A white or colored slip applied to clay as a coating. The term "slip" is often used interchangeably with this, but we think of slip more as a decorative material/process. The tile industry uses the largest volumes of engobe by far, these are employed as opaque barriers between less-than-white bodies and their glazes. Engobes are so valuable to the tile industry because they enable the use of locally available (and therefore much less expensive) red and brown burning bodies (the white engobe provides a surface on which glazes can have the same brilliant colors as on porcelain). The use of these locals clays has another key advantage: red burning bodies vitrify at much lower temperatures, resulting in energy savings. There is another area of cost saving: glazes need less zircon opacifier (one of the most expensive raw materials used in ceramics). However, there is a downside: This process rewets ware so it can add a day to your drying procedure. However the benefits can also accelerate others parts of the process.
The covering power of an engobe is amazing. If they are not over-fluxed.
This cone 6 mug is made from a black clay (containing 10% burnt umber). The engobe on the inside is covered by a clear glaze. The color is the same as if the engobe were on a white or buff firing stoneware. Engobes get their covering power from the fact that they do not melt. If you see an engobe with lots of frit it will likely melt too much, be suspicious.
Stage 1 of engobing a cone 6 red stoneware mug
On the right is what it will look like when fired with a clear glaze on the inside and amber-clear on the outside. On the left it has dried and is ready for a little fix-up before bisque firing.
Too much frit in an engobe and it will lose opacity and whiteness
The white slip on the left is an adjustment to the popular Fish Sauce slip (L3685A: 8% Frit 3110 replaces 8% Pyrax to make it harder and fire-bond to the body better). The one on the right (L3685C with 15% frit) is becoming translucent, obviously it will have a higher firing shrinkage than the body (a common cause of shivering at lips and contour changes). The slip is basically a very plastic white body. Since these are not nearly as vitreous as red ones at low fire they need help to mature and a frit is the natural answer. With the right amount the fired shrinkage of body and slip can be matched and the slip will be opaque. This underscores the need to tune the maturity of an engobe to the body and temperature. Although zircon could be added to the one on the right to opacify and whiten it, that would not fix the mismatch in fired shrinkage between it and the body.
A small laboratory variable speed propeller mixer
If you are at all serious about testing glazes and clay bodies, you need one of these. There are other methods, but nothing else comes close to this. These are expensive new, this one was more than $1000. But you can get them used on ebay.com. I adapted a mount (to give it vertical adjustment) from a hardware store. Propellers are also expensive, but you can design and 3D print them yourself or have them printed at a place like shapeways.com.
The same engobe. Same water content. What is the difference?
The engobe on the left, even though it has a fairly low water content, is running off the leather hard clay, dripping and drying slowly. The one on the right has been flocculated with epsom salts (powdered), giving it thixotropy (ability to gel when not in motion but flow when in motion). Now there are no drips, there are no thin or thick sections. It gels after a few seconds and can be uprighted and set on the shelf for drying.
Shivering on a transparent over an engobe
Example of a glaze (G1916J) shivering on the rim of a mug. But the situation is not as it might appear. This is a low quartz cone 03 vitreous red body having a lower-than-typical thermal expansion. The white slip (or engobe) has a moderate amount of quartz and is thus put under some compression by the body. But the compression is not enough to shiver off (e.g. at the rim) when by itself. However the covering glaze has an even lower expansion exerting added compression on the slip. This causes a failure at the slip-body interface.
Adding water actually made this white engobe run less? How?
The white slip (applied to a leather hard cup) on the left is dripping downward from the rim (even though it was held upside down for a couple of minutes!). Yet that slurry was very viscous with a 1.48 specific gravity. Why? Because it was not thixotropic. The fix? I watered it down to 1.46 (making it runny) and added pinches of powdered epsom salts (while mixing vigorously) until it thickened enough to stop motion in about 1-2 seconds on mixer shut-off. But that stop-motion is followed by a bounce-back. That is the thixotropy. It is easy overdo the epsom salts (gelling it too much), I add a drop or two of Darvan to rethin it if needed. When the engobe is right it gels after about 10 seconds of sitting, so I can stir it, dip and extract the mug, shake to drain it and then it gels and holds in place. Keep in mind, this is a pottery project. In industry they deflocculate engobes to reduce water content. But a deflocculated slurry can still be gelled (if it is runny).
