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Ulexite

Sodium calcium borate

Formula: NaCaB5O9·8H2O
Alternate Names: Television Stone

OxideAnalysisFormula
CaO13.84%0.667
Na2O7.65%0.333
B2O342.95%1.667
LOI35.55
Oxide Weight174.12
Formula Weight270.16
If this formula is not unified correctly please contact us.

Ulexite is a natural source of boron, it is similar to colemanite mineral. These two minerals are the only practical sources of insoluble boron for glazes (other than frits). Ulexite one of the lowest melting non-lead ceramic minerals, it can form an ultra-gloss transparent glass at cone 06. Strangely this material does not appear to flux bodies nearly as well as one might expect.

Ulexite is a truly uncommon ceramic mineral in that it contains almost no alumina or silica, it is nothing but fluxing oxides. This mineral forms in unusual geologic circumstances and can be found in very few places in the world. The chemistry given here is theoretical, actual deposits will have lower boron content.

The popular mineral Gerstley Borate, used by potters for many decades is, is composed partly of ulexite. It was mined and stockpiled in the California desert many years ago. The last remaining stockpile is being ground, bagged and sold by Laguna Clay. Ulexite is available in small quantities for potters at Plainsman Clays.

While Ulexite melts well, it does have a very high LOI (that means that gases are generated during melting). For this reason it is not possible to produce ultra-clear glazes at low temperatures (as with frits). Notwithstanding this, by doing a double-soak firing it is possible to clear many more bubbles. Thinner glazes layer are also much more transparent.

Ulexite is available industrially from Turkey and Chile. It is used in the fiberglass industry as a melter but its potential has never been exploited to any extent in ceramic glazes.


What is the secret of the higher gloss glaze on the right? Yikes, it is lead!

What is the secret of the higher gloss glaze on the right? Yikes, it is lead!

These cone 04 glazes have the same recipe (a version of Worthington Clear sourcing B2O3 from Ulexite instead of Gerstley borate). While the one on the left is OK, the one on the right is great! Why? It has 10% added lead bisilicate frit. Of course, I would not recommend this, I am just demonstrating how well it melts. Still, we gasp at the thought of using lead while we thrive on unstable flux-deprived, glass-deprived and alumina-deprived base stoneware glazes with additions of toxic colorants like chrome and manganese!

Alberta slip and Ulexite at cone 6

Alberta slip and Ulexite at cone 6

90% Alberta Slip (which is a mix of half and half raw and calcine) and 10% Ulexite fired at cone 6. A dazzling fluid dark amber transparent. You could also do this using frit.

The perfect storm to create boron-blue clouding at low fire

The perfect storm to create boron-blue clouding at low fire

Two clear glazes fired in the same slow-cool kiln on the same body with the same thickness. Why is one suffering boron blue (1916Q) and the other is not? Chemistry and material sourcing. Boron blue crystals will grow when there is plenty of boron (and other power fluxes), alumina is low, adequate silica is available and cooling is slow enough to give them time to grow. In the glaze on the left B2O3 is higher, crystal-fighting Al2O3 and MgO levels are alot lower, KNaO fluxing is alot higher, it has more SiO2 and the cooling is slow. In addition, it is sourcing B2O3 from a frit making the boron even more available for crystal formation (the glaze on the right is G2931F, it sources its boron from Ulexite).

Glaze melt fluidity comparison between G2931F and fritted G2931K show the effect of LOI

Glaze melt fluidity comparison between G2931F and fritted G2931K show the effect of LOI

These two glazes have the same chemistry but different recipes. The F gets its boron from Ulexite, and Ulexite has a high LOI (it generates gases during firing, notice that these gases have affected the downward flow during melting). The frit-based version on the right flows cleanly and contains almost no bubbles. At high and medium temperatures potters seldom have bubble issues with glazes. This is not because they do not occur, it is because the appearance of typical glaze types are not affected by bubbles (and infact are often enhanced by them). But at low temperatures potters usually want to achieve good clarity in transparents and brilliance in a colors, so they find themselves in the same territory as the ceramic industry. An important way to do this is by using more frits (and the right firing schedules).

