Alternate Names: Calcium Phosphate
|If this formula is not unified correctly please contact us.|
|DENS - Density (Specific Gravity)||3.10|
|GSPT - Frit Softening Point||1670C|
Bone ash is TriCalcium Phosphate in the form of Hydroxyapatite Ca5(OH)(PO4)3. This reacts when making bone china to give Anorthite (CaAl2Si2O8) and Ca3(PO4)2.
2*Ca5(OH)(PO4)3 --> 3*Ca3(PO4)2 + Ca(OH)2
Real bone ash is obtained by calcining bone up to approximately 1100°C and then cooling and milling. This material is still manufactured today since some of its important properties are due to the unique cellular structure of bones that is preserved through calcination. Real bone ash has excellent non-wetting properties, it is chemically inert and free of organic matters and has very high heat transfer resistance.
Bone ash has traditionally been added to porcelain to achieve a high degree of translucency (thus the name 'bone china'). The manufacture of bone china is difficult to master because the clays are non-plastic, ware is unstable in the kiln, and it is difficult to burn consistently to the body's narrow firing range. Today the availability of super-white kaolins, low iron feldspars and processed bentonites, smectites and hectorites makes it possible for almost anyone to make very white, translucent and strong porcelains even at cone 6.
Bone ash is not common in glazes. When employed it can cause the slurry to flocculate and thicken (and produce a very thick layer on the ware surface which cracks during drying). People often react to this by adding more water, producing a glaze that shrinks even more on drying and eventually thickens again. A better way is to add a little deflocculant to the glaze slurry (like Darvan).
Up to 1-2% bone ash can be used in enamels for opacification (more will usually cause pinholes). In glazes, as with enamels, too much or too high a temperature will cause blistering. In this use the phosphorus' influence toward a stiff melt generally checks the fluxing action of the calcia.
Bone ash or calcium phosphate are used to opacify opal glass (1-3%) because the P2O5 content forms colorless compounds with iron impurities.
Glaze Opacifier - White
Low temperature glazes sometimes employ bone ash for opacity because of the milky quality it produces. It can also be used to assist tin oxide where a less shiny surface can be tolerated.
Glaze Surface Texture - Texture
Bone ash encourages strong glaze textures; however, too much can produce crazing or blistering.
The whitest test bar here is a New-Zealand-kaolin-based cone 6 porcelain (employs VeeGum for plasticity). Immediately to the left of it are three North American-koalin-based bodies using standard bentonites. The bar to is right in a Grolleg based body that uses a standard bentonite rather than a white burning one. All are plastic.
These are two cone 6 transparent glazed porcelain mugs with a light bulb inside. On the left is the porcelainous Plainsman M370 (Laguna B-Mix 6 would have similar opacity). Right is a zero-porosity New Zealand kaolin based porcelain called Polar Ice (from Plainsmanclays.com also)! The secret to making a plastic porcelain this white and translucent is not just the NZ kaolin, but the use of a very expensive plasticizer, VeeGum T, to enable maximizing the feldspar to get the fired maturity.
Out Bound Links
Tri-Calcium Phos, Tribasic Calcium Phosphate, Synthetic Bone Ash, Calcium Orthophosphate
True bone china is a special type of translucent porcelain. Instead of feldspar, bone ash is used as the flux. The process requires more careful attention than normal porcelain. The vitrification range is narrow, kilns need to be fired carefully. Ware often warps so badly that it must be fired witho...
In Bound Links
The calcining process is used to remove some or all unwanted volatiles from a material (e.g. H2O, CO2, SO2) and/or to convert a material into a more stable, durable or harder state. Varying temperatures are employed to calcine various materials, depending on the decomposition temperature of the vol...