One small pinhole in a terra cotta mug and we have a problem
This is L3724E terra cotta stoneware. The inside slip is L3685S, a frit-fluxed engobe that is hard like the body and attaches well to it (engobes are often insufficiently fluxed). The glaze (G1916Q) is Frit 3195, Frit 3110 and 15% ball clay. The body has about 3% porosity, enough to make very strong pots. However that porosity is still enough to absorb water (and coffee). Although not too visible here, the pinhole in the inner surface has enabled absorption and there is a quarter-sized area of discoloration below the glaze. The piece could possibly be fired a cone higher, but testing would be required to see if the slip is still firing-shrinkage and thermal-expansion compatible with the body and that the body would not be over-fired. A better solution is adjust the firing curve to heal the glaze better. High temperature stoneware can easily have a 3% porosity also, so this is not just a low fire issue.
Double-slip layer incised decoration: A challenge in slip-body fitting
An example of a white engobe (L3685T) applied over a red clay body (L3724F), then a red engobe (also L3724F) applied over the white. The incised design reveals the white inter-layer. This is a tricky procedure, you have to make sure the two slips are well fitted to the body (and each other), having a compatible drying shrinkage, firing shrinkage, thermal expansion and quartz inversion behavior. This is much more complex that for glazes, they have no firing shrinkage and drying shrinkage only needs to be low enough for bisque application. Glazes also do not have quartz inversion issues.
Bleeding underglaze. Why?
This cobalt underglaze is bleeding into the transparent glaze that covers it. This is happening either because the underglaze is too highly fluxed, the over glaze has too high of a melt fluidity or the firing is being soaked too long. Engobes used under the glaze (underglazes) need to be formulated for the specific temperature and colorant they will host, cobalt is known for this problem so it needs to be hosted in a less vitreous engobe medium. When medium-colorant compounds melt too much they bleed, if too little they do not bond to the body well enough. Vigilance is needed to made sure the formulation is right.
How much does a glaze need to melt before it sticks to the body well?
The back flat side of balls of 1916J and Q low fire glaze that melted into a dome shape after being fired to 1550F. They have been turned over to see the back side (the front side is still stained by volatilizing carbon). Clearly they have reached zero porosity and are beginning to melt, yet they have not adhered to the vitreous porcelain tile! This demonstrates the degree to which an engobe must melt to secure itself well to the underlying body.
4 good reasons to consider making your own underglazes
Commercial underglaze colors fired at cone 8 in a flow tester (this is another good example of how valuable flow testers are). Underglazes need to melt enough to bond with the underlying body, but not so much that edges of designs bleed excessively into the overlying glaze. A regular glaze would melt enough to run well down the runway on this tester, but an underglaze should flow much less. The green one here is clearly not sufficiently developed. The black is too melted (and contains volatiles that are gasing). The pink is much further along than the blue. And cone 5, these samples all melt significantly less. Clearly, underglazes need to be targeted to melt at specific temperatures and each color needs specific formulation attention. Silk screening and inkjet printing are increasingly popular and these processes need ink that will fuse to the surface of the body.
The value of a white vitreous engobe over terra cotta at cone 03
At cone 03 many terra cottas will fire quite dense and stoneware-like. The lip of the mug on the left is covered with a vitreous white engobe (L3685U) under the glaze (G1916Q). Red bodies are much stronger at low temperatures, but do not lend themselves well to the bright glaze colors that work so well at that range. Putting an engobe on as a base enables decoration with colored slips and a clear over glaze. One caution: The engobe needs to have the same firing shrinkage as the body, to use a vitreous engobe the body needs a frit addition to be vitreous also. If you put a vitreous engobe on a porous earthenware its firing shrinkage will put it under tension and the poor bond with the body will mean quick or eventual failure.
How can you test if an engobe fits your clay body?
This is part of a project to fit a fritted vitreous engobe (slip) onto a terra cotta at cone 02 (it fires harder there). Left: On drying the red body curls the bi-clay strip toward itself, but on firing it goes the other way! Right: Test bars of the white slip and red body compare their drying and firing shrinkages. Center back: A mug with the white slip and a transparent overglaze. Notice the slip is going translucent under the glaze. Why? It is too vitreous. That explains how it can curl the bi-clay bars toward itself (it has a higher fired shrinkage). So rather than add zircon to opacify the slip, it is better to reduce its frit content (thereby reducing its firing shrinkage). Reducing the frit in the slip will also make it more opaque (because it will melt less). Front: A different, more vitreous red body (having a frit addition) fits the slip better (the strips dry and fire straight).
