Overglaze decoration (and often underglaze also) often bleed on the edges, especially brushstrokes. The higher the melt fluidity of the colored layer the more bleeding will occur, especially if the over or under glaze is also fluid. Cobalt colors are often more fluid and runny, that is why this problem is most commonly seen with blues.
Bleeding underglaze. Why?
This cobalt underglaze is bleeding into the transparent glaze that covers it. This is happening either because the underglaze is too highly fluxed, the over glaze has too high of a melt fluidity or the firing is being soaked too long. Engobes used under the glaze (underglazes) need to be formulated for the specific temperature and colorant they will host, cobalt is known for this problem so it needs to be hosted in a less vitreous engobe medium. When medium-colorant compounds melt too much they bleed, if too little they do not bond to the body well enough. Vigilance is needed to made sure the formulation is right.
A fluid melt glaze bleeds much more into adjoining ones
The outer green glaze on these cone 6 porcelain mugs has a high melt fluidity. The liner glaze on the lower one, G2926B, is high gloss but not highly melt fluid. Notice that it forms a fairly crisp boundary with the outer glaze at the lip of the mug. The upper liner is G3806C, a fluid melt high gloss clear. The outer and inner glazes bleed together completely forming a very fuzzy boundary.
Why you should not paint pure stain powders over glaze
On the left is a pure blue stain, on the right a green one. Obviously, the green is much more refractory. On the other hand, the green just sits on the surface as a dry, unmelted layer. For this type of work, stains need to be mixed into a glaze-like recipe of compatible chemistry (a medium) to create a good, paintable color. The blue is powerful, it would only need to comprise 5-10% of the recipe total. Its medium would need to have a stiffer melt (so the cobalt fluxes it to the desired degree of melt fluidity). A higher percentage of the green stain is needed, perhaps double. It's medium needs much more melt fluidity since the stain is refractory. Of course, only repeated testing would get them just right. Guidelines of the stain manufacturer for chemistry compatibility need to be consulted also (as certain stains will not develop their color unless their glaze medium host has a compatible chemistry). And, to be as paintable as possible, use use a gum-solution/water mix (e.g. 2 parts water to one part gum solution).
Cobalt and iron overglazes bleeding into the matte glaze
This is the G2934Y matte base with overglaze decoration fired at cone 6. Although this matte has a high melt fluidity, overglaze decoration can be successful as long as it is not applied too thick and not overfired. But in this case the glaze is thickly applied. Once the critical thickness boundary is passed, the glaze's ability to hold overglaze in place quick degrades. The G2934 recipe has less melt fluidity and fires to the same surface, it would would be a better choice as the base glaze in this case (and could be applied thicker). However this Y variation would be a good choice as the medium if you want to make your own overglaze brushable colors.
Underglaze color mayhem!
Commercial underglaze colors fired at cone 5 in a flow tester. Underglazes blend stains with a host recipe that should fuse them enough to adhere well to the body (two of these have not even begun to do that). The blue, green and red are from one manufacturer. Stain powders have different melting temperatures, so underglaze formulators must treat each stain individually, customizing the underglaze recipe to its melting behavior. As you can see, they have failed to do that here, the pink one has shrunk to half its size and is about to melt (it needs less flux). The green one is only sintered (it needs more flux). The black underglaze (D) (from a second manufacturer) contains gassing materials, it has become an Aero chocolate bar and is about to race down the runway. The E black (a third manufacturer) has not even started to melt or even sinter. The blacks were plastic, the colored ones were not. I am confused. How could the glaze possibly stick well to the body with the green or unmelted black under it?
4 good reasons to consider making your own underglazes
Commercial underglaze colors fired at cone 8 in a flow tester (this is another good example of how valuable flow testers are). Underglazes need to melt enough to bond with the underlying body, but not so much that edges of designs bleed excessively into the overlying glaze. A regular glaze would melt enough to run well down the runway on this tester, but an underglaze should flow much less. The green one here is clearly not sufficiently developed. The black is too melted (and contains volatiles that are gasing). The pink is much further along than the blue. And cone 5, these samples all melt significantly less. Clearly, underglazes need to be targeted to melt at specific temperatures and each color needs specific formulation attention. Silk screening and inkjet printing are increasingly popular and these processes need ink that will fuse to the surface of the body.
Underglazes can be incompatible with the clear overglaze
These are porcelain tiles that we bisque fired, one-coat decorated with underglazes (Crysanthos), glazed with G3806PS fluid-melt glossy clear glaze and fired to cone 6. Fluid melt clear glazes cover colors much better (without crawling or clouding). Some colors are bleeding, if needed this glaze can be adjusted (by adding kaolin) to make it melt a little less. The rose color on the upper right, #093, is not working? Why? It likely employs a chrome-tin stain, these have requirements: A clear glaze having a minimum amount of CaO, no ZnO and not too much B2O3. This glaze does not qualify. But no transparent glaze works with all underglazes. You could find others that work with #093 but they could cloud, craze, crawl and not be glossy enough. The other orange/pink colors here are working. Why? Because they likely employ inclusion stains. A key factor is that the black is working well, even when applied over the white underglaze.
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