes, G2934 does not (it is highlighted using a felt marker and solvent). Crazing, while appropriate on non-functional ware, is unsanitary and severely weakens the ware (up to 300%). If your ware develops this your customers will bring it back for replacement. What will you do? The thermal expansion of VC71 is alot higher. It is a product of the chemistry (in this case, high sodium and low alumina). No change in firing will fix this, the body and glaze are not expansion compatible. Period. The fix: Change bodies and start all over. Use another glaze. Or, adjust this recipe to reduce its thermal expansion.
These are 10 gram balls of four different common cone 6 clear glazes fired to 1800F (bisque temperature). How dense are they? I measured the porosity (by weighing, soaking, weighing again): G2934 cone 6 matte - 21%. G2926B cone 6 glossy - 0%. G2916F cone 6 glossy - 8%. G1215U cone 6 low expansion glossy - 2%. The implications: G2926B is already sealing the surface at 1800F. If the gases of decomposing organics in the body have not been fully expelled, how are they going to get through it? Pressure will build and as soon as the glaze is fluid enough, they will enter it en masse. Or, they will concentrate at discontinuities and defects in the surface and create pinholes and blisters. Clearly, ware needs to be bisque fired higher than 1800F.
I am getting closer to reduction speckle in oxidation. I make my own speckle by mixing the body and a glossy glaze 50:50 and adding 10% black stain. Then I slurry it, dry it, fire it in a crucible I make from alumina, crush it by hand and screen it. I am using G2934 cone 6 magnesia matte as the glaze on this mug on the left. To it I added 0.5% minus 20 mesh speck. Right is a cone 10R dolomite matte mug. Next I am going to screen out the smallest specks, switch to a matte glaze when making the specks (they are too shiny here), switch to dark brown stain. Later we will see if the specks need to bleed a little more. I am now pretty well certain I am going to be able to duplicate very well the reduction look in my oxidation kiln. I will publish the exactly recipe and technique as soon as I have it.
Left: G2934 magnesia cone 6 matte (sold by Plainsman Clays). Right (G2934D): The same glaze, but with 0.4 molar of BaO (from Ferro Frit CC-257) substituted for the 0.4 MgO it had. The MgO is the mechanism of the matte effect. Barium also creates mattes, but only if the chemistry of the host glaze and the temperature are right. In addition, barium mattes are normally made using the raw carbonate form, not a frit. In fritted form, barium can be a powerful flux when well dissolved in the melt and boron is present. This glaze is actually remarkably transparent. However, if this was fired lower it could very well matte.
We are looking at two pairs of samples, they demonstrate why knowing about glaze chemistry can be so important. Both pairs are the same glazes: G2934 cone 6 matte and G2916F cone 6 glossy. The left pair has 5% maroon stain added, the right pair 5% purple stain. The red and purple develop correctly in the glossy but not the matte. Why? The Mason Colorworks reference guide has the same precaution for both stains: the host glaze must be zincless and have 6.7-8.4% CaO (this is a little unclear, it is actually expressing a minimum, the more the CaO the better). The left-most samples of each pair here have 11% CaO, the right-most have 9%. So there is enough CaO. The problem is MgO (it is the mechanism of the matteness in the left two), it impedes the development of both colors. When you talk to tech support at any stain company, as I did with Mason on this, they need to know the chemistry of your glaze to help, not the recipe.
This is G2934Y (a version of the G2934 cone 6 matte base recipe that supplies much of the MgO from a frit instead of dolomite). Like the original, it has a beautiful fine silky matte surface and feels like it would not cutlery mark. But, as you can see on the left, it does! The marks can be cleaned off easily. But still, this is not ideal. The degree of matteness that a glaze has is a product of its chemistry. But can we fix this without doing any chemistry? Yes. By blending this with G2926B clear glossy (90:10 proportions) the marks are gone and the surface is only slightly changed.
At the top is a melt-flow ball of a cone 6 satin matte glaze, G2934. Left bottom: 8% 6213 Mason Hemlock green stain added. The color is good but it is not melting as much and the surface is more matte. A solution is to adjust the base: employ a 90:10 or 80:20 matte:glossy blend to give it better fluidity. Right bottom: 8% 6385 Mason Pansy Purple stain added. The percentage of stain appears to be a little low and its surface is a little too matte. Again, blend a some glossy clear in the the matte base to shine it up a little.
This is the G2934Y matte base recipe with only 8% Cerdec Orange encapsulated stain. G2934Y employs a frit-source for the MgO (as opposed to G2934 which sources the MgO from dolomite). The orange color is brighter on the mug on the left because the porcelain is whiter, Plainsman Polar Ice (the other one is #6 Tile Kaolin based, P300). If this was a glossy glaze the required percentage of stain would be higher. Other colors, like yellow, are equally vibrant. But not all, testing is needed.
This is the G2934Y matte base with overglaze decoration fired at cone 6. Although this matte has a high melt fluidity, overglaze decoration can be successful as long as it is not applied too thick and not overfired. But in this case the glaze is thickly applied. Once the critical thickness boundary is passed, the glaze's ability to hold overglaze in place quick degrades. The G2934 recipe has less melt fluidity and fires to the same surface, it would would be a better choice as the base glaze in this case (and could be applied thicker). However this Y variation would be a good choice as the medium if you want to make your own overglaze brushable colors.
These are 10 gram balls that we melted on porcelain tiles at cone 4 (top two) and cone 6 (bottom two). They compare the melt fluidity of G2934 (left) and G2934Y (right). The Y version sources its MgO from frit and talc (rather than dolomite). It is a much more fluid melt because the frit is yielding the oxides more readily. But Y has a key benefit: It has a much lower LOI, producing fewer entrained air bubbles and therefore fewer surface defects. And, even though it runs much more, it has the same matte surface! As long as it is applied at normal thickness, the extra melt fluidity does not cause any running. And it has another benefit: Less cutlery marking issues. It is actually a very durable and practical food surface glaze, having a low thermal expansion that fits almost any body. Although these appear glossy here, on ware they have the identical pleasant silky matte surface.
Out Bound Links
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By Tony Hansen