I want this engobe to gel in ten seconds. Why?
It is going to be applied to leather hard earthenware and it needs to be thixotropic (gelled when not in motion, liquid when in motion). Why? I do not want it to run down from the rims of the mugs after dipping. The process: Stir the engobe, pour-fill the mug, pour it out and push it upside down into the engobe. If I can pull it back out before the 10 second gel-time is up I get a perfectly even layer that does not move. A good test is to stir it then pull out the spatula slowly. If it hangs on in a even layer with only a few drips it is perfect. Achieving this behaviour requires very careful additions of powdered epsom salts (and thorough mixing between). As the slip approaches this 10 second threshold even a slight bit more salts will turn it into a bucket of jelly (if that happens I add a drop or two of Darvan). This process works across a range of specific gravities (about 1.45-1.6), the higher the SG the trickier it is (but the faster it dries).
Inner engobe separating at the rim
This is the only place we have noted separation with this engobe and body. The engobe was gelled and the piece was drained upside down. So this edge was thicker. The separation occurs to the convex contour a couple of mm down (and breaks away to that point). The engobe is more plastic that the clay and thus shrinks more. Normally the extra stickiness from the extra plasticity is an asset, but not always.
Potters can learn from how glazes are fit on ceramic tile
These are thermal expansion curves for body, engobe and glaze (from a dilatometer, a device that measures it against increasing temperature). The upper line is the body. The center line is the engobe. The lower line is the glaze. The ceramic tile industry is very conscious, not only of glaze-fit but also engobe-fit. Engobes (slips) are employed to cover brown or red burning bodies so they glaze like a porcelain. Typically technicians tune the formulation of the engobe to have an expansion between the body and glaze. The body is highest so that during cooling, as it contracts, it puts a squeeze on the engobe (the engobe thus never finds itself under tension). The glaze has the lowest expansion, it is under a state of compression by the engobe (and slightly more by the body). This equilibrium enables the tile to wear for many years without crazing or shivering. Chart courtesy of Mohamed Abdelmagid.
When engobing ware stick handles on well, avoid acute angles
The handle on this mug joined the wall at an acute angle. The wet engobe was applied to the leather-hard piece and took hours to dry (rewetting and softening the whole piece in the process). During that time the engobe was able to exploit the join and penetrate into it (the crack diverted straight into the soft weakened wall). Notice how the engobe has pooled at the join in the other two mugs also (although they did not fail). Engobes typically have a high water content and experiences like this teach us to take precautions when using them.
One way to avoid drying cracks on handle-joins of engobed mugs
The foot ring on these hard mugs has already been trimmed. At the stiff-leather-hard stage an engobe was applied to the inside. This rewet the bodies of the mugs, almost to the same point as freshly-thrown. But the handles did not get rewetted. To re-dry these mugs to the point of being able to turn them over will take 4-6 more hours. But by that time the handles will be bone dry. To prevent that I waxed them after trimming. That slows their drying down enough to keep them even with the body of the mug. To dry ware successfully the key is to keep all parts of a piece of the same water content throughout the process.
Bi-Clay strips test compatibility between engobe and body
Slips and engobes are fool-proof, right? Just mix the recipe you found on the internet, or that someone else recommends, and you are good to go. Wrong! Low fire slips need to be compatible with the body in two principle ways: drying and firing. Terra cotta bodies have low shrinkage at cone 06-04 (but high at cone 02). The percentage of frit in the engobe determines its firing shrinkage at each of those temperatures. Too much and the engobe is stretched on, too little and it is under compression. The lower the frit the less the glass-bonding with the body and the more chance of flaking if they do fit well (either during the firing or after the customer stresses your product). The engobe also needs to shrink with the body during drying. How can you measure compatibility? Bi-body strips. First I prepare a plastic sample of the engobe. Then I roll 4 mm thick slabs of it and the body, lay them face-to-face and roll that down to 4 mm again. I cut 2.5x12 cm bars and dry and fire them. The curling indicates misfit. This engobe needs more plastic clay (so it dry-shrinks more) and less frit (to shrink less on firing).
