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Crocus Martis

Anhydrous Ferrous Sulphate FeSo4, Calcined Copperas

OxideAnalysisFormula
Fe2O341.64%1.000
FeO37.48%1.761
SO320.88
Oxide Weight304.02
Formula Weight384.25
Enter the formula and formula weight directly into the Insight MDT dialog (since it records materials as formulas).
Enter the analysis into an Insight recipe and enter the LOI using Override Calculated LOI (in the Calc menu). It will calculate the formula.

Has been used in glazes as a substitute for red iron oxide.

There are varying ideas from country to country about what this material is. Historically it was just a naturally-occurring red iron oxide containing impurities (i.e. clay minerals) or an ultra-high iron clay. Today, Crocus Martis sold by ceramic suppliers is more likely to be a soluble synthetic impure red iron sulphate or a calcined-at-900C version of the sulphate (it is insoluble). This material is not normally highly processed and therefore can produce iron specking in glazes. Normal iron oxides can be used as a substitute (although less will be needed since this material has a significant weight loss during firing).

Sulphur is released during firing and it does not decompose fully until as high at 1200C.


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In Bound Links


By Tony Hansen

XML for Import into INSIGHT

<?xml version="1.0" encoding="UTF-8"?> <material name="Crocus Martis" descrip="Anhydrous Ferrous Sulphate FeSo4, Calcined Copperas" searchkey="" loi="20.88" casnumber=""> <oxides> <oxide symbol="Fe2O3" name="Iron Oxide, Ferric Oxide" status="" percent="41.640" tolerance=""/> <oxide symbol="FeO" name="Ferrous Oxide" status="" percent="37.480" tolerance=""/> </oxides> <volatiles> <volatile symbol="SO3" name="Sulfur Trioxide" percent="20.880" tolerance=""/> </volatiles> </material>


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