Dolomite matte glazes are normally fired at cone 10 and often have a very pleasant-to-the-touch silky-feeling surface. This unique feel is a product of tiny discontinuities in the glaze melt (phase changes) that exhibit at the surface as tiny waves and ripples. This phenomenon is thought to be associated with the sudden melting of MgO-sourcing particles and their conversion from an element that stiffens the melt to one that makes it more fluid (by introducing discontinuous phases of more fluidity). While the host glaze can have CaO, it needs to be at the low end of its normal range and the MgO needs to be at the high end. In addition a low silica:alumina ratio is necessary to provide a viscous enough melt and enough KNaO is needed to get a good glass. Dolomite normally sources some or all of the MgO, thus the term "dolomite matte" ("magnesia matte" is actually more correct, since talc sources MgO to produce the same effect). Thus, theoretically, it is not possible to significantly reduce the firing temperature of a specific cone 10 dolomite matte (since the mechanism would be lost). Notwithstanding, MgO can produce the silky effect at lower temperatures anyway! At cone 6, for example, in a low CaO and SiO2 glaze (also having plenty of Al2O3 to stiffen the melt and enough B2O3 flux), MgO will micro-wrinkle the surface to produce a silky matte! Dolomite does not work well to source the MgO at cone 6, talc should be used (thus the term "Talc Matte"). Even at low temperatures, MgO, as a refractory, can stiffen an otherwise fluid glaze melt and produce a matte surface (although not normally silky).
Dolomite bamboo matte glazed cone 10R mug
Courtesy of Susan Clarke
Cone 10R dolomite matte glaze with 5% manganese dioxide
By Tony Hansen
A magnesia matte that breaks on contours
GR10-G Silky magnesia matte cone 10R (Ravenscrag 100, Talc 10, Tin Oxide 4). This is a good example silky matte mechanism of high MgO. The Ravenscrag:Talc mix produces a good silky matte, the added tin appears to break the effect at the edges.
2, 5, 10, 15% dolomite added to Ravenscrag Slip at cone 10R
This is a buff stoneware clay. Crystal development toward a dolomite matte begins at 15%. By Kat Valenzuela.
Two great dolomite matte cone 10R recipes on iron stoneware
GR10-J Ravenscrag silky matte (right) and G2571A matte (left) on a dark burning iron speckled stoneware at cone 10R. Surfaces have identical feel (the chemistries are very close). The former fires a little darker color because of the iron contributed by the Ravenscrag Slip.
Ravenscrag dolomite matte
GR10-J Ravenscrag dolomite matte base glaze at cone 10R on Plainsman H443 iron speckled clay. This recipe was created by starting with the popular G2571 base recipe (googleable) and calculating a mix of materials having the maximum possible Ravenscrag Slip percentage. The resultant glaze has the same excellent surface properties (resistance to staining and cutlery marking) but has even better application and working properties. It is a little more tan in color because of the iron content of Ravenscrag Slip (see ravenscrag.com).
Tuning the degree of gloss in a colored matte glaze
Matte glazes have a fragile mechanism. That means the same recipe will be more matte for some people, more glossy for others (due to material, process and firing differences). In addition, certain colors will matte the base more and others will gloss it more. It is therefore critical for matte glaze recipes to have adjustability (a way to change the degree of gloss), both for circumstances and colors. This recipe is Plainsman G2934 base matte with 6% Mason 6600 black stain added. It has been formulated to be on the more matte side of the scale so that for most people a simple addition of G2926B (M370 transparent ultra clear base recipe) will increase the gloss. That means users need to be prepared to adjust each color of the matte to fine-tune its degree of gloss. Here you can see 5:95, 10:90, 15:85 and 20:80 blends of the matte:gloss recipe bases.
The difference between dolomite and calcium carbonate in a glaze
These glaze cones are fired at cone 6 and have the same recipe: 20 Frit 3134, 21 EP Kaolin, 27 calcium carbonate, 32 silica. The difference: The one on the left uses dolomite instead of calcium carbonate. Notice how the MgO from the dolomite completely mattes the surface whereas the CaO from the calcium carbonate produces a brilliant gloss.
A magnesia speckle matte at cone 6 oxidation is impossible, right? Wrong!
I am getting closer to reduction speckle in oxidation. I make my own speckle by mixing the body and a glossy glaze 50:50 and adding 10% black stain. Then I slurry it, dry it, fire it in a crucible I make from alumina, crush it by hand and screen it. I am using G2934 cone 6 magnesia matte as the glaze on this mug on the left. To it I added 0.5% minus 20 mesh speck. Right is a cone 10R dolomite matte mug. Next I am going to screen out the smallest specks, switch to a matte glaze when making the specks (they are too shiny here), switch to dark brown stain. Later we will see if the specks need to bleed a little more. I am now pretty well certain I am going to be able to duplicate very well the reduction look in my oxidation kiln. I will publish the exactly recipe and technique as soon as I have it.
Looking for a non-crazed non-cutlery marking cone 10R dolomite matte?
This is G2571A cone 10R dolomite matte on an ironware body made from native North Carolina clays. Few glazes have the pleasant silky feel that this has yet are still functional. The feldspar content in the body has been tuned to establish a compromise between the warmer color low percentages have with the higher strength that higher percentages impart. Careful porosity tests were done and recorded in an account at insight-live.com. The objective was to bring the body close to 3% absorption.
Matte glaze cutlery marks. Add 10% glossy glaze to it. No marking.
This is G2934Y (a version of the G2934 cone 6 matte base recipe that supplies much of the MgO from a frit instead of dolomite). Like the original, it has a beautiful fine silky matte surface and feels like it would not cutlery mark. But, as you can see on the left, it does! The marks can be cleaned off easily. But still, this is not ideal. The degree of matteness that a glaze has is a product of its chemistry. But can we fix this without doing any chemistry? Yes. By blending this with G2926B clear glossy (90:10 proportions) the marks are gone and the surface is only slightly changed.
Matte cone 6 glazes have identical chemistry but one melts more. Why?
These are 10 gram GBMF test balls that we melted on porcelain tiles at cone 4 (top two) and cone 6 (bottom two). They compare the melt fluidity of G2934 (left) and G2934Y (right). The Y version sources its MgO from frit and talc (rather than dolomite). It is a much more fluid melt because the frit is yielding the oxides more readily. But Y has a key benefit: It has a much lower LOI, producing fewer entrained air bubbles and therefore fewer surface defects. And, even though it runs much more, it has the same matte surface! As long as it is applied at normal thickness, the extra melt fluidity does not cause any running. And it has another benefit: Less cutlery marking issues. It is actually a very durable and practical food surface glaze, having a low thermal expansion that fits almost any body. Although these appear glossy here, on ware they have the identical pleasant silky matte surface.
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