An engobe is shivering off the rim of a low temperature mug
Classic terra cotta bodies are not vitreous, so engobes used on them need to have similar low fired shrinkage. But when terra cottas are fired above cone 04 they start to mature and fired shrinkage increases quickly, flaking off engobes that do not have sufficient added frit (to increase their shrinkage). Even if an under-compression engobe can hang on, the extra stresses of an overglaze of lower thermal expansion can compromise the engobe:body bond. That has happened on the center mug. That engobe has less frit (10% vs. 15% for the others). The clear glaze on the left has high thermal expansion and is crazing, while the engobe:body bond can tolerate that it, is obviously not desirable.
Four drops of Davan deflocculant fixed the problem!
This is a white engobe (L3954B) drying on two dark burning cone 6 stoneware leather-hard mugs (Plainsman M390). Those lumps are on the left cannot be screened out, they are agglomerates. That slip has excessive flocculant (powdered Epsom salts are added to gel it so that it stays put on the piece after dipping). About 4 drops of Darvan were added to one gallon of the slurry, this immediately made it smooth and a perfect consistency for application. It remains stable on ware (without runs). Engobes require tight control to have the right viscosity and thixotropy (which can be achieved over a range of specific gravities (about 1.45-1.6). When they are right they are a joy to use, when they are not ware is ruined.
Should you use a porcelain as an engobe on stoneware?
This is how bad the fit can actually be. In the front is a bi-clay strip of a grogged cone 10R sculpture clay sandwiched with a porcelain. After drying this bar was relatively straight. But during firing the porcelain has a much higher fired shrinkage and it pulls the bar toward itself. During cooling, the sculpture clay has a higher thermal expansion and it pushes from its side bending the bar further. This bar is a bomb of internal stresses, just waiting for a mechanical or thermal stress to bust it into a hundred pieces. Admittedly, putting a thin layer of this onto a piece of heavy ware is not going to bend it. But will it flake off when exposed to stresses (like freeze thaw, being put in an oven, having a hot liquid poured into it, being bumped).
When two clays are joined are they compatible?
These bi-body strips are made by rolling two clays together in a thin sandwich. Three porcelains are being compared to a very plastic grogged sculpture body. After drying (top) they curl a little, two toward the sculpture body and one, the most plastic of the porcelains, toward the white. But on firing to cone 8 they curl dramatically toward the porcelain side (because it shrinks alot more). Now imagine one of these porcelains is being used as a engobe on this body.
A Cone 6 white engobe works miracles on these dark and buff burning bodies
Left is Plainsman M340. Right is M390. Each mug has been white engobed inside and half-way down the outside. The insides have been glazed using G2926B clear. The inside surface has more depth and has a richer appearance than you could achieve using a white glaze (especially over the dark burning body). The outside of the left one is Alberta Slip base GA6A using Frit 3195 (it produces a more stable glass of lower thermal expansion). The outside glaze on the right is the clear plus 4% iron oxide. This technique of using the engobe enables porcelain-like functional surfaces on the insides and striking visual contrast and character on the outside of the dark body mug.
If you think one slip fits any body, think again
This flake shivered off the rim of a low fire terra cotta mug. It is Fishsauce slip. It is about 2 inches long and has razor sharp edges. This is not the sort of thing you would want to be falling into your coffee or food and then eating! This flake did give evidence that it was loosening so there was little danger of me consuming it, but smaller flakes can go unnoticed. Slips (or engobes) must be drying compatible, have the same firing shrinkage, the same thermal expansion and be quartz inversion compatible with the body. It is easy to ignore all that and pretend that it works, but the bond between engobe and body is fragile at low fire and easily compromised by the above incompatibilities. Slips must be fitted to the specific body, glaze and temperature; that involves a testing program and often a little chemistry. I have documented online how to I adapted this slip to Plainsman Terrastone 2 using my account at insight-live.com.
Glaze under excessive compression can flake off the engobe
The amber glaze on the outside of the left mug contains 20% super-low thermal expansion Ferro Frit 3249 as the melter. With no underlying engobe it can form enough of a bond with the body that it does not flake off at the rim (even though it is under excessive compression because its low thermal expansion). This flaking is called "shivering". The engobe, which does not melt like a glaze, has a more fragile bond with the body (and the glaze is pushing enough to make that bond fail). The mug on the right employs 20% Frit 3195 melter instead, producing a glaze that fits better. I hammered both of these rims repeatedly with a metal object to stress them, that one on the right definitely fits better.
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