The difference between these low fire transparents: Gerstley Borate vs. Ulexite

The difference between these low fire transparents: Gerstley Borate vs. Ulexite

Left: Worthington Clear cone 04 glaze (A) uses Gerstley Borate to supply the B2O3 and CaO. Right: A substitute using Ulexite and 12% calcium carbonate (B). The degree of melting is the same but the gassing of the calcium carbonate has disrupted the flow of B. Gerstley Borate gasses also, but does so at a stage in the firing that does not disrupt this recipe. However, as a glaze, B does not gel and produces a clearer glass. A further adjustment to source CaO from non-gassing wollastonite would likely improve it.

Why does Gerstley Borate melt in two stages? Because it is two minerals.

Why does Gerstley Borate melt in two stages? Because it is two minerals.

The ulexite in Gerstley Borate melts first, producing an opaque fired glass having the unmelted (and still gassing) particles of colemanite suspended in it. By 1750F the colemanite is almost melted also. Boron-containing frits, by contrast, begin softening at a much lower temperature and gradually spread and melt gradually. Not surprisingly they produce a more stable glaze (albeit often less interesting visually).

Surface tension is a big deal in transparent glazes at cone 04

Surface tension is a big deal in transparent glazes at cone 04

Low fire glazes must be able to pass the bubbles their bodies generate (or clouds of micro-bubbles will turn them white). This cone 04 flow tester makes it clear that although 3825B has a higher melt fluidity (it has flowed off onto the tile, A has not). And it has a much higher surface tension. How do I know that? The flow meets the runway at a perpendicular angle (even less), it is long and narrow and it is white (full of entrained micro-bubbles). Notice that A meanders down the runway, a broad, flat and relatively clear river. Low fire glazes must pass many more bubbles than their high temperature counterparts, the low surface tension of A aids that. A is Amaco LG-10. B is Crysanthos SG213 (Spectrum 700 behaves similar to SG13, although flowing less). However they all dry very slowly. Watch for a post on G2931J, a Ulexite/Frit-based recipe that works like A but dries on dipped ware in seconds (rather than minutes).

A cure for long-time low and medium fire Gerstley Borate sufferers: Ulexite!

A cure for long-time low and medium fire Gerstley Borate sufferers: Ulexite!

These are various different terra cotta clays fired to cone 04 (also a low fire white-buff fritted stoneware) with a recipe I formulated to source the same chemistry as the popular Worthington clear, but sourcing the B2O3 from Ulexite and a frit instead of Gerstley Borate (G2931B). All pieces are fired with a soak-soak-slow cool firing. Fit is good on all except a fritted terra cotta stoneware where it is shivering slightly (all were boil:ice tested). This outlines work I am doing to create an alternative recipe for the popular 50:30:20 GB:EPK:Silica recipe (Worthington clear) that uses Ulexite instead of Gerstley Borate (the later is notorious for turning glaze slurries into jelly!).

Out Bound Links

In Bound Links


By Tony Hansen

XML for Import into INSIGHT

<?xml version="1.0" encoding="UTF-8"?> <material name="Ulexite" descrip="Sodium calcium borate" searchkey="Television Stone" loi="0.00" casnumber="167077-83-0"> <oxides> <oxide symbol="CaO" name="Calcium Oxide, Calcia" status="" percent="13.840" tolerance=""/> <oxide symbol="Na2O" name="Sodium Oxide, Soda" status="" percent="7.650" tolerance=""/> <oxide symbol="B2O3" name="Boric Oxide" status="" percent="42.950" tolerance=""/> </oxides> <volatiles> <volatile symbol="LOI" name="Loss on Ignition" percent="35.550" tolerance=""/> </volatiles> </material>


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