Zircopax
Zirconium Silicate
| MLPT - Melting Point (MP) |
2550C |
Zircopax is a brand name version of zirconium silicate or zircon (see Zircon for more information). Zirconium prices are have increased rapidly in recent years, reflecting the world supply situation.
It is often used for semi-opaqueness (finer materials like Superpax provide more opacity). In North America, the most popular zirconium opacifiers fall under the brand names of Zircopax, Superpax and Excelopax. These vary according to particle size, the finer the size the greater the scattering of light (and thus the better the opacification). In addition, the finer sized materials contain a little extra silica for maximum whiteness.
Of course, the amount of zircopax in a glaze determines the opacity. Small amounts (1-3%) may give no noticeable difference but are sometimes employed to improve glaze hardness. Since zircopax is refractory, the more that is added the more the degree of glaze melting is going to be affected. Up to 15% or more might be needed to fully opacify a glaze. If higher amounts are needed the glaze formulation may need to be adjusted to reduce the amount of SiO2 or increase flux (to melt the glaze better).
Zircopax affects glaze melt viscosity, surface smoothness, thermal expansion and color development and can be implicated in a range of glazes faults associated with these. Please read the page on zircon for more information.
Zircopax can be used to whiten porcelain bodies, especially for casting, but of course, translucency is lost.
Typical Properties:
Formula: ZrSio4 Weight: 183.1
Linear Coefficient of Expansion (25-700C cm/cm/degreeC): 42 x 10 -7
Specific gravity: 4.5
Particle Size: Zircopax Superpax Excelopax
Microns, Ave. 1.3 .74 .55
Bulk density lbs/cu ft 100 75 75
Surface area, m2/g 4.5 9.8 12.8
Mechanisms
Glaze Opacifier - White Zirconium silicates are used primarily as opacifiers in glazes at all temperatures. Although tin oxide is more effective, zirconium materials are much cheaper and are more stable in reduction and less reactive with some colorants (i.e. chrome). Although zirconium oxide is effective as an opacifier, zirconium silicates disperse better and are cheaper where the glaze can tolerate or be reformulated to tolerate the added silica.
Out Bound Links
- (Materials - Alternative)
Tin Oxide - SnO2
Stannic Oxide, Tin(IV) Oxide, Tin Dioxide, SnO2
- (Materials - Related)
Superpax - Zirconium silicate
- (Materials - Related)
Zircopax Plus - Zirconium Silicate Opacifier
- (Materials - Related)
Ultrox - Zirconium Silicate Glaze Opacifier
- (Materials - Parent)
Zircon - ZrO2.SiO2
Zirconium Silicate
- (URLs)
Zirconium at Wikipedia
http://en.wikipedia.org/wiki/Zirconium - (Typecodes)
1: OPA - Opacifier
- (MDT - Member)
North America
The decision about what materials to include in th... - (MDT - Member)
Ron Roy
This is the traditional Ron Roy materials file. He... - (MDT - Member)
Crystal Glazes
These materials are specially defined for makers o... - (MDT - Member)
Australia
We are working on this database and would apprecia... - (MDT - Member)
New Zealand
We are working on this database and would apprecia...
In Bound Links
XML for Import into INSIGHT
<?xml version="1.0" encoding="UTF-8"?>
<material name="Zircopax" descrip="Zirconium Silicate" searchkey="" loi="0.00" casnumber="366497-20-3">
<oxides>
<oxide symbol="SiO2" name="Silicon Dioxide, Silica" status="" percent="32.790" tolerance=""/>
<oxide symbol="ZrO2" name="Zirconium Dioxide" status="U" percent="67.210" tolerance=""/>
</oxides>
</material> |
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