Digitalfire Ceramic Materials Database

Logged in as Level 2 access: Logout


Kaolin

Hydrated alumina silicate, Pure clay mineral

Formula: Al2O3.2SiO2 or Al2Si2O5(OH)4
Alternate Names: China Clay

OxideAnalysisFormula
Al2O340.21%1.00
SiO247.29%2.00
LOI12.50
Oxide Weight221.96
Formula Weight253.67
Enter the formula and formula weight directly into the Insight MDT dialog (since it records materials as formulas).
Enter the analysis into an Insight recipe and enter the LOI using Override Calculated LOI (in the Calc menu). It will calculate the formula.
DENS - Density (Specific Gravity) 2.62
MLPT - Melting Point (MP) 1770C M

A wide array of kaolin (also known as China Clay) products are available. These vary in plasticity, crystal and surface chemistry, particle shape and size, flow properties, permeability, etc. However the most common varieties most people will see are two: kaolins intended for plastic bodies or casting ones. Plastic kaolins can rival the workability of a ball clay, casting ones can be so short that it is difficult to even wedge or roll them without the plastic mass falling apart. Strangely, non-plastic kaolins are not necessarily whiter burning.

Pure kaolin is the clay of choice for bodies that need to be clean and white. Many porcelains contain only a kaolin mix as their clay complement. But kaolins have relatively low plasticity when compared to other raw clay types. Thus in non-casting plastic forming bodies it is often not possible to achieve enough plasticity employing kaolin alone. Additions of ball clays, bentonites and other plasticizers are thus common. Where translucency and whiteness are paramount, highly plastic kaolins and white burning ball clays and bentonites can be used .

Because kaolinite mineral has a much larger particle size than ball clay and bentonite materials, blending it with them in bodies can produce a good cross section of ultimate particle sizes (this imparts enhanced working and drying properties). Another advantage of the larger particle size of kaolins is that they are much more permeable to the passage of water. Thus kaolins, especially the larger sized ones, speed up casting rates in slurry bodies and drying rates in all bodies.

Kaolins are employed in glaze recipes to keep the silica, feldspar, frit and other particles from settling out (the surface chemistry of the particles and their interaction with water are responsible for this behavior). At the same time the oxide chemistry of kaolin makes it the primary source of alumina oxide for glazes.

Kaolin is a very refractory aluminum silicate. Kaolin-based bodies are used to make all kinds of refractory parts for industry. Kiln wash is often made from 50:50 mix of kaolin and silica. Cordierite is made mainly from kaolin. High heat duty grogs are made by calcining kaolin.

Kaolin is used in many industries other than ceramics, in fact the ceramics industry uses only a small amount of the total kaolin produced. Kaolin companies tend to be billion-dollar operations and kaolin is used in everything from paper to cosmetics, paint to agricultural products.

If you use kaolin in your production there is good reason to be doing routine quality control to make sure it is remaining consistent. Kaolins can sometimes have particulate impurities (can cause firing specks) and exhibit differences in soluble salts content, drying shrinkage, drying performance and behavior in slurries. Clays are often the most variable material that production departments have to deal with.

Kaolin transforms to mullite above 1000C, this is a key factor in the micro structure of porcelain and other types of bodies. This transformation is also exploited in engobes.


Mechanisms

  • Body Plasticity - Porcelain, Whtieware Bodies

    It is possible to make a plastic throwing body using 50% kaolin only, however you must choose one of the highly plastic varieties such as #6 Tile. Even then you will likely need a little bentonite to augment the kaolin. There is a huge range in kaolin plasticities, test for yourself to find out.

  • Glaze Suspender - General

    Kaolin is the most common glaze suspender. Depending on the type of kaolin used, 15-20% should be enough. Many fritted glazes are composed solely of frit and kaolin. Some kaolins make the glaze gel, this is a helpful additional mechanism to keep it suspended.

Out Bound Links

  • (Glossary - Unspecified) Clay

    Clays occur when parent clay-making rocks (there a...

  • (Materials - Parent) Kaolin - Al2O3.2SiO2 or Al2Si2O5(OH)4 - Hydrated alumina silicate, Pure clay mineral

    China Clay

  • (URLs - Technical inforamtion) Kaolin at Wikipedia.com
    http://en.wikipedia.org/wiki/Kaolin
  • (Hazards) Kaolin
    The hazards of using this material in the ceramic ...
  • (Typecodes) 1: GNM - Generic Material
  • (Typecodes - Type) 1: KAO - Kaolin
  • (URLs) Information at Kaolin.com
    http://kaolin.com/
  • (MDT - Member) Generic

    Generic for building a completely custom MDT. Only...

