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FlocculationThe opposite of deflocculation. Flocculation in a slurry can be a desired or undesired property. The same engobe. Same water content. What is the difference?
The engobe on the left, even though it has a fairly low water content, is running off the leather hard clay, dripping and drying slowly. The one on the right has been flocculated with epsom salts (powdered), giving it thixotropy (ability to gel when not in motion but flow when in motion). Now there are no drips, there are no thin or thick sections. It gels after a few seconds and can be uprighted and set on the shelf for drying. Should you throw out the brown water on top of settled glazes?
This is water from the top of a glaze that had been sitting for more than a year. Clearly, the solute contains iron. It is being dissolved out of one or more of the white powders in the glaze recipe (often frits). The iron, at least, is a contaminant. This should be thrown out and replaced with clean water. Why? We do not want anything dissolved in glaze slurries. It either migrates into the body with the water it absorbs during glazing or it migrates to the surface as the water evaporates. Both are bad. How much dissolved material would be lost? It would be measured in tenths or hundreds of a gram. Hypothetically then, if a bucket contains 1000 grams of the material, one ten-thousandth of it would be lost! Which clay contains more soluble salts?
Example of sedimentation test to compare soluble salts water extracts from suspended clay. This simple test also reveals ultimate particle size distribution differences in clays that a sieve analysis cannot do. Would it be possible to glaze a stainless steel spoon?
This is a stainless steel spoon that has been dipped into a ceramic engobe that has been flocculated using powdered epsom salts. Without the salts the slip completely runs off leaving only a film. But with the right amount it stays on the spoon in an even layer (as a gel), then hardens as it dewaters (left) and finally dries completely (right) with no cracks! It fired to cone 03 with no cracks. If this were fired high enough it would transform to a glaze. But it would craze. Special low expansion frits are available to make enamels for metals. How to stop an slip from running
The flocculated slip (left) hangs on, stays even and does not run. The normal slip (right) is thin and running on verticals and thinning at the rim. When to use vinegar and when to use epsom salts to flocculate a slurry
Slurries with more clay (like engobes, slips) generally respond better to epsom salts. However the extra clay also makes them more likely to go moldy, so you may need to add a few drops of Dettol to kill the bacteria (if they are stored for any length of time). Vinegar works better for glaze surries, but only if they have sufficient specific gravity. Many people like to make an epsom salts solution and add that, but if you have a good mixer you may find it more intuitive to add the crystals (which you should crush to a powder) and wait 30 seconds for the viscosity to respond. Fundamentals of Fluid Mechanics - book
Many aspects of ceramic production relate to the control of fluids (mostly suspensions). This is also true of material production. If you want to solve problems and optimize your process this is invaluable knowledge. This book is available at amazon.com. In Bound Links
By Tony Hansen |