  • (MDT - Member) Europe

    Countries of Eastern Europe and former Soviet Unio...

  • (MDT - Member) Australia

    We are working on this database and would apprecia...

  • (MDT - Member) Asia

    All of Asia including Turkey, Russia, Indosnesia, ...

  • (Minerals - Parent mineral) Kaolinite

    The most fundamental clay mineral. It is weathered...

  • (Glossary - Unspecified) Porcelain

    A comparatively white burning clay body (unless st...

  • (Tests - Unspecified) SHAB - Shrinkage/Absorption
  • (Tests - Unspecified) SIEV - Sieve Analysis 35-325 Wet
  • (MDT - Member) Africa

    All of continental Africa. We are working on this ...

  • (MDT - Member) Latin and South America

    Latin America and South America. We are working on...

  • (MDT - Member) New Zealand

    We are working on this database and would apprecia...

  • (MDT - Member) North America

    The decision about what materials to include in th...

  • (MDT - Member) UK

    We are working on this database and would apprecia...

  • (MDT - Member) Glass Industry

    The materials included in this MDT were selected i...

In Bound Links


Pictures
Ball clay and kaolin test bars side-by-side fired from cone 9-11 oxidation and 10 reduction.

Click for 494% larger

Large particle kaolin (left) and small-particle ball clay (right) DFAC drying disks demonstrate the dramatic difference in drying shrinkage and performance between these two extremes.

Click for 459% larger


By Tony Hansen

XML for Import into INSIGHT

<?xml version="1.0" encoding="UTF-8"?> <material name="Kaolin" descrip="Hydrated alumina silicate, Pure clay mineral" searchkey="China Clay" loi="0.00" casnumber="95077-05-7"> <oxides> <oxide symbol="Al2O3" name="Aluminum Oxide, Alumina" status="" percent="40.210" tolerance=""/> <oxide symbol="SiO2" name="Silicon Dioxide, Silica" status="" percent="47.290" tolerance=""/> </oxides> <volatiles> <volatile symbol="LOI" name="Loss on Ignition" percent="12.500" tolerance=""/> </volatiles> </material>
The future of ceramic recipe, material and physical testing record keeping is here. Just pennies a day.
Watch the video or sign-up at http://insight-live.com.

Maintain your recipes and materials on-line

  • Login to a private account or work with others in a group account (e.g. university).
  • Nothing to install (access it using your web browser). It is always the latest version.
  • Import existing material, recipe data.
  • As many side-by-side recipes and/or materials as you want (chemistry is shown for all).
  • Many ways to search and classify glaze and body recipes.
  • Glaze and body recipes are robust, with units-of-measure, pictures with individual titles and descriptions, material links.
  • Add variations to a recipe; each with its own pictures, descriptions and name/code-number extensions.
  • Recipes can link to materials, typecodes, projects and firing schedules (all managed in their own areas).
  • Standard reports and mix ticket reports with last-minute-totalling; variations report as if they are a complete recipe.
  • Video tutorials, help system, contact form on every page, dedicated messaging and support ticket systems.
  • It is an industrial-strength database system (unlimited capacity, fast, reliable, scalable).

Imports many file formats

  • Glaze recipe formats supported: HyperGlaze, GlazeGhem, GlazeMaster, Matrix, INSIGHT XML recipes (single and multiple), INSIGHT SQLite DB files.
  • Assign a batch number to recipe imports (later search by batch).
  • Assign multiple typecodes to imported glaze and body batches (to classify) (search on these later).
  • Prepend character sequences to glaze recipe names during import.
  • Import the pictures and pair them to their corresponding recipe records automatically.
  • One click to automatically export the database to an SQLite DB database file and download it (for use with desktop INSIGHT or just as a backup).
  • Export and import individual glaze recipes as text or XML.
  • Import materials data in various formats or just use the thousands of built-in reference materials.

Perfect for Education

  • Ceramic study programs can now accumulate material, recipe and testing data year-after-year, students can login and together build a valuable ceramic glaze and body knowledge resource.
  • Students already have internet connected devices, computers are not even needed in the class.
  • The Reference Manager gives you quick access to the Digitalfire Ceramic Reference Database.
Learn more..



Feedback, Suggestions

Your email address

Subject

Your Name

Message


Copyright 2003, 2008 http://digitalfire.com, All Rights Reserved
Get a free INSIGHT software trial

INSIGHT is ceramic chemistry
calculation software that runs on
Windows, Mac and Linux and talks
to this web site. ()